M50NiL steel was plasma nitrocarburized at 480 °C with and without rare earth （RE） addition. The microstructures of the surface layer were characterized by optical microscopy, X-ray diffraction and scanning ele...M50NiL steel was plasma nitrocarburized at 480 °C with and without rare earth （RE） addition. The microstructures of the surface layer were characterized by optical microscopy, X-ray diffraction and scanning electron microscopy. The mechanical proper-ties and corrosion resistances of the surface layer were studied by Vickers microhardness measurements and polarization tests in 3.5% NaCl solution. The results showed that RE atoms could diffuse into the surface layer of the steel and inhabit the formation ofε-Fe2–3（N,C） phase. As compared to the treatment without RE addition, RE addition further increased the surface hardness by 143 HV0.1, and further increased the thickness of the nitrocarburized layer by 39μm. Compared with the quenched bearing steel, the cor-rosion resistance of the samples nitrocarburized with and without RE addition could be significantly improved. Especially, the sample plasma nitrocarburized with RE addition exhibited the highest corrosion resistance.展开更多
Low temperature plasma nitrocarburizing of 17-4PH martensitic stainless steel was conducted at 430 ℃ with and without rare earth （RE） addition. The microstructure, kinetics, microhardness, wear behavior as well as ...Low temperature plasma nitrocarburizing of 17-4PH martensitic stainless steel was conducted at 430 ℃ with and without rare earth （RE） addition. The microstructure, kinetics, microhardness, wear behavior as well as corrosion resistance of the modified layer were studied by optical microscopy, X-ray diffraction, Vickers microhardness tester, pin-on-disc tribometer and potentiodynamic polarization tests. The results show that the thickness of plasma RE nitrocarburized layer is much thicker than that formed by nitrocarburizing without RE addition. The incorporation of RE does not change the kind of the phases and the nitrocarburized layer consists mainly of nitrogen and carbon expanded martensite （aN）, γ-Fe4N and a-Fe with a trace of CrN phases. The surface microhardness of plasma nitrocarburized layer can be increased by 100 HV after RE addition. Wear resistance of the specimen can be apparently improved by low temperature plasma nitrocarburizing with and without RE addition and without sacrificing its corrosion resistance. Wear reduction effect of low temperature plasma nitrocarburizing with RE addition is better than that of the conventional one.展开更多
The aim of this investigation is to reveal the influence of rare earths(RE) addition on mechanical properties of plasma nitrocarburized 17-4PH steel.The nitrocarburized layers were characterized by optical microscope,...The aim of this investigation is to reveal the influence of rare earths(RE) addition on mechanical properties of plasma nitrocarburized 17-4PH steel.The nitrocarburized layers were characterized by optical microscope,scanning electron microscope equipped with energy dispersive X-ray analyzer,X-ray diffractometer,microhardness tester and pin-on-disc tribometer.The results showed that RE atoms could diffuse into the surface layer of 17-4PH steel plasma nitrocarburized at 500 °C for 4 h and did not change the ...展开更多
In order to improve surface hardness and corrosion resistant property of 17-4PH martensitic stainless steel, the steel was plasma nitrocarburized at 560 ℃ for 2-4 h in a gas mixture of nitrogen, hydrogenand ethanol w...In order to improve surface hardness and corrosion resistant property of 17-4PH martensitic stainless steel, the steel was plasma nitrocarburized at 560 ℃ for 2-4 h in a gas mixture of nitrogen, hydrogenand ethanol with rare earths （RE） addition. The experimental results showed that the modified layer was characterized by a compound layer containing two distinct zones （i.e. out ~dark zone＇ and inner ＇white zone＇）. The inner ＇white zone＇ was almost a precipitation free zone and had high hardness as well as good corrosion resistance. An- odic polarization test results showed that the specimens plasma nitrocarburized with RE addition had good corrosion resistance resulted mainly from their higher corrosion potentials, lower corrosion current densities and larger passive regions as compared with those of the un- treated one.展开更多
