Manipulating the polarization of light at the nanoscale is essential for the development of nano-optical devices. Owing to its corrugated honeycomb structure, two-dimensional (2D) layered black phosphorus (BP) exh...Manipulating the polarization of light at the nanoscale is essential for the development of nano-optical devices. Owing to its corrugated honeycomb structure, two-dimensional (2D) layered black phosphorus (BP) exhibits outstanding in-plane optical anisotropy with distinct linear dichroism and optical birefringence in the visible region, which are superior characteristics for ultrathin polarizing optics. Herein, taking advantage of polarized Raman spectroscopy, we demonstrate that layered BP with a nanometer thickness can remarkably alter the polarization state of a linearly-polarized laser and behave as an ultrathin optical polarization element in a BP-Bi2Se3 stacking structure by inducing the exceptionally polarized Raman scattering of isotropic Bi2Se3. Our findings provide a promising alternative for designing novel polarization optics based on 2D anisotropic materials, which can be easily integrated in micro- sized all-optical and optoelectronic devices.展开更多
The pseudo-quaternary phase diagram of Brij35/sodium oleate/oleic acid/watersystems has been investigated, and the liquid crystal area has been identified, which covers abouttwo thirds of the whole phase diagram. The ...The pseudo-quaternary phase diagram of Brij35/sodium oleate/oleic acid/watersystems has been investigated, and the liquid crystal area has been identified, which covers abouttwo thirds of the whole phase diagram. The liquid crystal structure and behavior have been alsostudied by using polarizing texture, small angle X-ray scattering, ~2H-NMR and rheometer etc. Theresult shows that when the composition of the system changes along the line of AA′ in this largeliquid crystal region, the structural change iscubic→cubic/lamellar→lamellar→larnellar/hexagonal→hexagonal. Meanwhile, we made the firstattempt of systematic study of the rheological properties of the above system. The lattice constantsof cubic and hexagonal liquid crystals are 10.53 and 5.68 nm, respectively.展开更多
A novel optimal design of sub-wavelength metal rectangular gratings for the polarizing beam splitter (PBS) is proposed. The method is based on effective medium theory and the method of designing single layer antiref...A novel optimal design of sub-wavelength metal rectangular gratings for the polarizing beam splitter (PBS) is proposed. The method is based on effective medium theory and the method of designing single layer antireflection coating. The polarization performance of PBS is discussed by rigorous couple-wave analysis (RCWA) method at a wavelength of 1550 nm. The result shows that sub-wavelength metal rectangular grating is characterized by a high reflectivity, like metal films for TE polarization, and high transmissivity, like dielectric films for TM polarization. The optimal design accords well with the results simulated by RCWA method.展开更多
Understanding limb development not only gives insights into the outgrowth and differentiation of the limb,but also has clinical relevance.Limb development begins with two paired limb buds(forelimb and hindlimb buds),w...Understanding limb development not only gives insights into the outgrowth and differentiation of the limb,but also has clinical relevance.Limb development begins with two paired limb buds(forelimb and hindlimb buds),which are initially undifferentiated mesenchymal cells tipped with a thickening of the ectoderm,termed the apical ectodermal ridge(AER).As a transitional embryonic structure,the AER undergoes four stages and contributes to multiple axes of limb development through the coordination of signalling centres,feedback loops,and other cell ac-tivities by secretory signalling and the activation of gene expression.Within the scope of proximodistal pattering,it is understood that while fibroblast growth factors(FGFs)function sequentially over time as primary components of the AER signalling process,there is still no consensus on models that would explain proximodistal patterning itself.In anteroposterior pattermning,the AER has a dual-direction regulation by which it promotes the sonic hedgehog(Shh)gene expression in the zone of polarizing activity(ZPA)for proliferation,and inhibits Shh expression in the anterior mesenchyme.In dorsoventral patterming,the AER activates Engrailed-1(En1)expression,and thus represses Wnt family member 7a(Wnt7a)expression in the ventral ectoderm by the expression of Fgfs,Sp6/8,and bone morpho-genetic protein(Bmp)genes.The AER also plays a vital role in shaping the individual digits,since levels of Fgf4/8 and Bmps expressed in the AER affect digit patterning by controlling apoptosis.In summary,the knowledge of crosstalk within AER among the three main axes is essential to understand limb growth and pattern fomation,as the development of its areas proceeds simultaneously.展开更多
