The regional hydrological system is extremely complex because it is affected not only by physical factors but also by human dimensions.And the hydrological models play a very important role in simulating the complex s...The regional hydrological system is extremely complex because it is affected not only by physical factors but also by human dimensions.And the hydrological models play a very important role in simulating the complex system.However,there have not been effective methods for the model reliability and uncertainty analysis due to its complexity and difficulty.The uncertainties in hydrological modeling come from four important aspects：uncertainties in input data and parameters,uncertainties in model structure,uncertainties in analysis method and the initial and boundary conditions.This paper systematically reviewed the recent advances in the study of the uncertainty analysis approaches in the large-scale complex hydrological model on the basis of uncertainty sources.Also,the shortcomings and insufficiencies in the uncertainty analysis for complex hydrological models are pointed out.And then a new uncertainty quantification platform PSUADE and its uncertainty quantification methods were introduced,which will be a powerful tool and platform for uncertainty analysis of large-scale complex hydrological models.Finally,some future perspectives on uncertainty quantification are put forward.展开更多
现有基于深度学习的锂电池剩余寿命(Remaining Useful Life,RUL)预测方法中,锂电池多个内部状态所蕴含的寿命信息未得到充分考虑.鉴于此,提出了一种融合电池容量、阻抗与温度三个内部状态的RUL预测模型.首先,引入双向长短时记忆(Bi‑dire...现有基于深度学习的锂电池剩余寿命(Remaining Useful Life,RUL)预测方法中,锂电池多个内部状态所蕴含的寿命信息未得到充分考虑.鉴于此,提出了一种融合电池容量、阻抗与温度三个内部状态的RUL预测模型.首先,引入双向长短时记忆(Bi‑directional Long Short‑Term Memory,Bi‑LSTM)网络学习三种状态数据的时间相关性.其次,利用dropout技术与Bayesian变分推断技术间的等价性实现了RUL预测结果的不确定性量化,得到了预测结果的95%置信区间与概率密度分布(Probability Density Function,PDF),并分析了不同dropout率对预测不确定性的影响.最后,通过四种不同的深度学习模型框架与两种内部状态输入方案的对比实验,验证了本文方法的有效性.展开更多
Mathematical models provide a quantitative framework with which scientists can assess hypotheses on the potential underlying mechanisms that explain patterns in observed data at different spatial and temporal scales,g...Mathematical models provide a quantitative framework with which scientists can assess hypotheses on the potential underlying mechanisms that explain patterns in observed data at different spatial and temporal scales,generate estimates of key kinetic parameters,assess the impact of interventions,optimize the impact of control strategies,and generate forecasts.We review and illustrate a simple data assimilation framework for calibrating mathematical models based on ordinary differential equation models using time series data describing the temporal progression of case counts relating,for instance,to population growth or infectious disease transmission dynamics.In contrast to Bayesian estimation approaches that always raise the question of how to set priors for the parameters,this frequentist approach relies on modeling the error structure in the data.We discuss issues related to parameter identifiability,uncertainty quantification and propagation as well as model performance and forecasts along examples based on phenomenological and mechanistic models parameterized using simulated and real datasets.展开更多
工程设计中往往需要同时处理固有不确定性与认知不确定性。对于固有不确定性分析与量化,国内外已有诸多研究,例如 Monte Carlo 方法、正交多项式展开理论和概率密度演化理论等。而对认知不确定性、特别是固有不确定性与认知不确定性耦...工程设计中往往需要同时处理固有不确定性与认知不确定性。对于固有不确定性分析与量化,国内外已有诸多研究,例如 Monte Carlo 方法、正交多项式展开理论和概率密度演化理论等。而对认知不确定性、特别是固有不确定性与认知不确定性耦合情况下的研究,则还相对缺乏。该文中,针对数据稀缺与数据更新导致的认知不确定性,首先分别引入 Bootstrap 方法和 Bayes 更新方法进行不确定性表征。在此基础上,结合基于概率密度演化-测度变换的两类不确定性量化统一理论新框架,提出了存在认知不确定性情况下的不确定性传播与可靠性分析高效方法及其具体数值算法。由此,给出了基于数据进行工程系统不确定性量化、传播与可靠性分析的基本途径。通过具有工程实际数据的 3 个工程实例分析,包括无限边坡稳定性分析、挡土墙稳定性分析和屋面桁架结构可靠性分析,验证了该文方法的精度和效率。展开更多
