Predispersed solvent extraction (PDSE) is a new method for separating solutes from aqueous solution by solvent extraction and one which has shown promise for extraction from extremely dilute solution very efficient an...Predispersed solvent extraction (PDSE) is a new method for separating solutes from aqueous solution by solvent extraction and one which has shown promise for extraction from extremely dilute solution very efficient and very quick. The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interfacial mass transfer and low interfacial mass transfer areas in solvent extraction process. In present paper, colloidal liquid aphrons are successfully generated using kerosene as a solvent, tributyl phosphate(TBP) as an extractant, sodium dodecyl benzene sulphate(SDBS) as surfactant in aqueous phase and Tween-80 in oil phase. Extraction of phenol from dilute solution was studied by using colloidal liquid aphrons and colloidal gas aphrons in a semi-batch extraction column. It has been found that the PDSE process is more suitable for extraction of dilute solutions. It has also been discovered that the PDSE process has a great advantage over traditional single-stage extraction process.展开更多
Predispersed solvent extraction (PDSE) is a new extraction technique in which one of the two phases (usually the oil phase) is predispersed into minute droplets. The essential part of this novel technique is the use o...Predispersed solvent extraction (PDSE) is a new extraction technique in which one of the two phases (usually the oil phase) is predispersed into minute droplets. The essential part of this novel technique is the use of colloidal liquid aphrons (CLA) together with colloidal gas aphrons (CGA). The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interfacial mass transfer etc. In this paper, PDSE process, CLA and CGA are systematically reviewed and the potential applications of CLA, CGA and PDSE for the various areas of separation as well as the latest development in this area are discussed.展开更多
The extraction experiments of chromium（W） from aqueous waste solution by predispersed solvent extraction （PDSE） process with extractant （HEHPEHE） and its mixture, including acidic extractant （D2EHPA）, alkaline...The extraction experiments of chromium（W） from aqueous waste solution by predispersed solvent extraction （PDSE） process with extractant （HEHPEHE） and its mixture, including acidic extractant （D2EHPA）, alkaline extractant （TOA） and neutral extractant （TBP） were carried out respectively. It is found that the extractant HEHPEHE exhibited high extraction selectivity to chromium（III） from aqueous waste solution. The colloidal liquid aphrons （CLAs） were successfully generated using kerosene as a solvent, HEHPEHE as an extractant, sodium dodecyl benzene sulphate （SDBS） as a surfactant in aqueous phase and polyoxyethylene sorbitol anhydride monolaurate （Tween-20） in oil phase. To study the extraction efficiency and advantages of the PDSE process in the removal of chromium（III）, the effects of major factors, such as initial chromium（III） concentration, volume of colloidal gas aphrons （CGAs）, HEHPEHE volume fraction, phase ratio （solvent phase to water phase）, mass fraction of dodecyl trimethylammonium bromide （HTAB）, mass fraction of SDBS, mass fraction of Tween-20 and initial pH of aqueous waste solution were also investigated and the appropriate process conditions were obtained. Under the appropriate conditions, the extraction efficiency of chromium（III） above 99.9 % can be achieved and the treated aqueous waste solution can be discharged directly without polluting the environment.展开更多
Aims Several mechanistic hypotheses have been developed to explain the existence of alpine treelines worldwide.The reproduction limita-tion hypothesis(RLH)postulates that reproductive processes such as seed production...Aims Several mechanistic hypotheses have been developed to explain the existence of alpine treelines worldwide.The reproduction limita-tion hypothesis(RLH)postulates that reproductive processes such as seed production and dispersal are restricted in treeline envi-ronments,thereby limiting the establishment of new individuals in advance of extant treelines.Despite its popularity,no study has tested this hypothesis in a comprehensive fashion.In this experi-ment,we attempted to answer whether there are enough viable seeds being dispersed beyond treeline for sexually mediated tree-line advance,and what the implications of climate change might be on these processes.Methods We established 30 plots across two aspects(north vs.south)and three elevational habitats(forest,treeline and tundra)in a white spruce(Picea glauca)boreal forest-alpine tundra ecotone in south-west Yukon,Canada.In each plot,tree characteristics,seed produc-tion and predispersal damage were measured.Additionally,eight dispersal trays were positioned in each plot to measure seed rain,and germination trials with and without predation exclosures were constructed in a subset of plots