Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some d...Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some drilling wells of deep water area close to the central depression belt, Miocene marine source rocks with better organic matter abundance and hydrocarbon generation have been found, which have achieved better source rock standard based on the analysis of geochemical charac- teristics. Although there are no exploratory wells in deep water area of the research region, through the comparative analysis of geochemical data of several typical exploratory wells respectively from shallow water area in the basin, central depression belt margin in deep-water area of the basin and Site 1148 of deep sea drilling in the South China Sea Basin, it reveals that the tendency of the quality of source rocks becomes positive gradually from delta to bathyal environment, which then becomes negative as in deep oceanic environment. Owing to the lack of terrestrial organic matter input, the important controlling factors of Miocene marine source rocks in the Qiongdongnan Basin are ocean productivity and preservation conditions of organic matter. The element geochemistry data indicate that the tendency of the paleoproductivity and the preservation conditions of organic matter become positive as water depth increase from shallow area to bathyal area close to central depression belt. So it is speculated that there must exist high quality source rocks in the central depression area where the preservation conditions of organic matter are much better. Besides, in theory, in oxygen-poor zone of oceanic environment at the water depth 400–1 000 m, the preservation conditions of organic matter are well thus forming high-quality marine source rocks. The result- ing speculation, it is reasonable to consider that there are high hydrocarbon generation potential source rocks in bathyal environment of the Qiongdongnan Basin, especially at th展开更多
The pore characteristics of shale reservoirs in the lower submember of Member 3 to upper submember of Member 4 of Shahejie Formation in Dongying sag are analyzed,influences of mineral content and organic matter conten...The pore characteristics of shale reservoirs in the lower submember of Member 3 to upper submember of Member 4 of Shahejie Formation in Dongying sag are analyzed,influences of mineral content and organic matter content on porosity and pore size are also investigated,and through the diagenetic thermal simulation experiment,the main pore evolution is further discussed.The results show that the pore structure of shale reservoirs is complex,the micron-nanometer pores can storage liquid hydrocarbons,and the free-phase crude oil is mainly distributed in intergranular dissolution pores of calcite,recrystallized intergranular pores,intergranular shrinkage fractures of clay mineral which have large pore size.Framework minerals and organic matter content directly influence porosity and pore size of shale reservoirs,relationship between porosity and content of felsic mineral as well as content of organic matter content is linear and positive,while relationship between content of carbonated mineral is negative.At the buried depth from 2500 to 3500 m,concentration of organic acid from hydrocarbon generation and expulsion of organic matter,increasing range of pressure coefficient,are well corresponding to highporosity intervals;pore formation in shale oil reservoirs are almost controlled by diagenetic evolution of clay minerals;framework storage spaces formed by carbonate grain crystals as well as intergranular and intergranular dissolution pores of carbonate increases porosity of shale oil reservoirs;local increase of porosity at the depth of 3500e3800 m is mainly caused by coupling of hydrocarbon-generating overpressure and dissolution,and size,distribution and connectivity of pores are enhanced obviously.展开更多
The well-preserved Mesoproterozoic succession in the North China platform consists mainly of three iithological associations including peritidal quartz sandstone, shallow marine and lagoonal dark to black shales, and ...The well-preserved Mesoproterozoic succession in the North China platform consists mainly of three iithological associations including peritidal quartz sandstone, shallow marine and lagoonal dark to black shales, and shallow epeiric carbonates, with a total thickness of up to 8 000 m. In addition to well-documented microplants, macroalgae, and microbial buildups, abundant microbially induced sedimentary structures （MISS） and mat-related sediments have been recognized in these rocks. Intensive microbial mat layers and MISS are especially well preserved in the carbonates of the upper Gaoyuzhuang （高于庄） （ca. 1.5 Ga） and lower Wumishan （雾迷山） （ca. 1.45 Ga） formations, indicating diversified microbial activities and a high organic production. In these petrified biomats, putative microbial fossils （both coccoidal and filamentous） and framboidal pyrites have been identified. The abundance of authigenic carbonate minerals in the host rocks, such as, acicular aragonites, rosette barites, radial siderites, ankerites, and botryoidal carbonate cements, suggests authigenic carbonate precipitation from anaerobic oxidation of methane （AOM） under anoxic/euxinic conditions. Warm climate and anoxic/euxinic conditions in the Mesoproterozoic oceans may have facilitated high microbial productivity and organic burial in sediments. Although authigenic carbonate cements may record carbonate precipitation from anaerobic methane oxidation, gas blister （or dome） structures may indicate gas release from active methanogenesis during shallow burial. Bituminous fragments in mat-related carbonates also provide evidence for hydrocarbon generation. Under proper conditions, the Mesoproterozoic mat-rich carbonates will have the potential for hydrocarbon generation and serve as source rocks. On the basis of petrified biomats, a rough estimation suggests that the Mesoproterozoic carbonates of the North China platform might have a hydrocarbon production potential in the order of 10 ×10^8 t.展开更多