To weaken the influence of profile error on compressor aerodynamic performance, especially on pressure ratio and efficiency, a robust design method considering profile error is built to improve the robustness of aerod...To weaken the influence of profile error on compressor aerodynamic performance, especially on pressure ratio and efficiency, a robust design method considering profile error is built to improve the robustness of aerodynamic performance of the blade. The characteristics of profile error are random and small-scaled, which means that to evaluate the influence of profile error on blade aerodynamic performance is a time-intensive and high-precision work. For this reason, non-intrusive polynomial chaos(NIPC) and Kriging surrogate model are introduced in this robust design method to improve the efficiency of uncertainty quantification(UQ) and ensure the evaluate accuracy. The profile error satisfies the Gaussian distribution, and NIPC is carried out to do uncertainty quantification since it has advantages in prediction accuracy and efficiency to get statistical behavior of random profile error. In the integrand points of NIPC, several surrogate models are established based on Latin hypercube sampling(LHS)+ Kriging, which further reduces the costs of optimization design by replacing calling computational fluid dynamic(CFD) repeatedly. The results show that this robust design method can significantly improve the performance robustness in shorter time(40 times faster) without losing accuracy, which is meaningful in engineering application to reduce manufacturing cost in the premise of ensuring the aerodynamic performance. Mechanism analysis of the robustness improvement samples carried out in current work can help find out the key parameter dominating the robustness under the disturbance of profile error, which is meaningful to further improvement of compressor robustness.展开更多
This work presents a comprehensive fourth-order predictive modeling (PM) methodology that uses the MaxEnt principle to incorporate fourth-order moments (means, covariances, skewness, kurtosis) of model parameters, com...This work presents a comprehensive fourth-order predictive modeling (PM) methodology that uses the MaxEnt principle to incorporate fourth-order moments (means, covariances, skewness, kurtosis) of model parameters, computed and measured model responses, as well as fourth (and higher) order sensitivities of computed model responses to model parameters. This new methodology is designated by the acronym 4<sup>th</sup>-BERRU-PM, which stands for “fourth-order best-estimate results with reduced uncertainties.” The results predicted by the 4<sup>th</sup>-BERRU-PM incorporates, as particular cases, the results previously predicted by the second-order predictive modeling methodology 2<sup>nd</sup>-BERRU-PM, and vastly generalizes the results produced by extant data assimilation and data adjustment procedures.展开更多
This work presents a comprehensive second-order predictive modeling (PM) methodology designated by the acronym 2<sup>nd</sup>-BERRU-PMD. The attribute “2<sup>nd</sup>” indicates that this met...This work presents a comprehensive second-order predictive modeling (PM) methodology designated by the acronym 2<sup>nd</sup>-BERRU-PMD. The attribute “2<sup>nd</sup>” indicates that this methodology incorporates second-order uncertainties (means and covariances) and second-order sensitivities of computed model responses to model parameters. The acronym BERRU stands for “Best- Estimate Results with Reduced Uncertainties” and the last letter (“D”) in the acronym indicates “deterministic,” referring to the deterministic inclusion of the computational model responses. The 2<sup>nd</sup>-BERRU-PMD methodology is fundamentally based on the maximum entropy (MaxEnt) principle. This principle is in contradistinction to the fundamental principle that underlies the extant data assimilation and/or adjustment procedures which minimize in a least-square sense a subjective user-defined functional which is meant to represent the discrepancies between measured and computed model responses. It is shown that the 2<sup>nd</sup>-BERRU-PMD methodology generalizes and extends current data assimilation and/or data adjustment procedures while overcoming the fundamental limitations of these procedures. In the accompanying work (Part II), the alternative framework for developing the “second- order MaxEnt predictive modelling methodology” is presented by incorporating probabilistically (as opposed to “deterministically”) the computed model responses.展开更多
