A facile approach was developed for the synthesis of polycrystalline palladium nanoparticles(Pd NPs)by using tannic acid(TA) as green reagent and stabilizer in a 30 ℃ water bath. The size of Pd NPs can be tuned in a ...A facile approach was developed for the synthesis of polycrystalline palladium nanoparticles(Pd NPs)by using tannic acid(TA) as green reagent and stabilizer in a 30 ℃ water bath. The size of Pd NPs can be tuned in a range of 10–60 nm simply by adjusting the concentration of Pd precursor. The catalytic activity and stability of the as-obtained Pd NPs toward formic acid oxidation were analyzed. It is found that these Pd NPs with different sizes exhibit size-dependent and enhanced formic acid oxidation performance compared to the commercial Pd black catalyst. It should be noted that the Pd catalysts with an average size of 24 nm demonstrate the best catalytic activity and stability among the other prepared Pd NPs, which can be ascribed to its larger electrochemical surface area(ECSA)and polycrystalline structure with defects.展开更多
This study investigated the level of natural radioactivity and radiological risks of 40 different ceramic tiles through gamma-ray spectroscopy using a high-purity germanium detector. The calculated activity concentrat...This study investigated the level of natural radioactivity and radiological risks of 40 different ceramic tiles through gamma-ray spectroscopy using a high-purity germanium detector. The calculated activity concentrations were evaluated to determine their potential radiological risks to human health. Furthermore, the activity concentrations were subjected to the RESRAD-BUILD computer code to assess the effect of ventilation rate, dweller position, and room size and direction on the total effective dose(TED). The simulated TED received by a receptor when changing the ventilation rate in a room ranged from0.26 ± 0.01 to 0.61 ± 0.01 mSv/y; however,the percentage variations in the TED due to dweller position and room size are 34, 31,and 35% and 33, 27, and 40% for the x-,y-,and z-directions, respectively. The overall TED received by the dweller based on room size and direction is 0.75 mSv/y. The calculated radiological risk parameters were all below the recommended maximum limit. However, the TED received by the dweller is significantly affected by the directions of the measurement, position,room size,and ventilation. Therefore,estimating the TED from one direction would underestimate the total dose received by the dweller.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51371119 and 51571151)
文摘A facile approach was developed for the synthesis of polycrystalline palladium nanoparticles(Pd NPs)by using tannic acid(TA) as green reagent and stabilizer in a 30 ℃ water bath. The size of Pd NPs can be tuned in a range of 10–60 nm simply by adjusting the concentration of Pd precursor. The catalytic activity and stability of the as-obtained Pd NPs toward formic acid oxidation were analyzed. It is found that these Pd NPs with different sizes exhibit size-dependent and enhanced formic acid oxidation performance compared to the commercial Pd black catalyst. It should be noted that the Pd catalysts with an average size of 24 nm demonstrate the best catalytic activity and stability among the other prepared Pd NPs, which can be ascribed to its larger electrochemical surface area(ECSA)and polycrystalline structure with defects.
基金supported by the Universiti Kebangsaan Malaysia(UKM)under Grant Number GGPM-2017-084
文摘This study investigated the level of natural radioactivity and radiological risks of 40 different ceramic tiles through gamma-ray spectroscopy using a high-purity germanium detector. The calculated activity concentrations were evaluated to determine their potential radiological risks to human health. Furthermore, the activity concentrations were subjected to the RESRAD-BUILD computer code to assess the effect of ventilation rate, dweller position, and room size and direction on the total effective dose(TED). The simulated TED received by a receptor when changing the ventilation rate in a room ranged from0.26 ± 0.01 to 0.61 ± 0.01 mSv/y; however,the percentage variations in the TED due to dweller position and room size are 34, 31,and 35% and 33, 27, and 40% for the x-,y-,and z-directions, respectively. The overall TED received by the dweller based on room size and direction is 0.75 mSv/y. The calculated radiological risk parameters were all below the recommended maximum limit. However, the TED received by the dweller is significantly affected by the directions of the measurement, position,room size,and ventilation. Therefore,estimating the TED from one direction would underestimate the total dose received by the dweller.