The pulse plasma nitrocarburizing for 30CrMnSiA steel was conducted at 560 ℃ for 8 h in mixed gases of N2：3H2 and different flow rates of rare earths （RE） addition. Effects of rare earths （RE） addition in the ca...The pulse plasma nitrocarburizing for 30CrMnSiA steel was conducted at 560 ℃ for 8 h in mixed gases of N2：3H2 and different flow rates of rare earths （RE） addition. Effects of rare earths （RE） addition in the carrier gas on the surface morphology, phase structure and mechanical properties of the nitrocarburized layer were characterized by optical microscopy （OM）, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, microhardness testing and wear testing, respectively. The results showed that the surface phase structures changed from dual phases ε-Fe2.3N（C） and γ′-Fe4N（C） to phase Fe3C and incipient nitrides, and the nitrocarburized surface hardness value decreased slightly from 756 to 681 HV0.1 with the RE addition increasing in the cartier gas, and the corresponding morphology of the nitrocarburized surface was granular nitride group （diameter 0.8-1.5 μm） and compact-fine Fe3C stick and patch （mean size 100-300 nm）, respectively. The wear resistance of the experimental steel could be improved remarkably by plasma RE nitrocarburizing. The nitrocarburized layer with Fe3C phase formed in the mixed gases of N2：3H2 and flow rate of 0.5 L/min RE addition showed the lowest friction coefficient and the narrowest wear track.展开更多
Plasma nitrocarburizing and plasma oxidizing treatments were performed to improve the wear and corrosion resistance of SKD 61 steel.Plasma nitrocarburizing was conducted for 12 h at 540℃in the nitrogen, hydrogen and ...Plasma nitrocarburizing and plasma oxidizing treatments were performed to improve the wear and corrosion resistance of SKD 61 steel.Plasma nitrocarburizing was conducted for 12 h at 540℃in the nitrogen, hydrogen and methane atmosphere to produce theε-Fe-（2-3）（N,C） phase.The compound layer produced by plasma nitrocarburising was predominantly composed ofε-phase,with a small proportion ofγ′-Fe-4 （N,C） phase. The thickness of the compound layer and the diffusion layer are about 10μm and about 200μm,respectively. Plasma post oxidation was performed on the nitrocarburized samples with various oxygen/hydrogen ratio at constant temperature of 500℃for 1 h.The very thin magnetite （Fe-3O-4） layer of 1-2μm in thickness on top of the compound layer was obtained.Anodic polarization test revealed that plasma nitrocarburizing process contributed a significant improvement of corrosion resistance of SKD 61 steel.However,the corrosion characteristics of the nitrocarburized compound layer was deteriorated by oxidation treatment.展开更多
Plasma nitrocarburizing of nanocrystallized （NC） 3J33 steel were carried out at 400 and 430 ℃ for 4 h in a mixed gas of N2：3H2 and different flow rates of rare earths （RE） La and Ce reagents in this paper. Effec...Plasma nitrocarburizing of nanocrystallized （NC） 3J33 steel were carried out at 400 and 430 ℃ for 4 h in a mixed gas of N2：3H2 and different flow rates of rare earths （RE） La and Ce reagents in this paper. Effects of temperature, rare earth addition and its addition amount on the microstructure and hardness of the nitrocarburized layer of NC 3J33 steel were also investigated. Surface phase composition of the nitrocarburized samples was analyzed by X-ray diffraction. Metallurgical structure, La and Ce concentration and microhardness profiles of cross-sectional nitrocarburized samples were studied using an optical microscope, a scanning electron microscope equipped with an energy dispersive X-ray analyzer and Vickers microhardness tester, respectively. The results showed that the surfaces of the nitrocarburized samples were mainly composed of γ＇-Fe4N and α＇-Fe （α-Fe dissolved with N and C） when the NC 3J33 steel was nitrocarburized at 400 ℃. As the temperature was enhanced up to 430 ℃, the surfaces consisted of γ＇-Fe4N, α＇-Fe and low nitrogen compound FeNx （x=0.0324–0.0989）, and simple substance La was presented when RE flow rate was 0.1 L/min. The addition of La and Ce into nitrocarburized gas increased the thickness and hardness of the nitrocarburized layers. The samples nitrocarburized at 400 ℃ with RE flow rate of 0.025 L/min and 430 ℃ of 0.05 L/min possessed the thickest nitrocarburized layer, highest proportion of nitrides and hardness profile. RE elements could diffuse into the nitrocarburized layer and their concentration increased with temperature. The excess RE impeded the permeation of N, C elements and led to thinner compound layer as well as the diffusion layer.展开更多
基金supported by the National Natural Science Foundation of China(51371070,51401062)
文摘M50NiL steel was plasma nitrocarburized at 480 °C with and without rare earth （RE） addition. The microstructures of the surface layer were characterized by optical microscopy, X-ray diffraction and scanning electron microscopy. The mechanical proper-ties and corrosion resistances of the surface layer were studied by Vickers microhardness measurements and polarization tests in 3.5% NaCl solution. The results showed that RE atoms could diffuse into the surface layer of the steel and inhabit the formation ofε-Fe2–3（N,C） phase. As compared to the treatment without RE addition, RE addition further increased the surface hardness by 143 HV0.1, and further increased the thickness of the nitrocarburized layer by 39μm. Compared with the quenched bearing steel, the cor-rosion resistance of the samples nitrocarburized with and without RE addition could be significantly improved. Especially, the sample plasma nitrocarburized with RE addition exhibited the highest corrosion resistance.