This work presents a comprehensive second-order predictive modeling (PM) methodology based on the maximum entropy (MaxEnt) principle for obtaining best-estimate mean values and correlations for model responses and par...This work presents a comprehensive second-order predictive modeling (PM) methodology based on the maximum entropy (MaxEnt) principle for obtaining best-estimate mean values and correlations for model responses and parameters. This methodology is designated by the acronym 2<sup>nd</sup>-BERRU-PMP, where the attribute “2<sup>nd</sup>” indicates that this methodology incorporates second- order uncertainties (means and covariances) and second (and higher) order sensitivities of computed model responses to model parameters. The acronym BERRU stands for “Best-Estimate Results with Reduced Uncertainties” and the last letter (“P”) in the acronym indicates “probabilistic,” referring to the MaxEnt probabilistic inclusion of the computational model responses. This is in contradistinction to the 2<sup>nd</sup>-BERRU-PMD methodology, which deterministically combines the computed model responses with the experimental information, as presented in the accompanying work (Part I). Although both the 2<sup>nd</sup>-BERRU-PMP and the 2<sup>nd</sup>-BERRU-PMD methodologies yield expressions that include second (and higher) order sensitivities of responses to model parameters, the respective expressions for the predicted responses, for the calibrated predicted parameters and for their predicted uncertainties (covariances), are not identical to each other. Nevertheless, the results predicted by both the 2<sup>nd</sup>-BERRU-PMP and the 2<sup>nd</sup>-BERRU-PMD methodologies encompass, as particular cases, the results produced by the extant data assimilation and data adjustment procedures, which rely on the minimization, in a least-square sense, of a user-defined functional meant to represent the discrepancies between measured and computed model responses.展开更多
This work illustrates the innovative results obtained by applying the recently developed the 2<sup>nd</sup>-order predictive modeling methodology called “2<sup>nd</sup>- BERRU-PM”, where the ...This work illustrates the innovative results obtained by applying the recently developed the 2<sup>nd</sup>-order predictive modeling methodology called “2<sup>nd</sup>- BERRU-PM”, where the acronym BERRU denotes “best-estimate results with reduced uncertainties” and “PM” denotes “predictive modeling.” The physical system selected for this illustrative application is a polyethylene-reflected plutonium (acronym: PERP) OECD/NEA reactor physics benchmark. This benchmark is modeled using the neutron transport Boltzmann equation (involving 21,976 uncertain parameters), the solution of which is representative of “large-scale computations.” The results obtained in this work confirm the fact that the 2<sup>nd</sup>-BERRU-PM methodology predicts best-estimate results that fall in between the corresponding computed and measured values, while reducing the predicted standard deviations of the predicted results to values smaller than either the experimentally measured or the computed values of the respective standard deviations. The obtained results also indicate that 2<sup>nd</sup>-order response sensitivities must always be included to quantify the need for including (or not) the 3<sup>rd</sup>- and/or 4<sup>th</sup>-order sensitivities. When the parameters are known with high precision, the contributions of the higher-order sensitivities diminish with increasing order, so that the inclusion of the 1<sup>st</sup>- and 2<sup>nd</sup>-order sensitivities may suffice for obtaining accurate predicted best- estimate response values and best-estimate standard deviations. On the other hand, when the parameters’ standard deviations are sufficiently large to approach (or be outside of) the radius of convergence of the multivariate Taylor-series which represents the response in the phase-space of model parameters, the contributions stemming from the 3<sup>rd</sup>- and even 4<sup>th</sup>-order sensitivities are necessary to ensure consistency between the computed and measured response. In such cases, the use of展开更多
Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superp...Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superposition of both matrix effects and signal uncertainty directly affects plasma parameters and further influences spectral intensity and LIBS quantification performance,a data selection method based on plasma temperature matching(DSPTM)was proposed to reduce both matrix effects and signal uncertainty.By selecting spectra with smaller plasma temperature differences for all samples,the proposed method was able to build up the quantification model to rely more on spectra with smaller matrix effects and signal uncertainty,therefore improving final quantification performance.When applied to quantitative analysis of the zinc content in brass alloys,it was found that both accuracy and precision were improved using either a univariate model or multiple linear regression(MLR).More specifically,for the univariate model,the root-mean-square error of prediction(RMSEP),the determination coefficients(R^(2))and relative standard derivation(RSD)were improved from 3.30%,0.864 and 18.8%to 1.06%,0.986 and 13.5%,respectively;while for MLR,RMSEP,R^(2)and RSD were improved from 3.22%,0.871 and 26.2%to 1.07%,0.986 and 17.4%,respectively.These results prove that DSPTM can be used as an effective method to reduce matrix effects and improve repeatability by selecting reliable data.展开更多
Uncertainties in structure properties can result in different responses in hybrid simulations. Quantification of the effect of these tmcertainties would enable researchers to estimate the variances of structural respo...Uncertainties in structure properties can result in different responses in hybrid simulations. Quantification of the effect of these tmcertainties would enable researchers to estimate the variances of structural responses observed from experiments. This poses challenges for real-time hybrid simulation （RTHS） due to the existence of actuator delay. Polynomial chaos expansion （PCE） projects the model outputs on a basis of orthogonal stochastic polynomials to account for influences of model uncertainties. In this paper, PCE is utilized to evaluate effect of actuator delay on the maximum displacement from real-time hybrid simulation of a single degree of freedom （SDOF） structure when accounting for uncertainties in structural properties. The PCE is first applied for RTHS without delay to determine the order of PCE, the number of sample points as well as the method for coefficients calculation. The PCE is then applied to RTHS with actuator delay. The mean, variance and Sobol indices are compared and discussed to evaluate the effects of actuator delay on uncertainty quantification for RTHS. Results show that the mean and the variance of the maximum displacement increase linearly and exponentially with respect to actuator delay, respectively. Sensitivity analysis through Sobol indices also indicates the influence of the single random variable decreases while the coupling effect increases with the increase of actuator delay.展开更多
基金National Key Basic Research Program of China,No.2010CB428403National Grand Science and Technology Special Project of Water Pollution Control and Improvement,No.2009ZX07210-006
文摘The regional hydrological system is extremely complex because it is affected not only by physical factors but also by human dimensions.And the hydrological models play a very important role in simulating the complex system.However,there have not been effective methods for the model reliability and uncertainty analysis due to its complexity and difficulty.The uncertainties in hydrological modeling come from four important aspects：uncertainties in input data and parameters,uncertainties in model structure,uncertainties in analysis method and the initial and boundary conditions.This paper systematically reviewed the recent advances in the study of the uncertainty analysis approaches in the large-scale complex hydrological model on the basis of uncertainty sources.Also,the shortcomings and insufficiencies in the uncertainty analysis for complex hydrological models are pointed out.And then a new uncertainty quantification platform PSUADE and its uncertainty quantification methods were introduced,which will be a powerful tool and platform for uncertainty analysis of large-scale complex hydrological models.Finally,some future perspectives on uncertainty quantification are put forward.
文摘现有基于深度学习的锂电池剩余寿命(Remaining Useful Life,RUL)预测方法中,锂电池多个内部状态所蕴含的寿命信息未得到充分考虑.鉴于此,提出了一种融合电池容量、阻抗与温度三个内部状态的RUL预测模型.首先,引入双向长短时记忆(Bi‑directional Long Short‑Term Memory,Bi‑LSTM)网络学习三种状态数据的时间相关性.其次,利用dropout技术与Bayesian变分推断技术间的等价性实现了RUL预测结果的不确定性量化,得到了预测结果的95%置信区间与概率密度分布(Probability Density Function,PDF),并分析了不同dropout率对预测不确定性的影响.最后,通过四种不同的深度学习模型框架与两种内部状态输入方案的对比实验,验证了本文方法的有效性.
