Neodymium-based heterocyclic Schiff base complex was prepared and applied for the coordination polymerization of isoprene. This complex polymerized isoprene to afford products featuring high cis-1,4 stereospecificity ...Neodymium-based heterocyclic Schiff base complex was prepared and applied for the coordination polymerization of isoprene. This complex polymerized isoprene to afford products featuring high cis-1,4 stereospecificity （ca. 95%） and high molecular weight （ca, 10^5） in the presence of the triisobutyl aluminium （AliBu3） as cocatalyst, The microstructure of obtained polyisoprene was investigated by FTIR, 1^H NMR. Two different kinds of active centers in the catalyst system were examined by GPC method.展开更多
基金The authors are indebted to the financial supports of the National Natural Science Foundation of China （No.20774078 and the Key Program No.20434020）；the Special Funds for Major Basic Research Projects （G2005CB623802）.
文摘Neodymium-based heterocyclic Schiff base complex was prepared and applied for the coordination polymerization of isoprene. This complex polymerized isoprene to afford products featuring high cis-1,4 stereospecificity （ca. 95%） and high molecular weight （ca, 10^5） in the presence of the triisobutyl aluminium （AliBu3） as cocatalyst, The microstructure of obtained polyisoprene was investigated by FTIR, 1^H NMR. Two different kinds of active centers in the catalyst system were examined by GPC method.
