文章通过对液相水合生产优质低盐重质纯碱引进工艺技术及设备选型进行了深入探讨和技术研究,在与大型碱厂采用传统固相水合生产工艺进行技术对比的基础上,论证了在海拔高度3 000 m、大气压强70.8 k Pa的高原地区条件下,首创引进高原地...文章通过对液相水合生产优质低盐重质纯碱引进工艺技术及设备选型进行了深入探讨和技术研究,在与大型碱厂采用传统固相水合生产工艺进行技术对比的基础上,论证了在海拔高度3 000 m、大气压强70.8 k Pa的高原地区条件下,首创引进高原地区液相水合生产优质低盐重质纯碱技术,并且实现了生产能力扩大化,达到了节能高效的综合效益。展开更多
Structural rejuvenation is vital and attractive for modulating the energetic state and structural heterogeneity of bulk metallic glasses(BMGs). In this paper, we show that cooling a BMG from a supercooled liquid regio...Structural rejuvenation is vital and attractive for modulating the energetic state and structural heterogeneity of bulk metallic glasses(BMGs). In this paper, we show that cooling a BMG from a supercooled liquid region at laboratory rates can reverse the relaxation enthalpy lost during the preceding structural relaxation. Increasing the cooling rate is beneficial for enhancing atomic mobility and dynamic mechanical relaxation intensity. Therefore, this rejuvenation methodology promotes tailoring the mechanical properties of BMGs and provides a comprehensive understanding of the rejuvenation mechanism.展开更多
The nanocrystallization behaviour of a bulk Zr-based metallic glass subjected to compressive stress is investigated in the supercooled liquid region. Compared with annealing treatments without compressive stress, comp...The nanocrystallization behaviour of a bulk Zr-based metallic glass subjected to compressive stress is investigated in the supercooled liquid region. Compared with annealing treatments without compressive stress, compressive deformation promotes the development of nucleation and suppresses the coarsening of nanocrystallites at high temperatures.展开更多
We have fabricated an unexpected type of supported planar bilayer composed of receptor phospholipids and single-chained diacetylenes as fluorogenic reporters using protruded anchor moieties with a positive terminal ch...We have fabricated an unexpected type of supported planar bilayer composed of receptor phospholipids and single-chained diacetylenes as fluorogenic reporters using protruded anchor moieties with a positive terminal charge.Nanoscale topographical and surface thermodynamic analyses,as well as molecular dynamics simulations,revealed the coexistence of well-dispersed liquid-condensed(L_(c))domains forming nano-islands and liquid-expanded(L_(e))region in the planar bilayer,enhancing sensitivity against a prototype of ubiquitous membrane-associated antimicrobial peptides,melittin.The L_(e)regions,acting as target receptors,enabled sensitive detection as the melittin adsorbed and inserted into these regions due to strong hydrophobic interactions between phospholipids and melittin.The L_(c)domains,serving as signal reporters,enabled diacetylenes to assemble,polymerize,and fluoresce in response to the insertion of melittin into the L_(e)regions.Thus,biphasic nanodomains of the planar lipid bilayer finally endowed this sensor system with a detection range of 100μMto 50 nM and a limit of detection(LOD)of∼37 nM for melittin.This exceeded the operational performance of the colorimetric polydiacetylene vesicle solution 45 times,which reportedly ranged from 100 to 4μM with an LOD of∼1.7μM.展开更多
Bulk metallic glasses (BMGs) with large supercooled liquid region are promising materials for superplastic forming. In this paper, we demonstrate a microstructure-based strategy to pinpoint the composition with the la...Bulk metallic glasses (BMGs) with large supercooled liquid region are promising materials for superplastic forming. In this paper, we demonstrate a microstructure-based strategy to pinpoint the composition with the largest supercooled liquid region in La 86 x Al 14 Cu x (x=16 at%-20 at%) metallic glass system. By monitoring the changes in crystallization behavior of the glassy alloys with composition to search for the alloys exhibiting eutectic crystallization, the glassy alloys with the largest supercooled liquid region in the given alloy system can be found. The metallic glasses with Cu contents of 16 at%-19 at% exhibited two crystallization peaks, and the primary crystallization product was identified to be α-La by means of DSC, XRD and TEM. The increase in Cu content resulted in the decay of the primary crystallization peak and the increase in onset temperature of crystallization, leading to the enlargement of supercooled liquid region. By further suppressing the α-La primary crystallization with increasing Cu content up to 20 at%, the eutectic crystallization of α-La and LaCu 13 through one crystallization reaction occurred upon heating, where the largest supercooled liquid region of 65 K for La 66 Al 14 Cu 20 glassy alloy was located. This study indicats that, in a given glassy alloy system, a larger supercooled liquid region can be achieved by optimizing the alloy compositions to suppress the primary crystallization.展开更多
文摘文章通过对液相水合生产优质低盐重质纯碱引进工艺技术及设备选型进行了深入探讨和技术研究,在与大型碱厂采用传统固相水合生产工艺进行技术对比的基础上,论证了在海拔高度3 000 m、大气压强70.8 k Pa的高原地区条件下,首创引进高原地区液相水合生产优质低盐重质纯碱技术,并且实现了生产能力扩大化,达到了节能高效的综合效益。