基金the National Natural Science Foundation of China(No.51071061)the Heilongjiang Postdoctoral Subsidies,China(No.LBHZ10199)+1 种基金the Fundamental Research Funds for the Central Universities,China(No.HEUCFR1129)the China Postdoctoral Science Foundation(No.20110491026)for financial support of this research work
文摘Low temperature plasma nitrocarburizing of 17-4PH martensitic stainless steel was conducted at 430 ℃ with and without rare earth （RE） addition. The microstructure, kinetics, microhardness, wear behavior as well as corrosion resistance of the modified layer were studied by optical microscopy, X-ray diffraction, Vickers microhardness tester, pin-on-disc tribometer and potentiodynamic polarization tests. The results show that the thickness of plasma RE nitrocarburized layer is much thicker than that formed by nitrocarburizing without RE addition. The incorporation of RE does not change the kind of the phases and the nitrocarburized layer consists mainly of nitrogen and carbon expanded martensite （aN）, γ-Fe4N and a-Fe with a trace of CrN phases. The surface microhardness of plasma nitrocarburized layer can be increased by 100 HV after RE addition. Wear resistance of the specimen can be apparently improved by low temperature plasma nitrocarburizing with and without RE addition and without sacrificing its corrosion resistance. Wear reduction effect of low temperature plasma nitrocarburizing with RE addition is better than that of the conventional one.
基金supported by the National Natural Science Foundation of China (50871035)the Ph.D. Programs Foundation of Ministry of Education of China (20060213017)
文摘The aim of this investigation is to reveal the influence of rare earths(RE) addition on mechanical properties of plasma nitrocarburized 17-4PH steel.The nitrocarburized layers were characterized by optical microscope,scanning electron microscope equipped with energy dispersive X-ray analyzer,X-ray diffractometer,microhardness tester and pin-on-disc tribometer.The results showed that RE atoms could diffuse into the surface layer of 17-4PH steel plasma nitrocarburized at 500 °C for 4 h and did not change the ...
基金Project supported by National Natural Science Foundation of China(51071061,11176011)Heilongjiang Postdoctoral Subsidies(LBH-Z10199)+1 种基金Fundamental Research Funds for the Central Universities(HEUCFR1129)China Postdoctoral Science Foundation(20110491026)
文摘In order to improve surface hardness and corrosion resistant property of 17-4PH martensitic stainless steel, the steel was plasma nitrocarburized at 560 ℃ for 2-4 h in a gas mixture of nitrogen, hydrogenand ethanol with rare earths （RE） addition. The experimental results showed that the modified layer was characterized by a compound layer containing two distinct zones （i.e. out ~dark zone＇ and inner ＇white zone＇）. The inner ＇white zone＇ was almost a precipitation free zone and had high hardness as well as good corrosion resistance. An- odic polarization test results showed that the specimens plasma nitrocarburized with RE addition had good corrosion resistance resulted mainly from their higher corrosion potentials, lower corrosion current densities and larger passive regions as compared with those of the un- treated one.
