NaNbO3-Co2O3 co-added PZN-PZT （PZCNNT） ceramics were prepared using conventional solid state reaction. The piezoelectric and dielectric properties were measured. The experimental results show that the addition of 0....NaNbO3-Co2O3 co-added PZN-PZT （PZCNNT） ceramics were prepared using conventional solid state reaction. The piezoelectric and dielectric properties were measured. The experimental results show that the addition of 0.3mo1% Co2O3 leads to low dielectric loss （tgδ） in PZCNNT ceramics and the proper addition of NaNbO3 not only improves piezoelectric properties but also decreases intensively dielectric loss and mechanical loss. The optimal ceramic having d33=310 pC/N, kp=0.59, εr=985, tgδ=0.0034, Qm=1380 was obtained.展开更多
The definitions of the third-order elastic,piezoelectric,and dielectric constants and the properties of the associated tensors are discussed.Based on the energy conservation and coordinate transformation,the relations...The definitions of the third-order elastic,piezoelectric,and dielectric constants and the properties of the associated tensors are discussed.Based on the energy conservation and coordinate transformation,the relations among the third-order constants are obtained.Furthermore,the relations among the third-order elastic,piezoelectric,and dielectric constants of the seven crystal systems and isotropic materials are listed in detail.These third-order constants relations play an important role in solving nonlinear problems of elastic and piezoelectric materials.It is further found that all third-order piezoelectric constants are 0 for 15 kinds of point groups,while all third-order dielectric constants are 0 for 16 kinds of point groups as well as isotropic material.The reason is that some of the point groups are centrally symmetric,and the other point groups are high symmetry.These results provide the foundation to measure these constants,to choose material,and to research nonlinear problems.Moreover,these results are helpful not only for the study of nonlinear elastic and piezoelectric problems,but also for the research on flexoelectric effects and size effects.展开更多
This paper describes the preparation of a piezoelectric glass ceramic material from potassium sodium niobate （Ko.sNa0.sNbO3; KNN） using a novel melting method. The effects of the subsequent heat-treatment on the opt...This paper describes the preparation of a piezoelectric glass ceramic material from potassium sodium niobate （Ko.sNa0.sNbO3; KNN） using a novel melting method. The effects of the subsequent heat-treatment on the optical, thermal, electrical, and mechanical properties of the material are carefully examined, and its crystal structure and surface morphol- ogy are characterized respectively by x-ray diffraction and scanning electron microscopy. This new material has a much higher piezoelectric coefficient （163 pC.N-1） than traditional piezoelectric ceramics （131 pC.N-1 ）. On this basis therefore, a strategy for the future study and development of lead-free KNN-based piezoelectric glass ceramics is proposed.展开更多
文摘NaNbO3-Co2O3 co-added PZN-PZT （PZCNNT） ceramics were prepared using conventional solid state reaction. The piezoelectric and dielectric properties were measured. The experimental results show that the addition of 0.3mo1% Co2O3 leads to low dielectric loss （tgδ） in PZCNNT ceramics and the proper addition of NaNbO3 not only improves piezoelectric properties but also decreases intensively dielectric loss and mechanical loss. The optimal ceramic having d33=310 pC/N, kp=0.59, εr=985, tgδ=0.0034, Qm=1380 was obtained.
基金Project supported by the National Natural Science Foundation of China(Nos.11872186 and11272126)the Fundamental Research Funds for the Central Universities(No.HUST:2016JCTD114)
文摘The definitions of the third-order elastic,piezoelectric,and dielectric constants and the properties of the associated tensors are discussed.Based on the energy conservation and coordinate transformation,the relations among the third-order constants are obtained.Furthermore,the relations among the third-order elastic,piezoelectric,and dielectric constants of the seven crystal systems and isotropic materials are listed in detail.These third-order constants relations play an important role in solving nonlinear problems of elastic and piezoelectric materials.It is further found that all third-order piezoelectric constants are 0 for 15 kinds of point groups,while all third-order dielectric constants are 0 for 16 kinds of point groups as well as isotropic material.The reason is that some of the point groups are centrally symmetric,and the other point groups are high symmetry.These results provide the foundation to measure these constants,to choose material,and to research nonlinear problems.Moreover,these results are helpful not only for the study of nonlinear elastic and piezoelectric problems,but also for the research on flexoelectric effects and size effects.
文摘This paper describes the preparation of a piezoelectric glass ceramic material from potassium sodium niobate （Ko.sNa0.sNbO3; KNN） using a novel melting method. The effects of the subsequent heat-treatment on the optical, thermal, electrical, and mechanical properties of the material are carefully examined, and its crystal structure and surface morphol- ogy are characterized respectively by x-ray diffraction and scanning electron microscopy. This new material has a much higher piezoelectric coefficient （163 pC.N-1） than traditional piezoelectric ceramics （131 pC.N-1 ）. On this basis therefore, a strategy for the future study and development of lead-free KNN-based piezoelectric glass ceramics is proposed.