The lower Tertiary Eh3 is divided into two sections： the upper members of Eh3 and the lower members of Eh3 in the Biyang Depression. The first section is generally regarded as a key target of oil and gas exploration,...The lower Tertiary Eh3 is divided into two sections： the upper members of Eh3 and the lower members of Eh3 in the Biyang Depression. The first section is generally regarded as a key target of oil and gas exploration, but the resource potential of the lower members of Eh3 has been neglected. We have obtained new knowledge about Eh3 from comprehensive geological research. The lower members of Eh3 are high-quality and main source rocks, which have good oil and gas resource potential. This is a new direction for oil and gas exploration. The geochemistry characteristics of source rocks of the lower members of Eh3 in the lower Tertiary of the Biyang Depression were analyzed in detail. A basin modeling method was applied to hydrocarbon generation of the lower and upper members of Eh3 source rocks, the oil and gas resource potential was comparatively analyzed, and then favorable tectonic zones were pointed out. In the lower members of Eh3, a set of semi-deep lake to deep lake high-quality source rocks occurs rich in algae organisms, mainly of type II1, with a high abundance of organic matter. Most of the source rocks are just in the peak stage of hydrocarbon generation, which is a favorable foundation for forming abundant oil and gas resources in the Biyang Depression. The comparative analysis of the hydrocarbon- generation quantities between lower and upper members of the Eh3 source rocks shows that the lower members of Eh3 have good oil and gas resource potential, and the hydrocarbon-generation quantity accounts for 51% of the total in Eh3. Specifically, the oil-generating quantity accounts for 50% of the total and the gas-generating quantity accounts for two thirds of the total. Therefore, source rocks in the lower members of Eh3 of the Biyang Depression have good oil and gas resource potential, which is a key factor for future deep oil and gas exploration.展开更多
It has been confirmed that the key source rocks of Qiongdongnan Basin are associated with the Yacheng Formation, which was deposited in a transitional marine-continental environment. Because the distribution and evolu...It has been confirmed that the key source rocks of Qiongdongnan Basin are associated with the Yacheng Formation, which was deposited in a transitional marine-continental environment. Because the distribution and evolution patterns of the source rocks in the major depressions are different, it is important to determine the most abundant hydrocarbon-generation depressions in terms of exploration effectiveness. Based on an analysis of organic matter characteristics of the source rocks, in combination with drilling data and seismic data, this paper establishes a model to evaluate the hydrocarbon-generation depressions in the deepwater area of Qiongdongnan Basin. First of all, by using the method of seismic-facies model analysis, the distribution of sedimentary facies was determined. Then, the sedimentary facies were correlated with the organic facies, and the distribution of organic facies was predicted. Meanwhile, the thickness of source rocks for all the depressions was calculated on the basis of a quantitative analysis of seismic velocity and lithology. The relationship between mudstone porosity and vitrinite reflectance（Ro） was used to predict the maturity of source rocks. Second, using the parameters such as thickness and maturity of source rocks, the quantity and intensity of gas generation for Yacheng and Lingshui Formations were calculated. Finally, in combination with the identified hydrocarbon resources, the quantity and intensity of gas generation were used as a guide to establish an evaluation standard for hydrocarbon-generation depressions, which was optimized for the main depressions in the Central Depression Belt. It is proposed that Lingshui, Ledong, Baodao and Changchang Depressions are the most abundant hydrocarbon depressions, whilst Songnan and Beijiao Depressions are rich hydrocarbon depressions. Such an evaluation procedure is beneficial to the next stage of exploration in the deep-water area of Qiongdongnan Basin.展开更多
