The corrosion resistance of weathering bridge steels containing conventional contents of Ni(0.20 wt%, 0.42 wt%, 1.50 wt%) and a higher content of Ni(3.55 wt%) in a simulated hot and humid coastal-industrial atmosphere...The corrosion resistance of weathering bridge steels containing conventional contents of Ni(0.20 wt%, 0.42 wt%, 1.50 wt%) and a higher content of Ni(3.55 wt%) in a simulated hot and humid coastal-industrial atmosphere was investigated by corrosion depth loss, scanning electron microscopy–energy-dispersive X-ray spectroscopy, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and electrochemical methods. The results showed that, with increasing Ni content, the mechanical properties of the bridge steel were markedly improved, the welding parameters were satisfactory at room temperature, and the corrosion resistance was enhanced. When the Ni content was low(≤0.42 wt%), the crystallization process of the corrosion products was substantially promoted, enhancing the stability of the rust layer. When the Ni content was higher(~3.55 wt%), the corrosion reaction of the steel quickly reached a balance, because the initial rapid corrosion induced the formation of a protective rust layer in the early stage. Simultaneously, NiO and NiFe_2O_4 were generated in large quantities; they not only formed a stable, compact, and continuous oxide protective layer, but also strongly inhibited the transformation process of the corrosion products. This inhibition reduced the structural changes in the rust layer, thereby enhancing the protection. However, when the Ni content ranged from 0.42 wt% to 1.50 wt%, the corrosion resistance of the bridge steel increased only slightly.展开更多
SAW308L submerged arc welding wire and SJ601A submerged arc welding flux were selected to weld the 12 mm 08Cr19MnNi3Cu2N low nickel and high nitrogen austenitic stainless steel plates with three different welding heat...SAW308L submerged arc welding wire and SJ601A submerged arc welding flux were selected to weld the 12 mm 08Cr19MnNi3Cu2N low nickel and high nitrogen austenitic stainless steel plates with three different welding heat input,and microstructure,tensile properties,microhardness and corrosion properties of the welded joints were studied.The results show that no defects are found in the three groups of welded joints,and the welded joints have better performance.The tensile strength of 08Cr19MnNi3Cu2N stainless steel welded joints with different heat input is slightly lower than that of the base metal,and fracture occurs in the weld zone,and the hardness of the weld zone is lower than that of the base metal.The weld microstructure of stainless steel welded joints with different heat input is composed of austenite+δferrite,and ferrite is uniformly distributed in austenite.With the increase of the welding heat input,the ferrite content in the weld zone decrease gradually,the grain size in the thermal affected zone increase gradually,and the impact toughness reduce.展开更多
基金financially supported by the National Natural Science Foundation of China (No. 51304040)the Fundamental Research Funds for the Central Universities (No. N150204008)
文摘The corrosion resistance of weathering bridge steels containing conventional contents of Ni(0.20 wt%, 0.42 wt%, 1.50 wt%) and a higher content of Ni(3.55 wt%) in a simulated hot and humid coastal-industrial atmosphere was investigated by corrosion depth loss, scanning electron microscopy–energy-dispersive X-ray spectroscopy, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and electrochemical methods. The results showed that, with increasing Ni content, the mechanical properties of the bridge steel were markedly improved, the welding parameters were satisfactory at room temperature, and the corrosion resistance was enhanced. When the Ni content was low(≤0.42 wt%), the crystallization process of the corrosion products was substantially promoted, enhancing the stability of the rust layer. When the Ni content was higher(~3.55 wt%), the corrosion reaction of the steel quickly reached a balance, because the initial rapid corrosion induced the formation of a protective rust layer in the early stage. Simultaneously, NiO and NiFe_2O_4 were generated in large quantities; they not only formed a stable, compact, and continuous oxide protective layer, but also strongly inhibited the transformation process of the corrosion products. This inhibition reduced the structural changes in the rust layer, thereby enhancing the protection. However, when the Ni content ranged from 0.42 wt% to 1.50 wt%, the corrosion resistance of the bridge steel increased only slightly.
文摘SAW308L submerged arc welding wire and SJ601A submerged arc welding flux were selected to weld the 12 mm 08Cr19MnNi3Cu2N low nickel and high nitrogen austenitic stainless steel plates with three different welding heat input,and microstructure,tensile properties,microhardness and corrosion properties of the welded joints were studied.The results show that no defects are found in the three groups of welded joints,and the welded joints have better performance.The tensile strength of 08Cr19MnNi3Cu2N stainless steel welded joints with different heat input is slightly lower than that of the base metal,and fracture occurs in the weld zone,and the hardness of the weld zone is lower than that of the base metal.The weld microstructure of stainless steel welded joints with different heat input is composed of austenite+δferrite,and ferrite is uniformly distributed in austenite.With the increase of the welding heat input,the ferrite content in the weld zone decrease gradually,the grain size in the thermal affected zone increase gradually,and the impact toughness reduce.
