Gaomiaozi(GMZ)bentonite is a potential buffer/backfill material for a deep geological disposal of highlevel radioactive waste.It has a wide pore size distribution(PSD)with sizes ranging from several nanometers to more...Gaomiaozi(GMZ)bentonite is a potential buffer/backfill material for a deep geological disposal of highlevel radioactive waste.It has a wide pore size distribution(PSD)with sizes ranging from several nanometers to more than one hundred microns.Thus,properly characterizing the pore structures of GMZ bentonite is a challenging issue.In this study,pressure-controlled porosimetry(PCP),ratecontrolled porosimetry(RCP),and scanning electron microscopy(SEM)were used to investigate the PSD of GMZ bentonite,The results indicate that each method has its limitation,and a combined use of PCP and RCP is suitable to obtain the full-scale PSD of GMZ bentonite.Moreover,we also compared the full-scale PSD with nuclear magnetic resonance(NMR)result.It is found that there is no significant difference in the range of PSD characterization between NMR and mercury intrusion method(PCP and RCP).However,in a ce rtain range,the detection accuracy of NMR is higher than that of mercury injection method.Finally,permeability prediction based on PCP and SEM data was conducted,and both of the two methods were found to be able to predict the permeability.The combined method is effective to obtain the full-scale PSD of GMZ bentonite,which is the key to estimation of the sealing ability of bentonite buffer.展开更多
Inundation of the Three Gorges Reservoir has created a 30-m water-level fluctuation zone with seasonal hydrological alternations of submergence and exposure, which may greatly affect soil properties and bank stability...Inundation of the Three Gorges Reservoir has created a 30-m water-level fluctuation zone with seasonal hydrological alternations of submergence and exposure, which may greatly affect soil properties and bank stability. The aim of this study was to investigate the response of soil pore structure to seasonal water-level fluctuation in the reservoir, and particularly, the hydrological change of wetting and drying cycles. Soil pore structure was visualized with industrial X-ray computed tomography and digital image analysis techniques. The results showed that soil total porosity(? 100 ?m), total pore number, total throat number, and mean throat surface area increased significantly under wetting and drying cycles. Soil porosity, pore number and throat numberwithin each size class increased in the course of wetting and drying cycles. The coordination number, degree of anisotropy and fractal dimension were indicating an increase. In contrast, the mean shape factor, pore-throat ratio, and Euler-Poincaré number decreased due to wetting and drying cycles. These illustrated that the wetting and drying cycles made soil pore structure become more porous, continuous, heterogeneous and complex. It can thus be deduced that the water-level fluctuation would modify soil porosity, pore size distribution, and pore morphology in the Three Gorges Reservoir, which may have profound implications for soil processes, soil functions, and bank stability.展开更多
Nitrogen huff-n-puff(N_(2)HnP) appears to be an economical and high-efficiency enhanced oil recovery(EOR) technique for tight oil reservoirs.There is however a lack of understanding of the pore-level EOR performance o...Nitrogen huff-n-puff(N_(2)HnP) appears to be an economical and high-efficiency enhanced oil recovery(EOR) technique for tight oil reservoirs.There is however a lack of understanding of the pore-level EOR performance of N2HnP under tight reservoir conditions.In this work,a non-magnetic reactor was created and combined with a nuclear magnetic resonance(NMR) device for real-time monitoring of oil distribution in the HnP experiment.N_(2)HnP experiments were then performed in a tight sandstone core sample at a temperature of 353 K and an injection pressure≥ 24 MPa.The pore-level oil distribution under reservoir conditions was monitored and the EOR performance of N2HnP in specific pores was analyzed.The pore throat structures of the core sample and the phase behavior of the N_(2)-Oil system were analyzed to elucidate the EOR mechanism of N_(2)HnP.An oil recovery factor of 37.52% can be achieved after four cycles,which proves the EOR potential of N_(2)HnP for tight reservoirs.The highest recoveries after N_(2)HnP are obtained in the large pores,followed by the medium pores,the small pores,and finally the micro pores.Increases in soaking time and injection pressure resulted in slight and pronounced increases in oil recovery,respectively,both of which are mainly reflected in the first cycle.Specifically,increasing the soaking time only slightly improves the cumulative oil recovery in the small pores while increasing the injection pressure significantly improves the cumulative oil recovery in the small,medium,and large pores simultaneously.However,variations in both injection pressure and soaking time have a negligible effect on the cumulative oil recovery of the micro pores.展开更多