Background:Cholesterol crystallization is an essential step toward gallstone formation.Although model bile studies showed that competition occurs between the gallstone surface and the surrounding aqueous phase for cho...Background:Cholesterol crystallization is an essential step toward gallstone formation.Although model bile studies showed that competition occurs between the gallstone surface and the surrounding aqueous phase for cholesterol molecules available for crystallization,this has not been investigated in human bile.Methods:Fresh gallbladder bile was obtained during laparoscopic cholecystectomy from 13 patients with cholesterol(n紏10)or pigment(n紏3)stones.Small cholesterol gallstones were collected from another two patients.Both native and ultrafiltered bile with or without added gallstones was analysed by polarized light microscopy for the presence of arc-like and needle-like anhydrous cholesterol crystals and classic cholesterol monohydrate crystals.Weight of the added stones was evaluated before and after 21 days of bile incubation.Results:In unfiltered bile,the presence of stones was associated with a trend towards less anhydrous cholesterol crystals,but significantly more aggregated cholesterol monohydrate crystals.In ultrafiltered bile,the presence of stones tended to inhibit the formation of arc-like or needle-like crystals and was associated with significantly greater amounts of both platelike and aggregated cholesterol monohydrate crystals.After 21 days of the incubation,stone weight was decreased in both unfiltered(–4.561.6%,P紏0.046)and ultrafiltered bile(–6.561.5%,P紏0.002).Bile from pigment-stone patients was clear in the absence of stones,but showed early appearance of plate-like and aggregated cholesterol monohydrate crystals in all samples to which cholesterol gallstones were added.Conclusions:The physical presence of cholesterol gallstones in both native and filtered bile greatly influences cholesterol crystallization pathways.Whereas cholesterol monohydrate crystals increase,anhydrous cholesterol crystals tend to be inhibited.Detachment of solid cholesterol crystals from the gallstone surface may explain these findings.展开更多
Polarizing beam splitter (PBS) is a critical optical component in projection display system because PBS performance greatly influences the contrast and brightness of the system. PBS performance is usually measured by ...Polarizing beam splitter (PBS) is a critical optical component in projection display system because PBS performance greatly influences the contrast and brightness of the system. PBS performance is usually measured by spectrophotometer after coating and cementing, but the measured result cannot represent the actual performance in practice because people usually change the incident angle in one plane (horizontal plane) and do not consider the other plane (vertical plane). Geometrical polarization rotation occurring at reduced F-number influences the measuring precision of s-polarization transmittance (Ts) and p-polarization reflectance (Rp). A more accurate and practical way to measure the performance of broadband, wide-angle PBS is presented in this paper.展开更多
An embedded wire-grid nanograting was designed and fabricated for using as a broadband polarizing beam splitter to reflect s-polarized light and transmit p-polarized light. A protected cladding layer of the same mater...An embedded wire-grid nanograting was designed and fabricated for using as a broadband polarizing beam splitter to reflect s-polarized light and transmit p-polarized light. A protected cladding layer of the same material as the grating's was deposited on the ridge, whereas the wire-grid is deposited in the grating trenches, which makes it more firm during application. High polarization extinction ratios of above 40 and 20 dB for transmission and reflection, respectively, with a broad wavelength range for the whole optical communication bandwidth (850 -1700 nm) and a wide angular tolerance (〉 ±20 °) are obtained by optimization of the designed structures, and the grating period is 200 nm.展开更多
Pluta polarizing interference microscope was used to follow the crazing that occur on the surface of stretched polypropylene fibres at different drawing conditions. The samples were stretched until crazing initiated, ...Pluta polarizing interference microscope was used to follow the crazing that occur on the surface of stretched polypropylene fibres at different drawing conditions. The samples were stretched until crazing initiated, and then craze propagation was monitored as a function of drawing speed and test temperature. The effect of craze dimension on their propagation velocity was taken into account. Three-dimensional birefringence profile for crazed polypropylene fibre has been demonstrated to investigate the birefringence of crazed fibre at different test times for fixed drawing speed value. Also the mean birefringence values of crazed polypropylene fibres were calculated and the results showed that, these values increased with the areal craze density. Video images were used to calculate the craze velocity. Optical micrographs and microinterferograms were presented for demonstrations.展开更多