For exploration and potential evaluation of deep shale reservoirs with high maturity,hydrocarbon generation and pore evolution of muddy shale in deep high evolution stage were investigated by the high-temperature high...For exploration and potential evaluation of deep shale reservoirs with high maturity,hydrocarbon generation and pore evolution of muddy shale in deep high evolution stage were investigated by the high-temperature high-pressure simulation experiment.Results indicated that under high pressure condition,nano-scale micropores in organic matter-rich muddy shale constantly increased as rise of temperature and pressure,leading to increase of shale porosity.However,in the high mature-overmature stage,shale porosity decreased with further increase of temperature and pressure.In contrast to micropores,micro-scale capillary pores and megapores in shale constantly decreased as rise of simulation temperature or pressure,indicating that deep-burial reservoirs was not favorable for free-gas storage;but significant increase of micropores and surface area during this stage could make up for a loss of adsorbed natural gas in shale due to decrease of adsorption capacity which was induced by increase of temperature and pressure,thus leading to high shale gas potential in deep layers.A large number of secondary micropores were developed in the simulated samples such as pyrite and dolomite,demonstrating that shale clasts and mineral matrix could also form abundant secondary micropores during the deep evolution stage;during the evolution process,shale as hydrocarbon source rock could generate a large amount of acidic fluid which was favorable for development of secondary porosity.展开更多
基金The Major State Basic Research Development Program (973 Program) under contract No. 2009CB219402
文摘Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some drilling wells of deep water area close to the central depression belt, Miocene marine source rocks with better organic matter abundance and hydrocarbon generation have been found, which have achieved better source rock standard based on the analysis of geochemical charac- teristics. Although there are no exploratory wells in deep water area of the research region, through the comparative analysis of geochemical data of several typical exploratory wells respectively from shallow water area in the basin, central depression belt margin in deep-water area of the basin and Site 1148 of deep sea drilling in the South China Sea Basin, it reveals that the tendency of the quality of source rocks becomes positive gradually from delta to bathyal environment, which then becomes negative as in deep oceanic environment. Owing to the lack of terrestrial organic matter input, the important controlling factors of Miocene marine source rocks in the Qiongdongnan Basin are ocean productivity and preservation conditions of organic matter. The element geochemistry data indicate that the tendency of the paleoproductivity and the preservation conditions of organic matter become positive as water depth increase from shallow area to bathyal area close to central depression belt. So it is speculated that there must exist high quality source rocks in the central depression area where the preservation conditions of organic matter are much better. Besides, in theory, in oxygen-poor zone of oceanic environment at the water depth 400–1 000 m, the preservation conditions of organic matter are well thus forming high-quality marine source rocks. The result- ing speculation, it is reasonable to consider that there are high hydrocarbon generation potential source rocks in bathyal environment of the Qiongdongnan Basin, especially at th
基金The work was supported by the National Science and Technology Major Project of China(No.2017ZX05049)the National Basic Research Program of China(973 Program)(No.2014CB239102)the National Natural Science Foundation of China(No.41572087).
文摘The pore characteristics of shale reservoirs in the lower submember of Member 3 to upper submember of Member 4 of Shahejie Formation in Dongying sag are analyzed,influences of mineral content and organic matter content on porosity and pore size are also investigated,and through the diagenetic thermal simulation experiment,the main pore evolution is further discussed.The results show that the pore structure of shale reservoirs is complex,the micron-nanometer pores can storage liquid hydrocarbons,and the free-phase crude oil is mainly distributed in intergranular dissolution pores of calcite,recrystallized intergranular pores,intergranular shrinkage fractures of clay mineral which have large pore size.Framework minerals and organic matter content directly influence porosity and pore size of shale reservoirs,relationship between porosity and content of felsic mineral as well as content of organic matter content is linear and positive,while relationship between content of carbonated mineral is negative.At the buried depth from 2500 to 3500 m,concentration of organic acid from hydrocarbon generation and expulsion of organic matter,increasing range of pressure coefficient,are well corresponding to highporosity intervals;pore formation in shale oil reservoirs are almost controlled by diagenetic evolution of clay minerals;framework storage spaces formed by carbonate grain crystals as well as intergranular and intergranular dissolution pores of carbonate increases porosity of shale oil reservoirs;local increase of porosity at the depth of 3500e3800 m is mainly caused by coupling of hydrocarbon-generating overpressure and dissolution,and size,distribution and connectivity of pores are enhanced obviously.
