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电解质溶液相平衡热力学模型研究进展 被引量:6
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作者 周桓 李以圭 《计算机与应用化学》 CAS CSCD 北大核心 2003年第3期327-334,共8页
从电解质溶液理论、活度系数模型和状态方程出发,对用于电解质溶液相平衡关联、预测的成功模型及近年来应用研究的进展,以工程应用模型为重点,进行了综述。从长程静电作用和非静电作用对活度系数的贡献的角度,介绍了活度系数模型中,以De... 从电解质溶液理论、活度系数模型和状态方程出发,对用于电解质溶液相平衡关联、预测的成功模型及近年来应用研究的进展,以工程应用模型为重点,进行了综述。从长程静电作用和非静电作用对活度系数的贡献的角度,介绍了活度系数模型中,以Debye-Hckel理论和MSA理论为基础的长程静电作用项的进展,介绍了Pitzer方程、E-NRTL、E-UNIQUAC以及化学贡献等活度系数模型的研究与应用进展;电解质状态方程则从3个方面总结了近年来的研究进展,即:以三次型方程、微扰理论为基础的电解质溶液状态方程和高温超临界条件下电解质溶液状态方程。 展开更多
关键词 电解质溶液 相平衡 热力学模型 活度系数模型 状态方程 PITZER方程 E-NRTL E-UNIQUAC
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Phase Equilibria Constraints on Relations of Ore-bearing Intrusions with Flood Basalts in the Panxi Region,Southwestern China 被引量:7
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作者 ZHANG Zhaochong HAO Yanli +2 位作者 AI Yu LI Yin ZHAO Li 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2009年第2期295-309,共15页
There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PG... There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PGE)-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis (Q-PI-OI-Opx-Cpx system) has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts (including high-Ti, low-Ti and alkali basalts), respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and low-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limahe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basalts. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts. 展开更多
关键词 layered intrusions phase equalibria Cu-Ni sulfide deposit V-Ti-Fe oxide deposit Emeishan
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