基金Project supported by National Natural Science Foundation of China(51071061)NSAF Foundation of National Natural Science Foundation of China and China Academy of Engineering Physics (11176011)
文摘The pulse plasma nitrocarburizing for 30CrMnSiA steel was conducted at 560 ℃ for 8 h in mixed gases of N2：3H2 and different flow rates of rare earths （RE） addition. Effects of rare earths （RE） addition in the carrier gas on the surface morphology, phase structure and mechanical properties of the nitrocarburized layer were characterized by optical microscopy （OM）, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, microhardness testing and wear testing, respectively. The results showed that the surface phase structures changed from dual phases ε-Fe2.3N（C） and γ′-Fe4N（C） to phase Fe3C and incipient nitrides, and the nitrocarburized surface hardness value decreased slightly from 756 to 681 HV0.1 with the RE addition increasing in the cartier gas, and the corresponding morphology of the nitrocarburized surface was granular nitride group （diameter 0.8-1.5 μm） and compact-fine Fe3C stick and patch （mean size 100-300 nm）, respectively. The wear resistance of the experimental steel could be improved remarkably by plasma RE nitrocarburizing. The nitrocarburized layer with Fe3C phase formed in the mixed gases of N2：3H2 and flow rate of 0.5 L/min RE addition showed the lowest friction coefficient and the narrowest wear track.
文摘Plasma nitrocarburizing and plasma oxidizing treatments were performed to improve the wear and corrosion resistance of SKD 61 steel.Plasma nitrocarburizing was conducted for 12 h at 540℃in the nitrogen, hydrogen and methane atmosphere to produce theε-Fe-（2-3）（N,C） phase.The compound layer produced by plasma nitrocarburising was predominantly composed ofε-phase,with a small proportion ofγ′-Fe-4 （N,C） phase. The thickness of the compound layer and the diffusion layer are about 10μm and about 200μm,respectively. Plasma post oxidation was performed on the nitrocarburized samples with various oxygen/hydrogen ratio at constant temperature of 500℃for 1 h.The very thin magnetite （Fe-3O-4） layer of 1-2μm in thickness on top of the compound layer was obtained.Anodic polarization test revealed that plasma nitrocarburizing process contributed a significant improvement of corrosion resistance of SKD 61 steel.However,the corrosion characteristics of the nitrocarburized compound layer was deteriorated by oxidation treatment.
基金supported by the National Natural Science Foundation of China (50871035 and 51071061)Program of Excellent Team at Harbin In-stitute of Technology
文摘Plasma nitrocarburizing of nanocrystallized （NC） 3J33 steel were carried out at 400 and 430 ℃ for 4 h in a mixed gas of N2：3H2 and different flow rates of rare earths （RE） La and Ce reagents in this paper. Effects of temperature, rare earth addition and its addition amount on the microstructure and hardness of the nitrocarburized layer of NC 3J33 steel were also investigated. Surface phase composition of the nitrocarburized samples was analyzed by X-ray diffraction. Metallurgical structure, La and Ce concentration and microhardness profiles of cross-sectional nitrocarburized samples were studied using an optical microscope, a scanning electron microscope equipped with an energy dispersive X-ray analyzer and Vickers microhardness tester, respectively. The results showed that the surfaces of the nitrocarburized samples were mainly composed of γ＇-Fe4N and α＇-Fe （α-Fe dissolved with N and C） when the NC 3J33 steel was nitrocarburized at 400 ℃. As the temperature was enhanced up to 430 ℃, the surfaces consisted of γ＇-Fe4N, α＇-Fe and low nitrogen compound FeNx （x=0.0324–0.0989）, and simple substance La was presented when RE flow rate was 0.1 L/min. The addition of La and Ce into nitrocarburized gas increased the thickness and hardness of the nitrocarburized layers. The samples nitrocarburized at 400 ℃ with RE flow rate of 0.025 L/min and 430 ℃ of 0.05 L/min possessed the thickest nitrocarburized layer, highest proportion of nitrides and hardness profile. RE elements could diffuse into the nitrocarburized layer and their concentration increased with temperature. The excess RE impeded the permeation of N, C elements and led to thinner compound layer as well as the diffusion layer.
