Bonded type RE3+ doped luminescent co-polymer was synthesized by solution free radical copolymerization. The influence of charge sequence, monomers and co-polymerized method on properties and structures of the co-poly...Bonded type RE3+ doped luminescent co-polymer was synthesized by solution free radical copolymerization. The influence of charge sequence, monomers and co-polymerized method on properties and structures of the co-polymers was studied. The emission intensity of the co-polymers at different RE3+ concentrations was tested. The results showed that the co-polymers of Eu-PSt and Eu-PMMA both had wide absorption peak at 200-400 nm and the strongest peak appeared at 235 nm. The fluorescent intensity of Eu3+ doped polystyrene co-polymer was stronger than that of Eu3+ doped PMMA copolymer. The characteristic emission of europium ions was observed in the co-polymers. The copolymer doped with rare earth elements showed the 'sensitization effect' for the central ions. The bonded-type rare earth copolymer not only enhanced the energy transfer efficiency, but also improved the fluorescence intensity by increasing the rigidity of main and side chain.展开更多
A two-stage process has been developed to generate the silica-based macromonomer through surface-modification of silica with polymerizable vinyl groups. The silica surfaces were treated with excess 2,4-toluene diisocy...A two-stage process has been developed to generate the silica-based macromonomer through surface-modification of silica with polymerizable vinyl groups. The silica surfaces were treated with excess 2,4-toluene diisocynate (TDI), after which the residual isocyanate groups were converted into polymerizable vinyl groups by reaction with hydroxypropylacrylate (HPA). Thus, polystyrene/silica nanocomposites were prepared by conventional radical copolymerization of styrene with silica macromonomer. The main effecting factors, such as ratios of styrene to the macromonomer, together with polymerization time on the copolymerization were studied in detail. FTIR, DSC and TGA were utilized to characterize the nanocomposites. Experimental results revealed that the silica nanoparticles act as cross-linking points in the polystytene/silica nanocomposites, and the glass transition temperatures of the nanocomposites are higher than that of the corresponding pure polystyrene. The glass transition temperatures of nanocomposites increased with the increasing of silica contents, which were further ascertained by DSC.展开更多
A Monte Carlo method was used to take thorough account of the influences of different reactivity ratios and initial feed compositions on copolymer microstructure.The model proves the lack of azeotropic behavior in sys...A Monte Carlo method was used to take thorough account of the influences of different reactivity ratios and initial feed compositions on copolymer microstructure.The model proves the lack of azeotropic behavior in systems in which r_A>1 and r_B<1 or vice versa;it is also able to calculate the drift in the copolymer properties:copolymer composition,and randomness parameter.Moreover,for each reactivity ratio pair given,there is a unique reaction conversion,at which macromolecules produced inherit their ...展开更多
基金Project supported by the Special Funds for Major State Research Projectsthe National Natural Science Foundation of China (50373034)
文摘Bonded type RE3+ doped luminescent co-polymer was synthesized by solution free radical copolymerization. The influence of charge sequence, monomers and co-polymerized method on properties and structures of the co-polymers was studied. The emission intensity of the co-polymers at different RE3+ concentrations was tested. The results showed that the co-polymers of Eu-PSt and Eu-PMMA both had wide absorption peak at 200-400 nm and the strongest peak appeared at 235 nm. The fluorescent intensity of Eu3+ doped polystyrene co-polymer was stronger than that of Eu3+ doped PMMA copolymer. The characteristic emission of europium ions was observed in the co-polymers. The copolymer doped with rare earth elements showed the 'sensitization effect' for the central ions. The bonded-type rare earth copolymer not only enhanced the energy transfer efficiency, but also improved the fluorescence intensity by increasing the rigidity of main and side chain.
文摘A two-stage process has been developed to generate the silica-based macromonomer through surface-modification of silica with polymerizable vinyl groups. The silica surfaces were treated with excess 2,4-toluene diisocynate (TDI), after which the residual isocyanate groups were converted into polymerizable vinyl groups by reaction with hydroxypropylacrylate (HPA). Thus, polystyrene/silica nanocomposites were prepared by conventional radical copolymerization of styrene with silica macromonomer. The main effecting factors, such as ratios of styrene to the macromonomer, together with polymerization time on the copolymerization were studied in detail. FTIR, DSC and TGA were utilized to characterize the nanocomposites. Experimental results revealed that the silica nanoparticles act as cross-linking points in the polystytene/silica nanocomposites, and the glass transition temperatures of the nanocomposites are higher than that of the corresponding pure polystyrene. The glass transition temperatures of nanocomposites increased with the increasing of silica contents, which were further ascertained by DSC.
文摘A Monte Carlo method was used to take thorough account of the influences of different reactivity ratios and initial feed compositions on copolymer microstructure.The model proves the lack of azeotropic behavior in systems in which r_A>1 and r_B<1 or vice versa;it is also able to calculate the drift in the copolymer properties:copolymer composition,and randomness parameter.Moreover,for each reactivity ratio pair given,there is a unique reaction conversion,at which macromolecules produced inherit their ...