Asbestos is widely applied in such sectors as manufacturing automobiles, tractors, chemical industrial equipment, and electric equipment. Asbestos fiber is harmful to human health. Therefore, the technology of testing...Asbestos is widely applied in such sectors as manufacturing automobiles, tractors, chemical industrial equipment, and electric equipment. Asbestos fiber is harmful to human health. Therefore, the technology of testing for asbestos in products is especially important. At present, in our country’s national specifications, there is no determination method or specification that is applicable to the asbestos in electronic and electric products. In this article, the components of asbestos in electronic and electric products are identified using the method of combining polarizing microscope with X-ray diffractometer. This method is simple, fast, highly reliable, and suitable to be widely adopted.展开更多
Design and experimental studies on the wavelength multiplexing and polarization multiplexing of diode laser arrays were carried out. First, the structure of a A1GalnAs/GaAs/AIGaAs quantum well under compressive strain...Design and experimental studies on the wavelength multiplexing and polarization multiplexing of diode laser arrays were carried out. First, the structure of a A1GalnAs/GaAs/AIGaAs quantum well under compressive strain was used because the characteristic of wavelength was easier to adjust. We obtained diode laser arrays lasing in five different wavelengths, about 760 nm, 800 nm, 860 nm, 930 nm, and 976 nm. At the same time, four edge filters were designed, and an experimental study on the beam multiplexing of diode laser arrays was carried out. Second, two beams with different polarization states were composited using a half wave plate and a polarizing beam-splitter prism. After that, the beam focusing system was designed. Ultimately, ten beams of diode laser arrays in five wavelengths and two polarization states were composited, the total output power was 196 W and the overall efficiency was 76%. The size of the output focus spot was 144 × 1330μm2, and the power density of the focused light was as high as 1.02 ×105 W/cm2. Compared with a single diode laser array, the power density of the composite beam was improved by 4.3 times.展开更多
The morphology of a thermotropic aromatic polyester during the transitions between isotropic and anisotropic melts was studied by means of polarizing microscopy and small angle light scattering techniques. Both transi...The morphology of a thermotropic aromatic polyester during the transitions between isotropic and anisotropic melts was studied by means of polarizing microscopy and small angle light scattering techniques. Both transition processes were found to be composed of the initiation of a new phase at local places of the old phase matrix and the growth of the new phase domains. A change of Hv scattering patterns was observed in the transition temperature ranges and was explained as the result of heterogeneity of the mesophase system, but not the change in ordering of a homogeneous mesophase.展开更多
The morphological features of a side-chain liquid crystalline polymer during the mesophase transitions were investigated by using the DSC technique. The polymer used was polyacrylate with mesogens of three benzene rin...The morphological features of a side-chain liquid crystalline polymer during the mesophase transitions were investigated by using the DSC technique. The polymer used was polyacrylate with mesogens of three benzene rings attached to the main chain through a flexible spacer. A special two-phase texture was observed in the transition temperature range. Similar to main-chain liquid crystalline polymers the transition process of the side-chain liquid crystalline polymer was composed of an initiation of the new phase at local places of the old phase matrix and a growth process of the new phase domains.展开更多
This paper discusses the well-known delayed choice Quantum Eraser experiment performed by Kim <em>et al.</em> in 2000 and analyzes it from a Classical Physics perspective. I have included a diagram of the ...This paper discusses the well-known delayed choice Quantum Eraser experiment performed by Kim <em>et al.</em> in 2000 and analyzes it from a Classical Physics perspective. I have included a diagram of the setup used in the experiment. I show that the result of the experiment can be explained by Classical Physics and does not require “Spooky action at a distance” due to entangled particles, as Einstein famously once put it, nor events modifying the past due to the delayed choice aspect of the experiment.展开更多
The morphological changes of a side-chain liquid-crystalline polymethacrylate during isotropization and liquid-crystallization transitions were studied by means of polarizing microscopy. These transitions were found t...The morphological changes of a side-chain liquid-crystalline polymethacrylate during isotropization and liquid-crystallization transitions were studied by means of polarizing microscopy. These transitions were found to be composed of the initiation of a new phase at local places of the old phase matrix and the growth of the new phase: domains. The kinetics of the liquid-crystallization of the polymer from an isotropic melt to a smectic mesophase was also investigated. The isothermal process of the transition can be described by the Avrami equation. The values of the Avrami exponent were found to be around 2.6. which is lower than the value usually obtained for crystallization transition of polymers, but larger than that reported for liquid-crystallization transition