Shale gas reservoirs are found all over the world.Their endowment worldwide is estimated at 10,000 tcf by the GFREE team in the Schulich School of Engineering at the University of Calgary.The shale gas work and produc...Shale gas reservoirs are found all over the world.Their endowment worldwide is estimated at 10,000 tcf by the GFREE team in the Schulich School of Engineering at the University of Calgary.The shale gas work and production initiated successfully in the Unites States and extended to Canada will have application,with modifications,in several other countries in the future.The‘modifications’qualifier is important as each shale gas reservoir should be considered as a research project by itself to avoid fiascos and major financial losses.Shale gas reservoirs are best represented by at least quadruple porosity models.Some of the production obtained from shale reservoirs is dominated by diffusion flow.The approximate boundary between viscous and diffusion-like flow is estimated with Knudsen number.Viscous flow is present,for example,when the architecture of the rock is dominated by mega pore throat,macro pore throat,meso pore throat and sometimes micro pore throat.Diffusion flow on the other hand is observed at the nano pore throat level.The process speed concept has been used successfully in conventional reservoirs for several decades.However,the concept discussed in this paper for tight gas and shale gas reservoirs,with the support of core data,has been developed only recently,and permits differentiating between viscous and diffusion dominated flow.This is valuable,for example,in those cases where the formation to be developed is composed of alternating stacked layers of tight sands and shales,or where there are lateral variations due to facies changes.An approach to develop the concept of a super-giant shale gas reservoir is presented as well as a description of GFREE,a successful research program for tight formations.The paper closes with examples of detailed original gas-in-place(OGIP)calculations for 3 North American shale gas reservoirs including free gas in natural fractures and the porous network within the organic matter,gas in the non-organic matter,adsorbed gas,and estimates of free gas within fractures cr展开更多
Pore structure of porous media, including pore size and topology, is rather complex. In immiscible twophase displacement process, the capillary force affected by pore size dominates the two-phase flow in the porous me...Pore structure of porous media, including pore size and topology, is rather complex. In immiscible twophase displacement process, the capillary force affected by pore size dominates the two-phase flow in the porous media, affecting displacement results. Direct observation of the flow patterns in the porous media is difficult, and therefore knowledge about the two-phase displacement flow is insufficient. In this paper, a two-dimensional(2D) pore structure was extracted from a sandstone sample, and the flow process that CO_2 displaces resident brine in the extracted pore structure was simulated using the Navier eStokes equation combined with the conservative level set method. The simulation results reveal that the pore throat is a crucial factor for determining CO_2 displacement process in the porous media. The two-phase meniscuses in each pore throat were in a self-adjusting process. In the displacement process,CO_2 preferentially broke through the maximum pore throat. Before breaking through the maximum pore throat, the pressure of CO_2 continually increased, and the curvature and position of two-phase interfaces in the other pore throats adjusted accordingly. Once the maximum pore throat was broken through by the CO_2, the capillary force in the other pore throats released accordingly; subsequently, the interfaces withdrew under the effect of capillary fore, preparing for breaking through the next pore throat.Therefore, the two-phase displacement in CO_2 injection is accompanied by the breaking through and adjusting of the two-phase interfaces.展开更多
