Gas phase HeI photoelectron spectroscopy(UPS) yields a lot of information on the electronic structures, the conformations and the bonding characters of the studied molecules. Photoelectron spectra of some forked conju...Gas phase HeI photoelectron spectroscopy(UPS) yields a lot of information on the electronic structures, the conformations and the bonding characters of the studied molecules. Photoelectron spectra of some forked conjugative systems have been reported. And their experimental and theoretical basis on the rule of homologous linearity as well as molecular orbital characters of carbonyl group as a separative group have also been pointed out. In this note the UPS studies on some α-cyano ω-heterocyclic polyenic nitriles展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘Gas phase HeI photoelectron spectroscopy(UPS) yields a lot of information on the electronic structures, the conformations and the bonding characters of the studied molecules. Photoelectron spectra of some forked conjugative systems have been reported. And their experimental and theoretical basis on the rule of homologous linearity as well as molecular orbital characters of carbonyl group as a separative group have also been pointed out. In this note the UPS studies on some α-cyano ω-heterocyclic polyenic nitriles