to quantify dispersal and germina-tion success.Important Findings Results were highly variable both temporally and spatially.In 2014,a mast year,69%of adult trees produced cones compared to 0.4%in the following year.Higher density of trees in forest plots compared to treeline and tundra resulted in greater seed production at lower elevations.Across all plots,88%of seeds were damaged before dispersal or were not viable.Treeline plots had significantly greater predispersal damage.Seed rain was greater in south-facing plots than north-facing plots.Less than 2%of seeds produced on the landscape were dispersed into Tundra plots,located 50 m above treeline.There was a net movement of seeds from the north-facing slope to the south at our study site,likely due to prevailing winds during the dispersal period.Germination counts were more than double on north-facing slopes and one-third展开更多
Plant-insect interactions are key model systems to assess how some species affect the distribution, the abundance, and the evolution of others. Tree reproductive structures represent a critical resource for many insec...Plant-insect interactions are key model systems to assess how some species affect the distribution, the abundance, and the evolution of others. Tree reproductive structures represent a critical resource for many insect species, which can be likely drivers of demography, spatial distribution, and trait diversification of plants. In this review, we present the ecological implications of predispersal herbivory on tree reproductive structures by insects (PIHR) in forest ecosystems. Both insect's and tree's perspectives are addressed with an emphasis on how spatiotemporal variation and unpredictability in seed availability can shape such particular plant-animal interactions. Reproductive structure insects show strong trophic specialization and guild diversification. Insects evolved host selection and spatiotemporal dispersal strategies in response to variable and unpredictable abundance of reproductive structures in both space and time. If PIHR patterns have been well documented in numerous systems, evidences of the subsequent demographic and evolutionary impacts on tree populations are still constrained by time-scale challenges of experimenting on such long-lived organisms, and modeling approaches of tree dynamics rarely consider PIHR when including biotic interactions in their processes. We suggest that spatially explicit and mechanistic approaches of the interactions between individual tree fecundity and in sect dynamics will clarify predictions of the demogenetic implications of PIHR in tree populations. In a global change context, further experimental and theoretical contributions to the likelihood of life-cycle disruptions between plants and their specialized herbivores, and to how these changes may gen erate novel dynamic patterns in each partner of the interaction are increasingly critical.展开更多
对比4种预分散间苯二酚在半钢子午线轮胎钢丝带束层胶中的应用效果。结果表明,预分散间苯二酚 E 80在终炼时加入,不但可以避免间苯二酚在生产过程中因挥发而产生大量烟雾,而且可以改善胶料的分散性,提高胶料与钢丝帘线的粘合性能,... 对比4种预分散间苯二酚在半钢子午线轮胎钢丝带束层胶中的应用效果。结果表明,预分散间苯二酚 E 80在终炼时加入,不但可以避免间苯二酚在生产过程中因挥发而产生大量烟雾,而且可以改善胶料的分散性,提高胶料与钢丝帘线的粘合性能,所制造的145R12LT成品轮胎的耐久性能和高速性能均超过国家标准;以其减量替代预分散间苯二酚DCOF 50,可降低胶料成本约0 29元·kg-1。展开更多
基金Supported by the National Natural Science Foundation of China(No.29676021 and No.29836130)
文摘Predispersed solvent extraction (PDSE) is a new method for separating solutes from aqueous solution by solvent extraction and one which has shown promise for extraction from extremely dilute solution very efficient and very quick. The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interfacial mass transfer and low interfacial mass transfer areas in solvent extraction process. In present paper, colloidal liquid aphrons are successfully generated using kerosene as a solvent, tributyl phosphate(TBP) as an extractant, sodium dodecyl benzene sulphate(SDBS) as surfactant in aqueous phase and Tween-80 in oil phase. Extraction of phenol from dilute solution was studied by using colloidal liquid aphrons and colloidal gas aphrons in a semi-batch extraction column. It has been found that the PDSE process is more suitable for extraction of dilute solutions. It has also been discovered that the PDSE process has a great advantage over traditional single-stage extraction process.
基金Supported by National Natural Science Foundation of China(No. 29676021 and No. 29836130 ).
文摘Predispersed solvent extraction (PDSE) is a new extraction technique in which one of the two phases (usually the oil phase) is predispersed into minute droplets. The essential part of this novel technique is the use of colloidal liquid aphrons (CLA) together with colloidal gas aphrons (CGA). The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interfacial mass transfer etc. In this paper, PDSE process, CLA and CGA are systematically reviewed and the potential applications of CLA, CGA and PDSE for the various areas of separation as well as the latest development in this area are discussed.