of main-chain polymers. These results may indicate the difference in growth geometry of new phase during transition between crystallization and liquid-crystallization in general and between liquid-crystallization of main-chain and side-chain polymers. It was found that the liquid-crystallization of the used side-chain polymethacrylate may occur at small undercoolings with high transformation rate similar to that of main-chain polymers and small-molecule liquid crystals, while the crystallization of polymers can only proceed at large undercoolings. These phenomena can be explained by the idea that the surface free energy of nucleus during liquid-crystallization transition is less than that for crystallization, and evidence was obtained from analysis of the temperature dependence of the transformation rate.展开更多
文摘Manipulating the polarization of light at the nanoscale is essential for the development of nano-optical devices. Owing to its corrugated honeycomb structure, two-dimensional (2D) layered black phosphorus (BP) exhibits outstanding in-plane optical anisotropy with distinct linear dichroism and optical birefringence in the visible region, which are superior characteristics for ultrathin polarizing optics. Herein, taking advantage of polarized Raman spectroscopy, we demonstrate that layered BP with a nanometer thickness can remarkably alter the polarization state of a linearly-polarized laser and behave as an ultrathin optical polarization element in a BP-Bi2Se3 stacking structure by inducing the exceptionally polarized Raman scattering of isotropic Bi2Se3. Our findings provide a promising alternative for designing novel polarization optics based on 2D anisotropic materials, which can be easily integrated in micro- sized all-optical and optoelectronic devices.
基金This work was supported by the National Natural Science Foundation of China (Grant No. 30370945) Guizhou Provincial Governor Foundation (No. 6, 2001).
文摘The pseudo-quaternary phase diagram of Brij35/sodium oleate/oleic acid/watersystems has been investigated, and the liquid crystal area has been identified, which covers abouttwo thirds of the whole phase diagram. The liquid crystal structure and behavior have been alsostudied by using polarizing texture, small angle X-ray scattering, ~2H-NMR and rheometer etc. Theresult shows that when the composition of the system changes along the line of AA′ in this largeliquid crystal region, the structural change iscubic→cubic/lamellar→lamellar→larnellar/hexagonal→hexagonal. Meanwhile, we made the firstattempt of systematic study of the rheological properties of the above system. The lattice constantsof cubic and hexagonal liquid crystals are 10.53 and 5.68 nm, respectively.
基金Project supported by Science Foundation of the Chongqing Committee of Education,China (Grant No KJ071205)
文摘A novel optimal design of sub-wavelength metal rectangular gratings for the polarizing beam splitter (PBS) is proposed. The method is based on effective medium theory and the method of designing single layer antireflection coating. The polarization performance of PBS is discussed by rigorous couple-wave analysis (RCWA) method at a wavelength of 1550 nm. The result shows that sub-wavelength metal rectangular grating is characterized by a high reflectivity, like metal films for TE polarization, and high transmissivity, like dielectric films for TM polarization. The optimal design accords well with the results simulated by RCWA method.
基金Key Research and Development Project of Shandong Province(No.2017G006043),China。
文摘Understanding limb development not only gives insights into the outgrowth and differentiation of the limb,but also has clinical relevance.Limb development begins with two paired limb buds(forelimb and hindlimb buds),which are initially undifferentiated mesenchymal cells tipped with a thickening of the ectoderm,termed the apical ectodermal ridge(AER).As a transitional embryonic structure,the AER undergoes four stages and contributes to multiple axes of limb development through the coordination of signalling centres,feedback loops,and other cell ac-tivities by secretory signalling and the activation of gene expression.Within the scope of proximodistal pattering,it is understood that while fibroblast growth factors(FGFs)function sequentially over time as primary components of the AER signalling process,there is still no consensus on models that would explain proximodistal patterning itself.In anteroposterior pattermning,the AER has a dual-direction regulation by which it promotes the sonic hedgehog(Shh)gene expression in the zone of polarizing activity(ZPA)for proliferation,and inhibits Shh expression in the anterior mesenchyme.In dorsoventral patterming,the AER activates Engrailed-1(En1)expression,and thus represses Wnt family member 7a(Wnt7a)expression in the ventral ectoderm by the expression of Fgfs,Sp6/8,and bone morpho-genetic protein(Bmp)genes.The AER also plays a vital role in shaping the individual digits,since levels of Fgf4/8 and Bmps expressed in the AER affect digit patterning by controlling apoptosis.In summary,the knowledge of crosstalk within AER among the three main axes is essential to understand limb growth and pattern fomation,as the development of its areas proceeds simultaneously.
