Solubility of benzoic acid, terephthalic acid and 2,6-naphthalene dicarboxylic acid in water, acetic acid, N.N-dimethylformamide, N.N-dimethylacetamide, dimethyl sulphoxide and Ar-methyl-2-ketopyrrolidine were measure...Solubility of benzoic acid, terephthalic acid and 2,6-naphthalene dicarboxylic acid in water, acetic acid, N.N-dimethylformamide, N.N-dimethylacetamide, dimethyl sulphoxide and Ar-methyl-2-ketopyrrolidine were measured by dynamic method. The solubilities were calculated by UNIFAC group contribution method, in which new groups, BCCOOH and NCCOOH, were introduced to express the activity coefficients of aromatic acids and new interaction parameters of the new groups were expressed as the function of temperature, which were determined from the experimental data. The new interaction parameters provided good calculated result. The experimental data were also correlated with Wilson and y-h models, and results were compared with present UNIFAC model.展开更多
Quantitatively correcting the unconfined compressive strength for sample disturbance is an important research project in the practice of ocean engineering and geotechnical engineering. In this study, the specimens of ...Quantitatively correcting the unconfined compressive strength for sample disturbance is an important research project in the practice of ocean engineering and geotechnical engineering. In this study, the specimens of undisturbed natural marine clay obtained from the same depth at the same site were deliberately disturbed to different levels. Then, the specimens with different extents of sample disturbance were trimmed for both oedometer tests and unconfined compression tests. The degree of sample disturbance SD is obtained from the oedometer test data. The relationship between the unconfined compressive strength q u and SD is studied for investigating the effect of sample disturbance on q u. It is found that the value of q u decreases linearly with the increase in SD. Then, a simple method of correcting q u for sample disturbance is proposed. Its validity is also verified through analysis of the existing published data.展开更多
A meshless numerical simulation method, the moving-particle semi-implicit method （MPS） is presented in this paper to study the sloshing phenomenon in ocean and naval engineering. As a meshless method, MPS uses parti...A meshless numerical simulation method, the moving-particle semi-implicit method （MPS） is presented in this paper to study the sloshing phenomenon in ocean and naval engineering. As a meshless method, MPS uses particles to replace the mesh in traditional methods, the governing equations are discretized by virtue of the relationship of particles, and the Poisson equation of pressure is solved by incomplete Cholesky conjugate gradient method （ICCG）, the free surface is tracked by the change of numerical density. A numerical experiment of viscous liquid sloshing tank was presented and compared with the result got by the difference method with the VOF, and an additional modification step was added to make the simulation more stable. The results show that the MPS method is suitable for the simulation of viscous liquid sloshing, with the advantage in arranging the particles easily, especially on some complex curved surface.展开更多
文摘Solubility of benzoic acid, terephthalic acid and 2,6-naphthalene dicarboxylic acid in water, acetic acid, N.N-dimethylformamide, N.N-dimethylacetamide, dimethyl sulphoxide and Ar-methyl-2-ketopyrrolidine were measured by dynamic method. The solubilities were calculated by UNIFAC group contribution method, in which new groups, BCCOOH and NCCOOH, were introduced to express the activity coefficients of aromatic acids and new interaction parameters of the new groups were expressed as the function of temperature, which were determined from the experimental data. The new interaction parameters provided good calculated result. The experimental data were also correlated with Wilson and y-h models, and results were compared with present UNIFAC model.
文摘Quantitatively correcting the unconfined compressive strength for sample disturbance is an important research project in the practice of ocean engineering and geotechnical engineering. In this study, the specimens of undisturbed natural marine clay obtained from the same depth at the same site were deliberately disturbed to different levels. Then, the specimens with different extents of sample disturbance were trimmed for both oedometer tests and unconfined compression tests. The degree of sample disturbance SD is obtained from the oedometer test data. The relationship between the unconfined compressive strength q u and SD is studied for investigating the effect of sample disturbance on q u. It is found that the value of q u decreases linearly with the increase in SD. Then, a simple method of correcting q u for sample disturbance is proposed. Its validity is also verified through analysis of the existing published data.
基金the National Natural Science Foundation under Grant No.50579035
文摘A meshless numerical simulation method, the moving-particle semi-implicit method （MPS） is presented in this paper to study the sloshing phenomenon in ocean and naval engineering. As a meshless method, MPS uses particles to replace the mesh in traditional methods, the governing equations are discretized by virtue of the relationship of particles, and the Poisson equation of pressure is solved by incomplete Cholesky conjugate gradient method （ICCG）, the free surface is tracked by the change of numerical density. A numerical experiment of viscous liquid sloshing tank was presented and compared with the result got by the difference method with the VOF, and an additional modification step was added to make the simulation more stable. The results show that the MPS method is suitable for the simulation of viscous liquid sloshing, with the advantage in arranging the particles easily, especially on some complex curved surface.