基金Project (NCET-07-0577) supported by New Century Excellent Talents of Ministry of Education, China
文摘The extraction experiments of chromium（W） from aqueous waste solution by predispersed solvent extraction （PDSE） process with extractant （HEHPEHE） and its mixture, including acidic extractant （D2EHPA）, alkaline extractant （TOA） and neutral extractant （TBP） were carried out respectively. It is found that the extractant HEHPEHE exhibited high extraction selectivity to chromium（III） from aqueous waste solution. The colloidal liquid aphrons （CLAs） were successfully generated using kerosene as a solvent, HEHPEHE as an extractant, sodium dodecyl benzene sulphate （SDBS） as a surfactant in aqueous phase and polyoxyethylene sorbitol anhydride monolaurate （Tween-20） in oil phase. To study the extraction efficiency and advantages of the PDSE process in the removal of chromium（III）, the effects of major factors, such as initial chromium（III） concentration, volume of colloidal gas aphrons （CGAs）, HEHPEHE volume fraction, phase ratio （solvent phase to water phase）, mass fraction of dodecyl trimethylammonium bromide （HTAB）, mass fraction of SDBS, mass fraction of Tween-20 and initial pH of aqueous waste solution were also investigated and the appropriate process conditions were obtained. Under the appropriate conditions, the extraction efficiency of chromium（III） above 99.9 % can be achieved and the treated aqueous waste solution can be discharged directly without polluting the environment.
文摘Aims Several mechanistic hypotheses have been developed to explain the existence of alpine treelines worldwide.The reproduction limita-tion hypothesis(RLH)postulates that reproductive processes such as seed production and dispersal are restricted in treeline envi-ronments,thereby limiting the establishment of new individuals in advance of extant treelines.Despite its popularity,no study has tested this hypothesis in a comprehensive fashion.In this experi-ment,we attempted to answer whether there are enough viable seeds being dispersed beyond treeline for sexually mediated tree-line advance,and what the implications of climate change might be on these processes.Methods We established 30 plots across two aspects(north vs.south)and three elevational habitats(forest,treeline and tundra)in a white spruce(Picea glauca)boreal forest-alpine tundra ecotone in south-west Yukon,Canada.In each plot,tree characteristics,seed produc-tion and predispersal damage were measured.Additionally,eight dispersal trays were positioned in each plot to measure seed rain,and germination trials with and without predation exclosures were constructed in a subset of plots to quantify dispersal and germina-tion success.Important Findings Results were highly variable both temporally and spatially.In 2014,a mast year,69%of adult trees produced cones compared to 0.4%in the following year.Higher density of trees in forest plots compared to treeline and tundra resulted in greater seed production at lower elevations.Across all plots,88%of seeds were damaged before dispersal or were not viable.Treeline plots had significantly greater predispersal damage.Seed rain was greater in south-facing plots than north-facing plots.Less than 2%of seeds produced on the landscape were dispersed into Tundra plots,located 50 m above treeline.There was a net movement of seeds from the north-facing slope to the south at our study site,likely due to prevailing winds during the dispersal period.Germination counts were more than double on north-facing slopes and one-third
文摘Plant-insect interactions are key model systems to assess how some species affect the distribution, the abundance, and the evolution of others. Tree reproductive structures represent a critical resource for many insect species, which can be likely drivers of demography, spatial distribution, and trait diversification of plants. In this review, we present the ecological implications of predispersal herbivory on tree reproductive structures by insects (PIHR) in forest ecosystems. Both insect's and tree's perspectives are addressed with an emphasis on how spatiotemporal variation and unpredictability in seed availability can shape such particular plant-animal interactions. Reproductive structure insects show strong trophic specialization and guild diversification. Insects evolved host selection and spatiotemporal dispersal strategies in response to variable and unpredictable abundance of reproductive structures in both space and time. If PIHR patterns have been well documented in numerous systems, evidences of the subsequent demographic and evolutionary impacts on tree populations are still constrained by time-scale challenges of experimenting on such long-lived organisms, and modeling approaches of tree dynamics rarely consider PIHR when including biotic interactions in their processes. We suggest that spatially explicit and mechanistic approaches of the interactions between individual tree fecundity and in sect dynamics will clarify predictions of the demogenetic implications of PIHR in tree populations. In a global change context, further experimental and theoretical contributions to the likelihood of life-cycle disruptions between plants and their specialized herbivores, and to how these changes may gen erate novel dynamic patterns in each partner of the interaction are increasingly critical.
