采用大气等离子喷涂(APS)在高温合金表面制备一层Ni Co Cr Al Y粘结层,然后采用阴极等离子电解沉积(CPED)制备一层弥散Pt微粒的8YSZ涂层。通过在电解液中加入陶瓷微珠,促使阴极表面发生均匀的等离子微弧放电,实现了在大面积样品上沉积8...采用大气等离子喷涂(APS)在高温合金表面制备一层Ni Co Cr Al Y粘结层,然后采用阴极等离子电解沉积(CPED)制备一层弥散Pt微粒的8YSZ涂层。通过在电解液中加入陶瓷微珠,促使阴极表面发生均匀的等离子微弧放电,实现了在大面积样品上沉积8YSZ涂层。获得的涂层厚度到达120μm,具有多孔结构,由立方相和四方相8YSZ以及Pt组成。1100℃空气中循环氧化的结果表明,随着涂层中Pt含量的的增加,涂层的抗高温氧化和抗剥落性能得到明显提高。Pt微粒对8YSZ涂层的增韧作用主要为:Pt微粒塑性变形吸收裂纹扩展的能量,钝化裂纹尖端,减小裂纹尺寸,提高涂层的临界断裂应力。展开更多
In this work, we investigated the features of the anode plasma electrolytic saturation of titanium alloys with nitrogen and oxygen. In this case, the titanium samples may be heated to 1050 ℃ using aqueous solutions o...In this work, we investigated the features of the anode plasma electrolytic saturation of titanium alloys with nitrogen and oxygen. In this case, the titanium samples may be heated to 1050 ℃ using aqueous solutions of ammonium chloride as working electrolyte. The weight of titanium samples is found to change due to their oxidation and anode dissolution. An X-ray diffractometer, a scanning electron microscope,nuclear proton backscattering and an optical microscope were used to characterize the phase and elemental composition of the modified layer. The electrolyte composition（10 wt% ammonium chloride, 5wt% ammonia） and processing mode（850 ℃, 5 min） of commercially pure titanium（CP-Ti） allowing to obtain the hardened surface layer up to 0.1 mm with microhardness of 220 HV were proposed. Surface roughness Ra of samples after their nitriding for 5 min at 800 ℃ decreases from 1.67 to 0.082 μm. The anode plasma electrolytic nitriding could decrease friction coefficient and increase wear resistance of the CP-Ti. It is found that the anodic nitriding of low alloy titanium alloys reduces their corrosion rate in an aqueous solution of sulphuric（4.5%） and salt（0.2%） acids by 2 orders of magnitude. Results of cyclic testing show that anodic nitriding of commercial titanium leads to a decrease in corrosion rate by 8 times in solution of hydrochloric acid（6%） with addition of protein and vitamin.展开更多
文摘采用大气等离子喷涂(APS)在高温合金表面制备一层Ni Co Cr Al Y粘结层,然后采用阴极等离子电解沉积(CPED)制备一层弥散Pt微粒的8YSZ涂层。通过在电解液中加入陶瓷微珠,促使阴极表面发生均匀的等离子微弧放电,实现了在大面积样品上沉积8YSZ涂层。获得的涂层厚度到达120μm,具有多孔结构,由立方相和四方相8YSZ以及Pt组成。1100℃空气中循环氧化的结果表明,随着涂层中Pt含量的的增加,涂层的抗高温氧化和抗剥落性能得到明显提高。Pt微粒对8YSZ涂层的增韧作用主要为:Pt微粒塑性变形吸收裂纹扩展的能量,钝化裂纹尖端,减小裂纹尺寸,提高涂层的临界断裂应力。
基金supported by the Russian Science Foundation(Contract No.15-19-20027)to the Nekrasov Kostroma State University
文摘In this work, we investigated the features of the anode plasma electrolytic saturation of titanium alloys with nitrogen and oxygen. In this case, the titanium samples may be heated to 1050 ℃ using aqueous solutions of ammonium chloride as working electrolyte. The weight of titanium samples is found to change due to their oxidation and anode dissolution. An X-ray diffractometer, a scanning electron microscope,nuclear proton backscattering and an optical microscope were used to characterize the phase and elemental composition of the modified layer. The electrolyte composition（10 wt% ammonium chloride, 5wt% ammonia） and processing mode（850 ℃, 5 min） of commercially pure titanium（CP-Ti） allowing to obtain the hardened surface layer up to 0.1 mm with microhardness of 220 HV were proposed. Surface roughness Ra of samples after their nitriding for 5 min at 800 ℃ decreases from 1.67 to 0.082 μm. The anode plasma electrolytic nitriding could decrease friction coefficient and increase wear resistance of the CP-Ti. It is found that the anodic nitriding of low alloy titanium alloys reduces their corrosion rate in an aqueous solution of sulphuric（4.5%） and salt（0.2%） acids by 2 orders of magnitude. Results of cyclic testing show that anodic nitriding of commercial titanium leads to a decrease in corrosion rate by 8 times in solution of hydrochloric acid（6%） with addition of protein and vitamin.