基金The present chapter is written in the context of the project FOIE GRAS,which has received funding from the European Union’s Horizon 2020 Research and Innovation program under the Marie Sklodowska-Curie Grant Agreement No.722619.
文摘Background:Cholesterol crystallization is an essential step toward gallstone formation.Although model bile studies showed that competition occurs between the gallstone surface and the surrounding aqueous phase for cholesterol molecules available for crystallization,this has not been investigated in human bile.Methods:Fresh gallbladder bile was obtained during laparoscopic cholecystectomy from 13 patients with cholesterol(n紏10)or pigment(n紏3)stones.Small cholesterol gallstones were collected from another two patients.Both native and ultrafiltered bile with or without added gallstones was analysed by polarized light microscopy for the presence of arc-like and needle-like anhydrous cholesterol crystals and classic cholesterol monohydrate crystals.Weight of the added stones was evaluated before and after 21 days of bile incubation.Results:In unfiltered bile,the presence of stones was associated with a trend towards less anhydrous cholesterol crystals,but significantly more aggregated cholesterol monohydrate crystals.In ultrafiltered bile,the presence of stones tended to inhibit the formation of arc-like or needle-like crystals and was associated with significantly greater amounts of both platelike and aggregated cholesterol monohydrate crystals.After 21 days of the incubation,stone weight was decreased in both unfiltered(–4.561.6%,P紏0.046)and ultrafiltered bile(–6.561.5%,P紏0.002).Bile from pigment-stone patients was clear in the absence of stones,but showed early appearance of plate-like and aggregated cholesterol monohydrate crystals in all samples to which cholesterol gallstones were added.Conclusions:The physical presence of cholesterol gallstones in both native and filtered bile greatly influences cholesterol crystallization pathways.Whereas cholesterol monohydrate crystals increase,anhydrous cholesterol crystals tend to be inhibited.Detachment of solid cholesterol crystals from the gallstone surface may explain these findings.
基金(No. 2004C31107) supported by the Science and Technology Program of Zhejiang Province, China
文摘Polarizing beam splitter (PBS) is a critical optical component in projection display system because PBS performance greatly influences the contrast and brightness of the system. PBS performance is usually measured by spectrophotometer after coating and cementing, but the measured result cannot represent the actual performance in practice because people usually change the incident angle in one plane (horizontal plane) and do not consider the other plane (vertical plane). Geometrical polarization rotation occurring at reduced F-number influences the measuring precision of s-polarization transmittance (Ts) and p-polarization reflectance (Rp). A more accurate and practical way to measure the performance of broadband, wide-angle PBS is presented in this paper.
基金supported by the National Natural Science Foundation of China (No.60707017)the Science and Technology Plan of ZhejiangProvince, China (No.2006C1005)
文摘An embedded wire-grid nanograting was designed and fabricated for using as a broadband polarizing beam splitter to reflect s-polarized light and transmit p-polarized light. A protected cladding layer of the same material as the grating's was deposited on the ridge, whereas the wire-grid is deposited in the grating trenches, which makes it more firm during application. High polarization extinction ratios of above 40 and 20 dB for transmission and reflection, respectively, with a broad wavelength range for the whole optical communication bandwidth (850 -1700 nm) and a wide angular tolerance (〉 ±20 °) are obtained by optimization of the designed structures, and the grating period is 200 nm.
文摘Pluta polarizing interference microscope was used to follow the crazing that occur on the surface of stretched polypropylene fibres at different drawing conditions. The samples were stretched until crazing initiated, and then craze propagation was monitored as a function of drawing speed and test temperature. The effect of craze dimension on their propagation velocity was taken into account. Three-dimensional birefringence profile for crazed polypropylene fibre has been demonstrated to investigate the birefringence of crazed fibre at different test times for fixed drawing speed value. Also the mean birefringence values of crazed polypropylene fibres were calculated and the results showed that, these values increased with the areal craze density. Video images were used to calculate the craze velocity. Optical micrographs and microinterferograms were presented for demonstrations.
