The quantification of transparent exopolymer particles(TEP) by colorimetric method is of large error and low repeatability,one major reason of which is related to the absence of clear definition and evaluation for par...The quantification of transparent exopolymer particles(TEP) by colorimetric method is of large error and low repeatability,one major reason of which is related to the absence of clear definition and evaluation for part steps of the original method.It is obscure that the 80% sulfuric acid solution,acted as the extraction solution in the determination of TEP,is prepared based on a volume ratio or mass ratio.Furthermore,the change of solubility of recently available Gum Xanthan(GX) from the market means that the original protocol is no longer applicable,and the grinding of GX stock solution with a tissue grinder is replaced by shaking with a rotating shaker in the study to prevent the excessive dissolution of GX.We found that different preparation techniques could result in the varied concentrations of 80% H_(2)SO_(4).The duration of shaking during the preparation of standard solution significantly affected the slope of the calibration curve,which caused different correction results of TEP.The impacts of different extraction solution concentrations and shaking time of GX solution on the quantification of TEP were investigated based on the field sampling and laboratory analysis.The extraction capacities of H_(2)SO_(4) with different concentrations for Alcian Blue were distinct,but had limited effect on the final measuring result of TEP.The change of the standard curve slope came along with the variation of shaking time,which markedly altered the detection limit and calibration result,and the extended shaking time was in favor of the determination of low-concentration TEP.It was suggested that the extraction solution concentration,shaking time and filtration volume of standard solution are required to be well controlled and selected to obtain more accurate results for TEP with different concentrations.展开更多
Because nearby construction has harmful effects,precisely predicting blast-induced ground vibration is critical.In this paper,a hybrid artificial bee colony(ABC)and support vector machine(SVM)model was proposed for pr...Because nearby construction has harmful effects,precisely predicting blast-induced ground vibration is critical.In this paper,a hybrid artificial bee colony(ABC)and support vector machine(SVM)model was proposed for predicting the value of peak particle velocity(PPV),which is used to describe blast-induced ground vibration.To construct the model,5 potentially relevant factors,including controllable and uncontrollable parameters,were considered as input parameters,and PPV was set as the output parameter.Forty-five samples were recorded from the Hongling lead-zinc mine.An ABC-SVM model was developed and trained on 35 samples via 5-fold cross-validation(CV).A testing set(10 samples)was used to evaluate the prediction performance of the ABC-SVM model.SVM and four empirical models(United States Bureau of Mines(USBM),Amraseys-Hendron(A-H),Langefors-Kihstrom(L-K),and Central Mining Research Institute(CMRI))also were introduced for comparison.Next,the performances of the models were analyzed by using 3 statistical parameters:the correlation coefficient(R2),root-mean-square error(RMSE),and variance accounted for(VAF).ABC-SVM had the highest R2 and VAF values followed by the SVM,A-H,USBM,CMRI,and L-K methods.The results demonstrated that ABC-SVM outperformed SVM and the empirical predictors for predicting PPV.Moreover,the best results from the R2,RMSE,and VAF indices were 0.9628,0.2737,and 96.05%for the ABC-SVM model.The sensitivities of the parameters also were investigated,and the height difference between the blast point and the monitoring station was found to be the parameter that had the most influence on PPV.展开更多
基金The National Key Research and Development Project of China under contract No.2019YFC1407805the National Natural Science Foundation of China under contract Nos 41876134, 41676112 and 41276124+1 种基金the Tianjin 131 Innovation Team Program under contract No.20180314the Changjiang Scholar Program of Chinese Ministry of Education under contract No.T2014253。
文摘The quantification of transparent exopolymer particles(TEP) by colorimetric method is of large error and low repeatability,one major reason of which is related to the absence of clear definition and evaluation for part steps of the original method.It is obscure that the 80% sulfuric acid solution,acted as the extraction solution in the determination of TEP,is prepared based on a volume ratio or mass ratio.Furthermore,the change of solubility of recently available Gum Xanthan(GX) from the market means that the original protocol is no longer applicable,and the grinding of GX stock solution with a tissue grinder is replaced by shaking with a rotating shaker in the study to prevent the excessive dissolution of GX.We found that different preparation techniques could result in the varied concentrations of 80% H_(2)SO_(4).The duration of shaking during the preparation of standard solution significantly affected the slope of the calibration curve,which caused different correction results of TEP.The impacts of different extraction solution concentrations and shaking time of GX solution on the quantification of TEP were investigated based on the field sampling and laboratory analysis.The extraction capacities of H_(2)SO_(4) with different concentrations for Alcian Blue were distinct,but had limited effect on the final measuring result of TEP.The change of the standard curve slope came along with the variation of shaking time,which markedly altered the detection limit and calibration result,and the extended shaking time was in favor of the determination of low-concentration TEP.It was suggested that the extraction solution concentration,shaking time and filtration volume of standard solution are required to be well controlled and selected to obtain more accurate results for TEP with different concentrations.
基金National Natural Science Foundation of China(NSFC)under Grant Nos.52104125 and 52104109the Fundamental Research Funds for the Central Universities under Grant No.B220202056+2 种基金the Opening Fund of State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal Mines under Grant No.SKLMRDPC21KF04the Natural Science Basic Research Plan in Shaanxi Province of China(2022JQ-304)the Fund of Young Elite Scientists Sponsorship Program by CAST under Grant No.2021QNRC001。
文摘Because nearby construction has harmful effects,precisely predicting blast-induced ground vibration is critical.In this paper,a hybrid artificial bee colony(ABC)and support vector machine(SVM)model was proposed for predicting the value of peak particle velocity(PPV),which is used to describe blast-induced ground vibration.To construct the model,5 potentially relevant factors,including controllable and uncontrollable parameters,were considered as input parameters,and PPV was set as the output parameter.Forty-five samples were recorded from the Hongling lead-zinc mine.An ABC-SVM model was developed and trained on 35 samples via 5-fold cross-validation(CV).A testing set(10 samples)was used to evaluate the prediction performance of the ABC-SVM model.SVM and four empirical models(United States Bureau of Mines(USBM),Amraseys-Hendron(A-H),Langefors-Kihstrom(L-K),and Central Mining Research Institute(CMRI))also were introduced for comparison.Next,the performances of the models were analyzed by using 3 statistical parameters:the correlation coefficient(R2),root-mean-square error(RMSE),and variance accounted for(VAF).ABC-SVM had the highest R2 and VAF values followed by the SVM,A-H,USBM,CMRI,and L-K methods.The results demonstrated that ABC-SVM outperformed SVM and the empirical predictors for predicting PPV.Moreover,the best results from the R2,RMSE,and VAF indices were 0.9628,0.2737,and 96.05%for the ABC-SVM model.The sensitivities of the parameters also were investigated,and the height difference between the blast point and the monitoring station was found to be the parameter that had the most influence on PPV.