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Liquid-FEP-based U-tube triboelectric nanogenerator for harvesting water-wave energy 被引量:11
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作者 Lun Pan Jiyu Wang +5 位作者 Peihong Wang Ruijie Gao Yi-Cheng Wang Xiangwen Zhang Ji-Jun zou Zhong Lin Wang 《Nano Research》 SCIE EI CAS CSCD 2018年第8期4062-4073,共12页
Harvesting ambient mechanical energy is a key technology for realizing self-powered electronics. With advantages of stability and durabilid, a liquid-solid-based triboelectric nanogenerator (TENG) has recently drawn... Harvesting ambient mechanical energy is a key technology for realizing self-powered electronics. With advantages of stability and durabilid, a liquid-solid-based triboelectric nanogenerator (TENG) has recently drawn much attention. However, the impacts of liquid properties on the TENG performance and the related working principle are still unclear. We assembled herein a U-tube TENG based on the liquid-solid mode and applied 11 liquids to study the effects of liquid properties on the TENG output performance. The results confirmed that the key factors influencing the output are polarity, dielectric constant, and affinity to fluorinated ethylene propylene (FEP). Among the 11 liquids, the pure water-based U-tube TENG exhibited the best output with an open-circuit voltage (Voc) of 81.7 V and a short-circuit current (Isc) of 0.26 μA for the shaking mode (0.5 Hz), which can further increase to 93.0 V and 0.48 μA, respectively, for the horizontal shifting mode (1.25 Hz). The U-tube TENG can be utilized as a self-powered concentration sensor (component concentration or metal ion concentration) for an aqueous solution with an accuracy higher than 92%. Finally, an upgraded sandwich-like water-FEP U-tube TENG was applied to harvest water-wave energy, showing a high output with Voc of 350 V, Isc of 1.75 μA, and power density of 2.04 W/m3. We successfully lighted up 60 LEDs and powered a temperature-humidity meter. Given its high output performance, the water-FEP U-tube TENG is a very promising approach for harvesting water-wave energy for self-powered electronics. 展开更多
关键词 triboelectric nanogenerator FEP U tube liquid properties ionic aqueous solution water-wave energy
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离子液体水溶液中2-甲基氮杂芳烃苄位C(sp^3)—H官能化反应 被引量:2
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作者 艾锋 谢宗波 +2 位作者 姜国芳 季久健 乐长高 《有机化学》 SCIE CAS CSCD 北大核心 2018年第8期2174-2181,共8页
以中性离子液体水溶液为反应介质,无需催化剂的条件下,通过2-甲基氮杂芳烃苄位C(sp^3)—H与缺电子烯烃之间的加成反应,以良好产率合成了一系列氮杂芳烃衍生物.该方法操作简单,条件温和,不仅拓展了离子液体在氮杂芳烃的C(sp^3)—H官能化... 以中性离子液体水溶液为反应介质,无需催化剂的条件下,通过2-甲基氮杂芳烃苄位C(sp^3)—H与缺电子烯烃之间的加成反应,以良好产率合成了一系列氮杂芳烃衍生物.该方法操作简单,条件温和,不仅拓展了离子液体在氮杂芳烃的C(sp^3)—H官能化反应中的应用,对绿色化学的发展也有积极的推动作用. 展开更多
关键词 离子液体水溶液 缺电子烯烃 苄位C(sp^3)—H官能化 2-甲基氮杂芳烃
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功能离子液体水溶液吸收CO_2的研究
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作者 姚辉 焦阳 +1 位作者 刘红晶 李冬 《应用化工》 CAS CSCD 北大核心 2015年第9期1639-1642,共4页
采用自制的功能离子液体1-2-胺乙基丁基咪唑溴盐([NH2ebim]Br)、1-2-胺乙基甲基咪唑溴盐([NH2emim]Br)的水溶液作为吸收剂,进行吸收CO2的研究。考察了不同浓度的功能离子液体水溶液吸收CO2的吸收速率,温度对CO2的吸收速率的影响,不同功... 采用自制的功能离子液体1-2-胺乙基丁基咪唑溴盐([NH2ebim]Br)、1-2-胺乙基甲基咪唑溴盐([NH2emim]Br)的水溶液作为吸收剂,进行吸收CO2的研究。考察了不同浓度的功能离子液体水溶液吸收CO2的吸收速率,温度对CO2的吸收速率的影响,不同功能离子液体水溶液对吸收速率的影响,以及吸收剂的再生效率,并探讨了功能离子液体水溶液吸收CO2的机理。结果表明,功能离子液体水溶液实现了对CO2的化学吸收,吸收速率随着功能离子液体浓度和温度的增加而增加,而功能离子液体阳离子碳链长短对水溶液吸收CO2的速率影响不显著。实验中每摩尔功能离子液体吸收的CO2大于0.5 mol,其反应机理被提出。 展开更多
关键词 CO2 吸收 功能离子液体水溶液 有机醇胺
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