The local coordination environment of catalysts has been investigated ftor an extended period to obtain enhanced catalytic performance.Especially with the advancement of single-atom catalysts(SACs),research on the coo...The local coordination environment of catalysts has been investigated ftor an extended period to obtain enhanced catalytic performance.Especially with the advancement of single-atom catalysts(SACs),research on the coordination environment has been advanced to the atomic level.The surrounding coordination atoms of central metal atoms play important roles in their catalytic activity,selectivity and stability.In recent years,remarkable improvements of the catalytic performance of SACs have been achieved by the tailoring of coordination atoms,coordination numbers and second-or higher-coordination shells,which provided new opportunities for the further development of SACs.In this review,the characterization of coordination environment,tailoring of the local coordination environment,and their related adjustable catalytic performance will be discussed.We hope this review will provide new insights on further research of SACs.展开更多
以离心压缩机变工况性能换算、特性曲线变转速二次拟合、基于BWRS方程的气体物性计算为理论基础,以NetBeans IDE 6.7为开发平台,结合Excel,采用Java语言开发了离心压缩机性能评价软件。软件能够准确计算与压缩机工作过程相关的气体物性...以离心压缩机变工况性能换算、特性曲线变转速二次拟合、基于BWRS方程的气体物性计算为理论基础,以NetBeans IDE 6.7为开发平台,结合Excel,采用Java语言开发了离心压缩机性能评价软件。软件能够准确计算与压缩机工作过程相关的气体物性参数,实现电子图像版压缩机特性曲线的数字化,可对不同入口条件下的特性曲线进行换算及变转速拟合,确定压缩机的流量控制界限。以某天然气长输管道首站的历史运行数据为依据,验证了软件计算结果的准确性。该软件可用于优化压气站运行方案。展开更多
The relationship mechanism between the material pore structures and cathodic iodine chemistry plays a vital role in efficient Zn-I_(2) batteries,but is unclear,retarding further advances.This work innovatively indicat...The relationship mechanism between the material pore structures and cathodic iodine chemistry plays a vital role in efficient Zn-I_(2) batteries,but is unclear,retarding further advances.This work innovatively indicates a great contribution of∼2.5nm pore structure of nanocarbons to efficient iodine adsorption,rapid I^(−)↔I_(2) conversion,and polyiodide inhibition,via scrupulously designing catalysts with controllable pore sizes systematically.The I_(2)-loading within the designed nitrogen-doped nanocarbons can reach up to as high as 60.8 wt%.The batteries based on the cathode deliver impressive performances with a large capacity of 178.8 mAh/g and long-term cycling stability more than 4000 h at 5.0 C.Notably,these is no polyiodide such as I_(3)−and I_(5)−detected during the charge-discharge processes from comprehensive electrochemical cyclic voltammetry,X-ray photoelectron spectroscopy,and Raman technique.This work provides a novel knowledge-guided concept for rational pore design,promising better Zn-I_(2) batteries,which is also hoped to benefit other advanced energy technologies,such as Li-S,Li-ion,and Al-I_(2) batteries.展开更多
基金the National Key R&D Program of China(Nos.2018YFA0702003 and 2016YFA0202801)the National Natural Science Foundation of China(Nos.51631001,51872030,21890383,21671117,21871159,21901135,51702016,and 51501010)+1 种基金Beijing Institute of Technology Research Fund Program for Young ScholarsBeijing Municipal Science&Technology Commission(No.Z191100007219003).
文摘The local coordination environment of catalysts has been investigated ftor an extended period to obtain enhanced catalytic performance.Especially with the advancement of single-atom catalysts(SACs),research on the coordination environment has been advanced to the atomic level.The surrounding coordination atoms of central metal atoms play important roles in their catalytic activity,selectivity and stability.In recent years,remarkable improvements of the catalytic performance of SACs have been achieved by the tailoring of coordination atoms,coordination numbers and second-or higher-coordination shells,which provided new opportunities for the further development of SACs.In this review,the characterization of coordination environment,tailoring of the local coordination environment,and their related adjustable catalytic performance will be discussed.We hope this review will provide new insights on further research of SACs.
文摘以离心压缩机变工况性能换算、特性曲线变转速二次拟合、基于BWRS方程的气体物性计算为理论基础,以NetBeans IDE 6.7为开发平台,结合Excel,采用Java语言开发了离心压缩机性能评价软件。软件能够准确计算与压缩机工作过程相关的气体物性参数,实现电子图像版压缩机特性曲线的数字化,可对不同入口条件下的特性曲线进行换算及变转速拟合,确定压缩机的流量控制界限。以某天然气长输管道首站的历史运行数据为依据,验证了软件计算结果的准确性。该软件可用于优化压气站运行方案。
基金supported by the Tianjin Natural Science Foundation of China(Nos.20JCZDJC00280 and 20JCYBJC00380).
文摘The relationship mechanism between the material pore structures and cathodic iodine chemistry plays a vital role in efficient Zn-I_(2) batteries,but is unclear,retarding further advances.This work innovatively indicates a great contribution of∼2.5nm pore structure of nanocarbons to efficient iodine adsorption,rapid I^(−)↔I_(2) conversion,and polyiodide inhibition,via scrupulously designing catalysts with controllable pore sizes systematically.The I_(2)-loading within the designed nitrogen-doped nanocarbons can reach up to as high as 60.8 wt%.The batteries based on the cathode deliver impressive performances with a large capacity of 178.8 mAh/g and long-term cycling stability more than 4000 h at 5.0 C.Notably,these is no polyiodide such as I_(3)−and I_(5)−detected during the charge-discharge processes from comprehensive electrochemical cyclic voltammetry,X-ray photoelectron spectroscopy,and Raman technique.This work provides a novel knowledge-guided concept for rational pore design,promising better Zn-I_(2) batteries,which is also hoped to benefit other advanced energy technologies,such as Li-S,Li-ion,and Al-I_(2) batteries.