Bangladesh is a south Asian Monsoonal Country and the recent precipitation pattern in the Cox’s Bazar area of Bangladesh is changing and increasing the number of monsoonal slope failures and landslide hazards in the ...Bangladesh is a south Asian Monsoonal Country and the recent precipitation pattern in the Cox’s Bazar area of Bangladesh is changing and increasing the number of monsoonal slope failures and landslide hazards in the Kutubpalong & Balukhali Rohingya camp area. An attempt has been made to see the influence of seasonal variation of ground water level (G.W.L.) fluctuations on the stability of the eco hills and forests of Ukhiya Teknaf region. Ukhiya hills are in great danger because of cutting trees from the hill slopes and it is well established that due to recent change of climate, short term rainfall for few consecutive days during monsoon might show an influence on the factor of safety (Fs) values of the camp hill slopes. A clear G.W.L. variation between dry and wet seasons has an influence on the stability (Fs) values indicating that climate has a strong influence on the stability and threatening sustainable development. A stable or marginally stable slope might be unstable during raining and show a variation of ground water level (G.W.L.). The generation of pore water pressure (P.W.P.) is also influenced by seasonal variation of ground water level. During wet season negative P.W.P. called suction plays an important role to occur slope failures in the Ukhiya hills. Based on all calculated factor of safety values (Fs) at different locations, four (4) susceptible landslide risk zones are identified. They are very high risk (Fs = 0.18 to 0.46), high risk (Fs = 0.56 to 0.75), medium risk (Fs = 0.76 to 1.0) and marginally stable areas (Fs ≈ 1). Proper geo-engineering measures must be taken by the concerned authorizes to reduce P.W.P. during monsoon by installing rain water harvesting system, allowing sufficient drainage & other geotechnical measures to reduce the risk of slope failures in the Ukhiya hills. Based on the stability factor (Fs) at different slope locations of the camp hills, a risk map of the investigated area has been produced for the local community for their safety and to build up awareness & to m展开更多
基金support of the National Natural Science Foundation of China(Grant Nos.51809263)the Open Fund of Key Laboratory of Deep Earth Science and Engineering(Sichuan University)(Grant Nos.DESE201906 and DESE201907)。
文摘Gaomiaozi(GMZ)bentonite is a potential buffer/backfill material for a deep geological disposal of highlevel radioactive waste.It has a wide pore size distribution(PSD)with sizes ranging from several nanometers to more than one hundred microns.Thus,properly characterizing the pore structures of GMZ bentonite is a challenging issue.In this study,pressure-controlled porosimetry(PCP),ratecontrolled porosimetry(RCP),and scanning electron microscopy(SEM)were used to investigate the PSD of GMZ bentonite,The results indicate that each method has its limitation,and a combined use of PCP and RCP is suitable to obtain the full-scale PSD of GMZ bentonite.Moreover,we also compared the full-scale PSD with nuclear magnetic resonance(NMR)result.It is found that there is no significant difference in the range of PSD characterization between NMR and mercury intrusion method(PCP and RCP).However,in a ce rtain range,the detection accuracy of NMR is higher than that of mercury injection method.Finally,permeability prediction based on PCP and SEM data was conducted,and both of the two methods were found to be able to predict the permeability.The combined method is effective to obtain the full-scale PSD of GMZ bentonite,which is the key to estimation of the sealing ability of bentonite buffer.
基金funded by the National Natural Science Foundation of China(Grant No.41771321,41771320 and 41571278)Sichuan Science and Technology Program(Grant No.2018SZ0132)
文摘Inundation of the Three Gorges Reservoir has created a 30-m water-level fluctuation zone with seasonal hydrological alternations of submergence and exposure, which may greatly affect soil properties and bank stability. The aim of this study was to investigate the response of soil pore structure to seasonal water-level fluctuation in the reservoir, and particularly, the hydrological change of wetting and drying cycles. Soil pore structure was visualized with industrial X-ray computed tomography and digital image analysis techniques. The results showed that soil total porosity(? 100 ?m), total pore number, total throat number, and mean throat surface area increased significantly under wetting and drying cycles. Soil porosity, pore number and throat numberwithin each size class increased in the course of wetting and drying cycles. The coordination number, degree of anisotropy and fractal dimension were indicating an increase. In contrast, the mean shape factor, pore-throat ratio, and Euler-Poincaré number decreased due to wetting and drying cycles. These illustrated that the wetting and drying cycles made soil pore structure become more porous, continuous, heterogeneous and complex. It can thus be deduced that the water-level fluctuation would modify soil porosity, pore size distribution, and pore morphology in the Three Gorges Reservoir, which may have profound implications for soil processes, soil functions, and bank stability.