文摘Asbestos is widely applied in such sectors as manufacturing automobiles, tractors, chemical industrial equipment, and electric equipment. Asbestos fiber is harmful to human health. Therefore, the technology of testing for asbestos in products is especially important. At present, in our country’s national specifications, there is no determination method or specification that is applicable to the asbestos in electronic and electric products. In this article, the components of asbestos in electronic and electric products are identified using the method of combining polarizing microscope with X-ray diffractometer. This method is simple, fast, highly reliable, and suitable to be widely adopted.
基金supported by the National Science Foundation of China(No.61275145)
文摘Design and experimental studies on the wavelength multiplexing and polarization multiplexing of diode laser arrays were carried out. First, the structure of a A1GalnAs/GaAs/AIGaAs quantum well under compressive strain was used because the characteristic of wavelength was easier to adjust. We obtained diode laser arrays lasing in five different wavelengths, about 760 nm, 800 nm, 860 nm, 930 nm, and 976 nm. At the same time, four edge filters were designed, and an experimental study on the beam multiplexing of diode laser arrays was carried out. Second, two beams with different polarization states were composited using a half wave plate and a polarizing beam-splitter prism. After that, the beam focusing system was designed. Ultimately, ten beams of diode laser arrays in five wavelengths and two polarization states were composited, the total output power was 196 W and the overall efficiency was 76%. The size of the output focus spot was 144 × 1330μm2, and the power density of the focused light was as high as 1.02 ×105 W/cm2. Compared with a single diode laser array, the power density of the composite beam was improved by 4.3 times.
文摘The morphology of a thermotropic aromatic polyester during the transitions between isotropic and anisotropic melts was studied by means of polarizing microscopy and small angle light scattering techniques. Both transition processes were found to be composed of the initiation of a new phase at local places of the old phase matrix and the growth of the new phase domains. A change of Hv scattering patterns was observed in the transition temperature ranges and was explained as the result of heterogeneity of the mesophase system, but not the change in ordering of a homogeneous mesophase.
基金The authors are grateful to the Director Foundation of Institute of Chemistry,Chinese Academy of Sciences and Science Foundation of Polymer Physics Laboratory,Chinese Academy of Sciences for supporting this work
文摘The morphological features of a side-chain liquid crystalline polymer during the mesophase transitions were investigated by using the DSC technique. The polymer used was polyacrylate with mesogens of three benzene rings attached to the main chain through a flexible spacer. A special two-phase texture was observed in the transition temperature range. Similar to main-chain liquid crystalline polymers the transition process of the side-chain liquid crystalline polymer was composed of an initiation of the new phase at local places of the old phase matrix and a growth process of the new phase domains.
文摘This paper discusses the well-known delayed choice Quantum Eraser experiment performed by Kim <em>et al.</em> in 2000 and analyzes it from a Classical Physics perspective. I have included a diagram of the setup used in the experiment. I show that the result of the experiment can be explained by Classical Physics and does not require “Spooky action at a distance” due to entangled particles, as Einstein famously once put it, nor events modifying the past due to the delayed choice aspect of the experiment.
文摘The morphological changes of a side-chain liquid-crystalline polymethacrylate during isotropization and liquid-crystallization transitions were studied by means of polarizing microscopy. These transitions were found to be composed of the initiation of a new phase at local places of the old phase matrix and the growth of the new phase: domains. The kinetics of the liquid-crystallization of the polymer from an isotropic melt to a smectic mesophase was also investigated. The isothermal process of the transition can be described by the Avrami equation. The values of the Avrami exponent were found to be around 2.6. which is lower than the value usually obtained for crystallization transition of polymers, but larger than that reported for liquid-crystallization transition of main-chain polymers. These results may indicate the difference in growth geometry of new phase during transition between crystallization and liquid-crystallization in general and between liquid-crystallization of main-chain and side-chain polymers. It was found that the liquid-crystallization of the used side-chain polymethacrylate may occur at small undercoolings with high transformation rate similar to that of main-chain polymers and small-molecule liquid crystals, while the crystallization of polymers can only proceed at large undercoolings. These phenomena can be explained by the idea that the surface free energy of nucleus during liquid-crystallization transition is less than that for crystallization, and evidence was obtained from analysis of the temperature dependence of the transformation rate.