Fe-La, Fe-Ce, Fe-La-P, Fe-Ce-P and Fe-P alloys were obtained f rom aqueous solutions by using optimized electroplaing solutions and process con ditions. The experimental results show that these alloys (Fe-La-P, Fe-Ce-...Fe-La, Fe-Ce, Fe-La-P, Fe-Ce-P and Fe-P alloys were obtained f rom aqueous solutions by using optimized electroplaing solutions and process con ditions. The experimental results show that these alloys (Fe-La-P, Fe-Ce- P and Fe-P) have amorphous structure. The crystallization activation energy a nd kinetics equation of three kinds amorphous coatings have been determined by D SC method. The results indicated that the crystallization activation energy of F e-P, Fe-La-P, Fe-Ce-P amorphous coatings are 175.2, 370.1, 434.6kJ·m ol-1 respectively. The crystallization mechamism of three kinds amorphous alloy s may be expressed by Avrami-Erofeev equation (n=1), the kinetics equation is .展开更多
This paper summarizes the new developments in the study of barium rare-earth fluor-carbonate mineral structures .The second order superstructure of cebaite -(Ce ) was solved by using high power X-ray single crystal di...This paper summarizes the new developments in the study of barium rare-earth fluor-carbonate mineral structures .The second order superstructure of cebaite -(Ce ) was solved by using high power X-ray single crystal diffractometer . Five kinds of coordination forms were found . All atoms in the cell , including C and F , were properly located . In the process of study in a cordylite-(Ce ), a new mineral was discovered , whose chemical formula is (Ca0.5□0.5) BaCe2 (CO3)4F . It is isostructural with baiyuneboite - (Ce ), but different in composition (Na in baiyuneboite- (Ce ) is substituted by Ca disorderly ) . On the basis of the studies a proposal to re-define cordylite-(Ce )as a mineral group name is put forth by the authors . Finally a new type of twinning of huanghoite-(Ce ) was found on the systematical absence of diffraction data by means of a single crystal diffractometer .展开更多
文摘Fe-La, Fe-Ce, Fe-La-P, Fe-Ce-P and Fe-P alloys were obtained f rom aqueous solutions by using optimized electroplaing solutions and process con ditions. The experimental results show that these alloys (Fe-La-P, Fe-Ce- P and Fe-P) have amorphous structure. The crystallization activation energy a nd kinetics equation of three kinds amorphous coatings have been determined by D SC method. The results indicated that the crystallization activation energy of F e-P, Fe-La-P, Fe-Ce-P amorphous coatings are 175.2, 370.1, 434.6kJ·m ol-1 respectively. The crystallization mechamism of three kinds amorphous alloy s may be expressed by Avrami-Erofeev equation (n=1), the kinetics equation is .
文摘This paper summarizes the new developments in the study of barium rare-earth fluor-carbonate mineral structures .The second order superstructure of cebaite -(Ce ) was solved by using high power X-ray single crystal diffractometer . Five kinds of coordination forms were found . All atoms in the cell , including C and F , were properly located . In the process of study in a cordylite-(Ce ), a new mineral was discovered , whose chemical formula is (Ca0.5□0.5) BaCe2 (CO3)4F . It is isostructural with baiyuneboite - (Ce ), but different in composition (Na in baiyuneboite- (Ce ) is substituted by Ca disorderly ) . On the basis of the studies a proposal to re-define cordylite-(Ce )as a mineral group name is put forth by the authors . Finally a new type of twinning of huanghoite-(Ce ) was found on the systematical absence of diffraction data by means of a single crystal diffractometer .
