Photocatalyst was prepared by immobilizing TiO2 on glass beads using the traditional sol-gel method. Ultraviolet light （UV） produced by pulsed streamer discharge was then used to induce photocatalytic activity of Ti...Photocatalyst was prepared by immobilizing TiO2 on glass beads using the traditional sol-gel method. Ultraviolet light （UV） produced by pulsed streamer discharge was then used to induce photocatalytic activity of TiO2 photocatalyst. Decolouration efficiency of the representative azo dye （acid orange 7, AOT） was investigated using the synergistic system of pulsed streamer discharge plasma and TiO2 photocatalysis. The obtained results showed that the decolouration rate of AO7 could be increased by 16.7% under the condition of adding supported TiO2 in the pulsed streamer discharge system, compared to that in the sole pulsed streamer discharge plasma system, due to the synergistic effect of pulsed streamer discharge and TiO2 photocatalysis induced by pulsed streamer discharge. The synergistic system of pulsed streamer discharge and TiO2 photocatalyst was found to have more reactive radicals for degradation of organic compounds in water.展开更多
The photocatalytic degradation of the synthetic textile dye Reactive Yellow 145 (RY 145) in aqueous solution, using TiO2 coated non-woven fibers as photocatalyst, under UV-lamp irradiation, was studied. The effects of...The photocatalytic degradation of the synthetic textile dye Reactive Yellow 145 (RY 145) in aqueous solution, using TiO2 coated non-woven fibers as photocatalyst, under UV-lamp irradiation, was studied. The effects of the operational parameters such as initial dye concentration, pH, addition of oxidant hydrogen peroxide and addition of ethanol on the reaction rate were investigated. The effect of some inorganic ions such as and , commonly present in real effluents, on the photodegradation of RY 145 was also examined. The experimental results showed that the photocatalytic degradation rate was favoured by a high concentration of solution in respect to Langmuir-Hinshelwood model. The maximum rate of complete decolorization of RY 145 was observed in the acidic medium at pH 3. The presence of and anions led to an increase of the effectiveness of the photocatalytic degradation. However, the presence of and anions decreased differently the photodegradation reaction rate. TiO2/UV process was proved to be capable of the complete degradation of the RY 145.展开更多
基金supported by the National Natural Science Foundation Committee of China(No.20377006)Foundation of Education Ministry of China(No.2005141002)
文摘Photocatalyst was prepared by immobilizing TiO2 on glass beads using the traditional sol-gel method. Ultraviolet light （UV） produced by pulsed streamer discharge was then used to induce photocatalytic activity of TiO2 photocatalyst. Decolouration efficiency of the representative azo dye （acid orange 7, AOT） was investigated using the synergistic system of pulsed streamer discharge plasma and TiO2 photocatalysis. The obtained results showed that the decolouration rate of AO7 could be increased by 16.7% under the condition of adding supported TiO2 in the pulsed streamer discharge system, compared to that in the sole pulsed streamer discharge plasma system, due to the synergistic effect of pulsed streamer discharge and TiO2 photocatalysis induced by pulsed streamer discharge. The synergistic system of pulsed streamer discharge and TiO2 photocatalyst was found to have more reactive radicals for degradation of organic compounds in water.
文摘The photocatalytic degradation of the synthetic textile dye Reactive Yellow 145 (RY 145) in aqueous solution, using TiO2 coated non-woven fibers as photocatalyst, under UV-lamp irradiation, was studied. The effects of the operational parameters such as initial dye concentration, pH, addition of oxidant hydrogen peroxide and addition of ethanol on the reaction rate were investigated. The effect of some inorganic ions such as and , commonly present in real effluents, on the photodegradation of RY 145 was also examined. The experimental results showed that the photocatalytic degradation rate was favoured by a high concentration of solution in respect to Langmuir-Hinshelwood model. The maximum rate of complete decolorization of RY 145 was observed in the acidic medium at pH 3. The presence of and anions led to an increase of the effectiveness of the photocatalytic degradation. However, the presence of and anions decreased differently the photodegradation reaction rate. TiO2/UV process was proved to be capable of the complete degradation of the RY 145.
