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高应变率压缩下纳米孔洞对金属铝塑性变形的影响研究 被引量:7
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作者 第伍旻杰 胡晓棉 《物理学报》 SCIE EI CAS CSCD 北大核心 2015年第17期1-8,共8页
本文利用分子动力学模拟方法研究了含纳米孔洞金属铝在[110]晶向高应变率单轴压缩下弹塑性变形的微观过程.对比单孔洞和完整单晶的模型,讨论了多孔金属的应力应变关系及其位错发展规律.研究结果表明,对于多孔模型的位错积累过程,位错密... 本文利用分子动力学模拟方法研究了含纳米孔洞金属铝在[110]晶向高应变率单轴压缩下弹塑性变形的微观过程.对比单孔洞和完整单晶的模型,讨论了多孔金属的应力应变关系及其位错发展规律.研究结果表明,对于多孔模型的位错积累过程,位错密度随应变的增加可大致分为两个线性阶段.由同一个孔洞生成的位错在相互靠近过程中,其滑移速度越来越小;随着位错继续滑移,源自不同孔洞的位错之间开始交叉相互作用导致应变硬化.达到流变峰应力之后又由于位错密度增殖速率升高发生软化.当应变增加到11.8%时,所有孔洞几乎完全坍缩,并观察到在此过程中有棱位错生成. 展开更多
关键词 分子动力学 纳米孔洞 纳米多孔 位错
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Hydrogen-induced cracking by nanovoids in 310 stainless steel
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作者 黄一中 陈奇志 +1 位作者 王燕斌 褚武扬 《Science China(Technological Sciences)》 SCIE EI CAS 1998年第4期372-382,共11页
Hydrogen-induced cracking was investigated by TEM in-situ tension in hydrogenated stainless steel of type 310. It was found experimentally that hydrogen-induced cracking happens via nanovoid nucleation followed by qua... Hydrogen-induced cracking was investigated by TEM in-situ tension in hydrogenated stainless steel of type 310. It was found experimentally that hydrogen-induced cracking happens via nanovoid nucleation followed by quasi-cleavage along {111} planes when C H is higher. Otherwise, in the case of lower C H, hydrogen enhances ductile fracture via hydrogen-enhanced microvoid nucleation, growth and connection. A new model was proposed based on the present experiments. Dislocations break away from defect atmospheres and move away from the DFZ, leaving vacancy and hydrogen clusters along {111} planes. Hydrogen tends to combine with vacancy clusters and initiate nanovoids along {111} planes. Dense nanovoids connect each other, resulting in brittle cracking. Scattered nanovoids grow into microvoids or even macrovoids, leading to ductile fracture. 展开更多
关键词 STAINLESS STEEL TEM hydrogen-induced CRACKING nanovoid dislocation.
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Effect of void size and Mg contents on plastic deformation behaviors of Al-Mg alloy with pre-existing void:Molecular dynamics study
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作者 Ning Wei Ai-Qiang Shi +3 位作者 Zhi-Hui Li Bing-Xian Ou Si-Han Zhao Jun-Hua Zhao 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第6期580-588,共9页
The plastic deformation properties of cylindrical pre-void aluminum-magnesium(Al-Mg)alloy under uniaxial tension are explored using molecular dynamics simulations with embedded atom method(EAM)potential.The factors of... The plastic deformation properties of cylindrical pre-void aluminum-magnesium(Al-Mg)alloy under uniaxial tension are explored using molecular dynamics simulations with embedded atom method(EAM)potential.The factors of Mg content,void size,and temperature are considered.The results show that the void fraction decreases with increasing Mg in the plastic deformation,and it is almost independent of Mg content when Mg is beyond 5%.Both Mg contents and stacking faults around the void affect the void growth.These phenomena are explained by the dislocation density of the sample and stacking faults distribution around the void.The variation trends of yield stress caused by void size are in good agreement with the Lubarda model.Moreover,temperature effects are explored,the yield stress and Young’s modulus obviously decrease with temperature.Our results may enrich and facilitate the understanding of the plastic mechanism of Al-Mg with defects or other alloys. 展开更多
关键词 Al-Mg alloys molecular dynamics nanovoid plastic deformation
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纳米孔洞对Ni/Ni_(3)Al纳米线形变行为影响的原子模拟
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作者 阳喜元 《计算物理》 CSCD 北大核心 2022年第6期727-732,共6页
结合改进型嵌入原子势函数,利用分子动力学模拟Ni/Ni_(3)Al纳米线在单轴拉伸应变条件下的形变过程,研究其内在机制。结果表明:Ni/Ni_(3)Al纳米线的形变过程分为弹性、塑性形变两个阶段。在弹性形变阶段,其应力随着形变量变化呈线性关系... 结合改进型嵌入原子势函数,利用分子动力学模拟Ni/Ni_(3)Al纳米线在单轴拉伸应变条件下的形变过程,研究其内在机制。结果表明:Ni/Ni_(3)Al纳米线的形变过程分为弹性、塑性形变两个阶段。在弹性形变阶段,其应力随着形变量变化呈线性关系,通过拟合发现其弹性模量约等于120 GPa,明显低于相应的块体材料结果。在此基础上,重点分析纳米孔洞对Ni/Ni_(3)Al纳米线形变行为的影响,发现纳米孔洞的存在有效地破坏合金材料内部的微观结构,使得晶格位错交割无法形成,导致晶格滑移比较容易产生,从而降低合金纳米线的弹性模量等。 展开更多
关键词 形变行为 纳米孔洞 Ni/Ni_(3)Al纳米线 原子模拟
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SiO_2-TiO_2中空型界面光催化剂的制备及性能 被引量:3
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作者 许章炼 王晟 +2 位作者 王掏 王维 陈文兴 《催化学报》 SCIE CAS CSCD 北大核心 2008年第10期987-991,共5页
采用十八烷基三乙氧基硅烷对TiO2和核壳中空型纳米粒子SiO2-TiO2进行了壳表面疏水烷基化修饰,制备出新型界面光催化剂,并用IR和XRD进行表征.在紫外光照射下,考察了两种界面光催化剂的光稳定性,并以弱酸性黄G溶液的界面光降解为模型反应... 采用十八烷基三乙氧基硅烷对TiO2和核壳中空型纳米粒子SiO2-TiO2进行了壳表面疏水烷基化修饰,制备出新型界面光催化剂,并用IR和XRD进行表征.在紫外光照射下,考察了两种界面光催化剂的光稳定性,并以弱酸性黄G溶液的界面光降解为模型反应,考察了催化剂的光催化活性.结果表明,长链烷基成功接枝在了两种纳米粒子表面,且改性前后晶型无变化.与TiO2界面光催化剂相比,SiO2-TiO2界面光催化剂不仅具有优异的界面光稳定性,同时在无搅拌状态下对弱酸性黄G溶液也有良好的光催化活性. 展开更多
关键词 二氧化钛 二氧化硅 中空结构 界面 纳米粒子 光催化
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