基金Authors acknowledge financial support from the NSF grant 1610429 and the NSF grant 1414374 as part of the joint NSFNIH-USDA Ecology and Evolution of Infectious Diseases programUK BiotechnologyBiological Sciences Research Council grant BB/M008894/1 and the Division of International Epidemiology and Population Studies,National Institutes of Health.
文摘Mathematical models provide a quantitative framework with which scientists can assess hypotheses on the potential underlying mechanisms that explain patterns in observed data at different spatial and temporal scales,generate estimates of key kinetic parameters,assess the impact of interventions,optimize the impact of control strategies,and generate forecasts.We review and illustrate a simple data assimilation framework for calibrating mathematical models based on ordinary differential equation models using time series data describing the temporal progression of case counts relating,for instance,to population growth or infectious disease transmission dynamics.In contrast to Bayesian estimation approaches that always raise the question of how to set priors for the parameters,this frequentist approach relies on modeling the error structure in the data.We discuss issues related to parameter identifiability,uncertainty quantification and propagation as well as model performance and forecasts along examples based on phenomenological and mechanistic models parameterized using simulated and real datasets.
文摘工程设计中往往需要同时处理固有不确定性与认知不确定性。对于固有不确定性分析与量化,国内外已有诸多研究,例如 Monte Carlo 方法、正交多项式展开理论和概率密度演化理论等。而对认知不确定性、特别是固有不确定性与认知不确定性耦合情况下的研究,则还相对缺乏。该文中,针对数据稀缺与数据更新导致的认知不确定性,首先分别引入 Bootstrap 方法和 Bayes 更新方法进行不确定性表征。在此基础上,结合基于概率密度演化-测度变换的两类不确定性量化统一理论新框架,提出了存在认知不确定性情况下的不确定性传播与可靠性分析高效方法及其具体数值算法。由此,给出了基于数据进行工程系统不确定性量化、传播与可靠性分析的基本途径。通过具有工程实际数据的 3 个工程实例分析,包括无限边坡稳定性分析、挡土墙稳定性分析和屋面桁架结构可靠性分析,验证了该文方法的精度和效率。
基金support of the National Natural Science Foundation of China (NSFC) under the Grant No. 51790512the Overseas Expertise Introduction Project for Discipline Innovation (111 Project) under Grant No. B17037Industry-University-Research Cooperation Project of Aero Engine Corporation of China (AECC) under Grant No. HFZL2018CXY011-1 and MIIT
文摘To weaken the influence of profile error on compressor aerodynamic performance, especially on pressure ratio and efficiency, a robust design method considering profile error is built to improve the robustness of aerodynamic performance of the blade. The characteristics of profile error are random and small-scaled, which means that to evaluate the influence of profile error on blade aerodynamic performance is a time-intensive and high-precision work. For this reason, non-intrusive polynomial chaos(NIPC) and Kriging surrogate model are introduced in this robust design method to improve the efficiency of uncertainty quantification(UQ) and ensure the evaluate accuracy. The profile error satisfies the Gaussian distribution, and NIPC is carried out to do uncertainty quantification since it has advantages in prediction accuracy and efficiency to get statistical behavior of random profile error. In the integrand points of NIPC, several surrogate models are established based on Latin hypercube sampling(LHS)+ Kriging, which further reduces the costs of optimization design by replacing calling computational fluid dynamic(CFD) repeatedly. The results show that this robust design method can significantly improve the performance robustness in shorter time(40 times faster) without losing accuracy, which is meaningful in engineering application to reduce manufacturing cost in the premise of ensuring the aerodynamic performance. Mechanism analysis of the robustness improvement samples carried out in current work can help find out the key parameter dominating the robustness under the disturbance of profile error, which is meaningful to further improvement of compressor robustness.