基金supported by the National Natural Science Foundation of China (Grant Nos. 51971178 and 52271153)financially supported by National Natural Science Foundation of China (Grant No. 12072344)+4 种基金the Natural Science Basic Research Plan for Distinguished Young Scholars in Shaanxi Province(Grant No. 2021JC-12)the Natural Science Foundation of Chongqing(Grant No. cstc2020jcyj-jq X0001)sponsored by the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University (Grant No. CX2021015)the Youth Innovation Promotion Association of the Chinese Academy of Sciencesfinancial support from Research Grant Council (RGC) and the Hong Kong government through the General Research Fund (GRF)(Grant Nos.U11200719 and U11213118)。
文摘Structural rejuvenation is vital and attractive for modulating the energetic state and structural heterogeneity of bulk metallic glasses(BMGs). In this paper, we show that cooling a BMG from a supercooled liquid region at laboratory rates can reverse the relaxation enthalpy lost during the preceding structural relaxation. Increasing the cooling rate is beneficial for enhancing atomic mobility and dynamic mechanical relaxation intensity. Therefore, this rejuvenation methodology promotes tailoring the mechanical properties of BMGs and provides a comprehensive understanding of the rejuvenation mechanism.
基金Supported by the Science Foundation for Excellent Young Scholars of Heilongjiang Province under Grant No JC-05-11, the Program for New Century Excellent Talents in University of China under Grant No NCET-04-0322, and the Specialized Research Fund for the Doctoral Programme of Higher Education of China under Grant No 20040213049）
文摘The nanocrystallization behaviour of a bulk Zr-based metallic glass subjected to compressive stress is investigated in the supercooled liquid region. Compared with annealing treatments without compressive stress, compressive deformation promotes the development of nucleation and suppresses the coarsening of nanocrystallites at high temperatures.
基金This work was supported by the National Research Foundation of Korea(grant nos.NRF-2021R1A2C3009955 and 2017M3D1A1039421)and a Korea University Grant.
文摘We have fabricated an unexpected type of supported planar bilayer composed of receptor phospholipids and single-chained diacetylenes as fluorogenic reporters using protruded anchor moieties with a positive terminal charge.Nanoscale topographical and surface thermodynamic analyses,as well as molecular dynamics simulations,revealed the coexistence of well-dispersed liquid-condensed(L_(c))domains forming nano-islands and liquid-expanded(L_(e))region in the planar bilayer,enhancing sensitivity against a prototype of ubiquitous membrane-associated antimicrobial peptides,melittin.The L_(e)regions,acting as target receptors,enabled sensitive detection as the melittin adsorbed and inserted into these regions due to strong hydrophobic interactions between phospholipids and melittin.The L_(c)domains,serving as signal reporters,enabled diacetylenes to assemble,polymerize,and fluoresce in response to the insertion of melittin into the L_(e)regions.Thus,biphasic nanodomains of the planar lipid bilayer finally endowed this sensor system with a detection range of 100μMto 50 nM and a limit of detection(LOD)of∼37 nM for melittin.This exceeded the operational performance of the colorimetric polydiacetylene vesicle solution 45 times,which reportedly ranged from 100 to 4μM with an LOD of∼1.7μM.
基金supported by the National Natural Science Foundation of China (Grant Nos. 50631010, 50771005 and 50771006)the National Basic Research Program of China (Grant No. 2007CB613900)
文摘Bulk metallic glasses (BMGs) with large supercooled liquid region are promising materials for superplastic forming. In this paper, we demonstrate a microstructure-based strategy to pinpoint the composition with the largest supercooled liquid region in La 86 x Al 14 Cu x (x=16 at%-20 at%) metallic glass system. By monitoring the changes in crystallization behavior of the glassy alloys with composition to search for the alloys exhibiting eutectic crystallization, the glassy alloys with the largest supercooled liquid region in the given alloy system can be found. The metallic glasses with Cu contents of 16 at%-19 at% exhibited two crystallization peaks, and the primary crystallization product was identified to be α-La by means of DSC, XRD and TEM. The increase in Cu content resulted in the decay of the primary crystallization peak and the increase in onset temperature of crystallization, leading to the enlargement of supercooled liquid region. By further suppressing the α-La primary crystallization with increasing Cu content up to 20 at%, the eutectic crystallization of α-La and LaCu 13 through one crystallization reaction occurred upon heating, where the largest supercooled liquid region of 65 K for La 66 Al 14 Cu 20 glassy alloy was located. This study indicats that, in a given glassy alloy system, a larger supercooled liquid region can be achieved by optimizing the alloy compositions to suppress the primary crystallization.