基金financial support from the National Natural Science Foundation of China(52074319)the Strategic Cooperation Technology Project of CNPC(ZLZX2020-01-08)the Science Foundation of China University of Petroleum-Beijing(2462021QNXZ008)
文摘Nitrogen huff-n-puff(N_(2)HnP) appears to be an economical and high-efficiency enhanced oil recovery(EOR) technique for tight oil reservoirs.There is however a lack of understanding of the pore-level EOR performance of N2HnP under tight reservoir conditions.In this work,a non-magnetic reactor was created and combined with a nuclear magnetic resonance(NMR) device for real-time monitoring of oil distribution in the HnP experiment.N_(2)HnP experiments were then performed in a tight sandstone core sample at a temperature of 353 K and an injection pressure≥ 24 MPa.The pore-level oil distribution under reservoir conditions was monitored and the EOR performance of N2HnP in specific pores was analyzed.The pore throat structures of the core sample and the phase behavior of the N_(2)-Oil system were analyzed to elucidate the EOR mechanism of N_(2)HnP.An oil recovery factor of 37.52% can be achieved after four cycles,which proves the EOR potential of N_(2)HnP for tight reservoirs.The highest recoveries after N_(2)HnP are obtained in the large pores,followed by the medium pores,the small pores,and finally the micro pores.Increases in soaking time and injection pressure resulted in slight and pronounced increases in oil recovery,respectively,both of which are mainly reflected in the first cycle.Specifically,increasing the soaking time only slightly improves the cumulative oil recovery in the small pores while increasing the injection pressure significantly improves the cumulative oil recovery in the small,medium,and large pores simultaneously.However,variations in both injection pressure and soaking time have a negligible effect on the cumulative oil recovery of the micro pores.
基金Parts of this work were funded by the Natural Sciences and Engineering Research Council of Canada(NSERC agreement 347825-06)ConocoPhillips(agreement 4204638)+2 种基金Alberta Innovates Energy and Environment Solutions(AERI agreement 1711)the Schulich School of Engineering at the University of Calgary and Servipetrol Ltd.Porosities and permeabilities from Nikanassin drill cuttings were determined by Nisael Solano of the University of Calgary using Darcylog equipment provided by Mr.Roland Lenormand of Cydarex in Paris,FranceThe 3D hydraulic fracturing simulation was performed using GOHFER,contributed to the GFREE Research program by R.D.Barree of B&A and Kevin Svatek of Core Lab.