文摘This work presents a comprehensive fourth-order predictive modeling (PM) methodology that uses the MaxEnt principle to incorporate fourth-order moments (means, covariances, skewness, kurtosis) of model parameters, computed and measured model responses, as well as fourth (and higher) order sensitivities of computed model responses to model parameters. This new methodology is designated by the acronym 4<sup>th</sup>-BERRU-PM, which stands for “fourth-order best-estimate results with reduced uncertainties.” The results predicted by the 4<sup>th</sup>-BERRU-PM incorporates, as particular cases, the results previously predicted by the second-order predictive modeling methodology 2<sup>nd</sup>-BERRU-PM, and vastly generalizes the results produced by extant data assimilation and data adjustment procedures.
文摘This work presents a comprehensive second-order predictive modeling (PM) methodology designated by the acronym 2<sup>nd</sup>-BERRU-PMD. The attribute “2<sup>nd</sup>” indicates that this methodology incorporates second-order uncertainties (means and covariances) and second-order sensitivities of computed model responses to model parameters. The acronym BERRU stands for “Best- Estimate Results with Reduced Uncertainties” and the last letter (“D”) in the acronym indicates “deterministic,” referring to the deterministic inclusion of the computational model responses. The 2<sup>nd</sup>-BERRU-PMD methodology is fundamentally based on the maximum entropy (MaxEnt) principle. This principle is in contradistinction to the fundamental principle that underlies the extant data assimilation and/or adjustment procedures which minimize in a least-square sense a subjective user-defined functional which is meant to represent the discrepancies between measured and computed model responses. It is shown that the 2<sup>nd</sup>-BERRU-PMD methodology generalizes and extends current data assimilation and/or data adjustment procedures while overcoming the fundamental limitations of these procedures. In the accompanying work (Part II), the alternative framework for developing the “second- order MaxEnt predictive modelling methodology” is presented by incorporating probabilistically (as opposed to “deterministically”) the computed model responses.
文摘This work presents a comprehensive second-order predictive modeling (PM) methodology based on the maximum entropy (MaxEnt) principle for obtaining best-estimate mean values and correlations for model responses and parameters. This methodology is designated by the acronym 2<sup>nd</sup>-BERRU-PMP, where the attribute “2<sup>nd</sup>” indicates that this methodology incorporates second- order uncertainties (means and covariances) and second (and higher) order sensitivities of computed model responses to model parameters. The acronym BERRU stands for “Best-Estimate Results with Reduced Uncertainties” and the last letter (“P”) in the acronym indicates “probabilistic,” referring to the MaxEnt probabilistic inclusion of the computational model responses. This is in contradistinction to the 2<sup>nd</sup>-BERRU-PMD methodology, which deterministically combines the computed model responses with the experimental information, as presented in the accompanying work (Part I). Although both the 2<sup>nd</sup>-BERRU-PMP and the 2<sup>nd</sup>-BERRU-PMD methodologies yield expressions that include second (and higher) order sensitivities of responses to model parameters, the respective expressions for the predicted responses, for the calibrated predicted parameters and for their predicted uncertainties (covariances), are not identical to each other. Nevertheless, the results predicted by both the 2<sup>nd</sup>-BERRU-PMP and the 2<sup>nd</sup>-BERRU-PMD methodologies encompass, as particular cases, the results produced by the extant data assimilation and data adjustment procedures, which rely on the minimization, in a least-square sense, of a user-defined functional meant to represent the discrepancies between measured and computed model responses.
文摘This work illustrates the innovative results obtained by applying the recently developed the 2<sup>nd</sup>-order predictive modeling methodology called “2<sup>nd</sup>- BERRU-PM”, where the acronym BERRU denotes “best-estimate results with reduced uncertainties” and “PM” denotes “predictive modeling.” The physical system selected for this illustrative application is a polyethylene-reflected plutonium (acronym: PERP) OECD/NEA reactor physics benchmark. This benchmark is modeled using the neutron transport Boltzmann equation (involving 21,976 uncertain parameters), the solution of which is representative of “large-scale computations.” The results obtained in this work confirm the fact that the 2<sup>nd</sup>-BERRU-PM methodology predicts best-estimate results that fall in between the corresponding computed and measured values, while reducing the predicted standard deviations of the predicted results to values smaller than either the experimentally measured or the computed values of the respective standard deviations. The obtained results also indicate that 2<sup>nd</sup>-order response sensitivities must always be included to quantify the need for including (or not) the 3<sup>rd</sup>- and/or 4<sup>th</sup>-order sensitivities. When the parameters are known with high precision, the contributions of the higher-order sensitivities diminish with increasing order, so that the inclusion of the 1<sup>st</sup>- and 2<sup>nd</sup>-order sensitivities may suffice for obtaining accurate predicted best- estimate response values and best-estimate standard deviations. On the other hand, when the parameters’ standard deviations are sufficiently large to approach (or be outside of) the radius of convergence of the multivariate Taylor-series which represents the response in the phase-space of model parameters, the contributions stemming from the 3<sup>rd</sup>- and even 4<sup>th</sup>-order sensitivities are necessary to ensure consistency between the computed and measured response. In such cases, the use of
基金financial support from the Scientific Research Program for Young Talents of China National Nuclear Corporation(2020)National Natural Science Foundation of China(Nos.51906124 and 62205172)+1 种基金Shanxi Province Science and Technology Department(No.20201101013)Guoneng Bengbu Power Generation Co.,Ltd(No.20212000001)。
文摘Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superposition of both matrix effects and signal uncertainty directly affects plasma parameters and further influences spectral intensity and LIBS quantification performance,a data selection method based on plasma temperature matching(DSPTM)was proposed to reduce both matrix effects and signal uncertainty.By selecting spectra with smaller plasma temperature differences for all samples,the proposed method was able to build up the quantification model to rely more on spectra with smaller matrix effects and signal uncertainty,therefore improving final quantification performance.When applied to quantitative analysis of the zinc content in brass alloys,it was found that both accuracy and precision were improved using either a univariate model or multiple linear regression(MLR).More specifically,for the univariate model,the root-mean-square error of prediction(RMSEP),the determination coefficients(R^(2))and relative standard derivation(RSD)were improved from 3.30%,0.864 and 18.8%to 1.06%,0.986 and 13.5%,respectively;while for MLR,RMSEP,R^(2)and RSD were improved from 3.22%,0.871 and 26.2%to 1.07%,0.986 and 17.4%,respectively.These results prove that DSPTM can be used as an effective method to reduce matrix effects and improve repeatability by selecting reliable data.
基金National Science Foundation of China under grant No.51378107Fundamental Research Funds for the Central Universities and Doctoral Research Fund by Southeast University under Grant No.YBJJ-1442
文摘Uncertainties in structure properties can result in different responses in hybrid simulations. Quantification of the effect of these tmcertainties would enable researchers to estimate the variances of structural responses observed from experiments. This poses challenges for real-time hybrid simulation （RTHS） due to the existence of actuator delay. Polynomial chaos expansion （PCE） projects the model outputs on a basis of orthogonal stochastic polynomials to account for influences of model uncertainties. In this paper, PCE is utilized to evaluate effect of actuator delay on the maximum displacement from real-time hybrid simulation of a single degree of freedom （SDOF） structure when accounting for uncertainties in structural properties. The PCE is first applied for RTHS without delay to determine the order of PCE, the number of sample points as well as the method for coefficients calculation. The PCE is then applied to RTHS with actuator delay. The mean, variance and Sobol indices are compared and discussed to evaluate the effects of actuator delay on uncertainty quantification for RTHS. Results show that the mean and the variance of the maximum displacement increase linearly and exponentially with respect to actuator delay, respectively. Sensitivity analysis through Sobol indices also indicates the influence of the single random variable decreases while the coupling effect increases with the increase of actuator delay.