文摘Shale gas reservoirs are found all over the world.Their endowment worldwide is estimated at 10,000 tcf by the GFREE team in the Schulich School of Engineering at the University of Calgary.The shale gas work and production initiated successfully in the Unites States and extended to Canada will have application,with modifications,in several other countries in the future.The‘modifications’qualifier is important as each shale gas reservoir should be considered as a research project by itself to avoid fiascos and major financial losses.Shale gas reservoirs are best represented by at least quadruple porosity models.Some of the production obtained from shale reservoirs is dominated by diffusion flow.The approximate boundary between viscous and diffusion-like flow is estimated with Knudsen number.Viscous flow is present,for example,when the architecture of the rock is dominated by mega pore throat,macro pore throat,meso pore throat and sometimes micro pore throat.Diffusion flow on the other hand is observed at the nano pore throat level.The process speed concept has been used successfully in conventional reservoirs for several decades.However,the concept discussed in this paper for tight gas and shale gas reservoirs,with the support of core data,has been developed only recently,and permits differentiating between viscous and diffusion dominated flow.This is valuable,for example,in those cases where the formation to be developed is composed of alternating stacked layers of tight sands and shales,or where there are lateral variations due to facies changes.An approach to develop the concept of a super-giant shale gas reservoir is presented as well as a description of GFREE,a successful research program for tight formations.The paper closes with examples of detailed original gas-in-place(OGIP)calculations for 3 North American shale gas reservoirs including free gas in natural fractures and the porous network within the organic matter,gas in the non-organic matter,adsorbed gas,and estimates of free gas within fractures cr
基金funded by Key Laboratory of Coal-based CO_2 Capture and Geological Storage,Jiangsu Province,ChinaUS Advanced Coal Technology Consortium(No.2013 DFB60140-08)
文摘Pore structure of porous media, including pore size and topology, is rather complex. In immiscible twophase displacement process, the capillary force affected by pore size dominates the two-phase flow in the porous media, affecting displacement results. Direct observation of the flow patterns in the porous media is difficult, and therefore knowledge about the two-phase displacement flow is insufficient. In this paper, a two-dimensional(2D) pore structure was extracted from a sandstone sample, and the flow process that CO_2 displaces resident brine in the extracted pore structure was simulated using the Navier eStokes equation combined with the conservative level set method. The simulation results reveal that the pore throat is a crucial factor for determining CO_2 displacement process in the porous media. The two-phase meniscuses in each pore throat were in a self-adjusting process. In the displacement process,CO_2 preferentially broke through the maximum pore throat. Before breaking through the maximum pore throat, the pressure of CO_2 continually increased, and the curvature and position of two-phase interfaces in the other pore throats adjusted accordingly. Once the maximum pore throat was broken through by the CO_2, the capillary force in the other pore throats released accordingly; subsequently, the interfaces withdrew under the effect of capillary fore, preparing for breaking through the next pore throat.Therefore, the two-phase displacement in CO_2 injection is accompanied by the breaking through and adjusting of the two-phase interfaces.
文摘Bangladesh is a south Asian Monsoonal Country and the recent precipitation pattern in the Cox’s Bazar area of Bangladesh is changing and increasing the number of monsoonal slope failures and landslide hazards in the Kutubpalong & Balukhali Rohingya camp area. An attempt has been made to see the influence of seasonal variation of ground water level (G.W.L.) fluctuations on the stability of the eco hills and forests of Ukhiya Teknaf region. Ukhiya hills are in great danger because of cutting trees from the hill slopes and it is well established that due to recent change of climate, short term rainfall for few consecutive days during monsoon might show an influence on the factor of safety (Fs) values of the camp hill slopes. A clear G.W.L. variation between dry and wet seasons has an influence on the stability (Fs) values indicating that climate has a strong influence on the stability and threatening sustainable development. A stable or marginally stable slope might be unstable during raining and show a variation of ground water level (G.W.L.). The generation of pore water pressure (P.W.P.) is also influenced by seasonal variation of ground water level. During wet season negative P.W.P. called suction plays an important role to occur slope failures in the Ukhiya hills. Based on all calculated factor of safety values (Fs) at different locations, four (4) susceptible landslide risk zones are identified. They are very high risk (Fs = 0.18 to 0.46), high risk (Fs = 0.56 to 0.75), medium risk (Fs = 0.76 to 1.0) and marginally stable areas (Fs ≈ 1). Proper geo-engineering measures must be taken by the concerned authorizes to reduce P.W.P. during monsoon by installing rain water harvesting system, allowing sufficient drainage & other geotechnical measures to reduce the risk of slope failures in the Ukhiya hills. Based on the stability factor (Fs) at different slope locations of the camp hills, a risk map of the investigated area has been produced for the local community for their safety and to build up awareness & to m