基金supported by the SINOPEC project (G0800-06-ZS-319)the National Natural Science Foundation of China (No. 40621002)the Ministry of Education of China (IRT00546, B0711)
文摘The well-preserved Mesoproterozoic succession in the North China platform consists mainly of three iithological associations including peritidal quartz sandstone, shallow marine and lagoonal dark to black shales, and shallow epeiric carbonates, with a total thickness of up to 8 000 m. In addition to well-documented microplants, macroalgae, and microbial buildups, abundant microbially induced sedimentary structures （MISS） and mat-related sediments have been recognized in these rocks. Intensive microbial mat layers and MISS are especially well preserved in the carbonates of the upper Gaoyuzhuang （高于庄） （ca. 1.5 Ga） and lower Wumishan （雾迷山） （ca. 1.45 Ga） formations, indicating diversified microbial activities and a high organic production. In these petrified biomats, putative microbial fossils （both coccoidal and filamentous） and framboidal pyrites have been identified. The abundance of authigenic carbonate minerals in the host rocks, such as, acicular aragonites, rosette barites, radial siderites, ankerites, and botryoidal carbonate cements, suggests authigenic carbonate precipitation from anaerobic oxidation of methane （AOM） under anoxic/euxinic conditions. Warm climate and anoxic/euxinic conditions in the Mesoproterozoic oceans may have facilitated high microbial productivity and organic burial in sediments. Although authigenic carbonate cements may record carbonate precipitation from anaerobic methane oxidation, gas blister （or dome） structures may indicate gas release from active methanogenesis during shallow burial. Bituminous fragments in mat-related carbonates also provide evidence for hydrocarbon generation. Under proper conditions, the Mesoproterozoic mat-rich carbonates will have the potential for hydrocarbon generation and serve as source rocks. On the basis of petrified biomats, a rough estimation suggests that the Mesoproterozoic carbonates of the North China platform might have a hydrocarbon production potential in the order of 10 ×10^8 t.
文摘The lower Tertiary Eh3 is divided into two sections： the upper members of Eh3 and the lower members of Eh3 in the Biyang Depression. The first section is generally regarded as a key target of oil and gas exploration, but the resource potential of the lower members of Eh3 has been neglected. We have obtained new knowledge about Eh3 from comprehensive geological research. The lower members of Eh3 are high-quality and main source rocks, which have good oil and gas resource potential. This is a new direction for oil and gas exploration. The geochemistry characteristics of source rocks of the lower members of Eh3 in the lower Tertiary of the Biyang Depression were analyzed in detail. A basin modeling method was applied to hydrocarbon generation of the lower and upper members of Eh3 source rocks, the oil and gas resource potential was comparatively analyzed, and then favorable tectonic zones were pointed out. In the lower members of Eh3, a set of semi-deep lake to deep lake high-quality source rocks occurs rich in algae organisms, mainly of type II1, with a high abundance of organic matter. Most of the source rocks are just in the peak stage of hydrocarbon generation, which is a favorable foundation for forming abundant oil and gas resources in the Biyang Depression. The comparative analysis of the hydrocarbon- generation quantities between lower and upper members of the Eh3 source rocks shows that the lower members of Eh3 have good oil and gas resource potential, and the hydrocarbon-generation quantity accounts for 51% of the total in Eh3. Specifically, the oil-generating quantity accounts for 50% of the total and the gas-generating quantity accounts for two thirds of the total. Therefore, source rocks in the lower members of Eh3 of the Biyang Depression have good oil and gas resource potential, which is a key factor for future deep oil and gas exploration.
基金The National Science and Technology Major Project of the Ministry of Science and Technology of China under contract No.2011ZX05025
文摘It has been confirmed that the key source rocks of Qiongdongnan Basin are associated with the Yacheng Formation, which was deposited in a transitional marine-continental environment. Because the distribution and evolution patterns of the source rocks in the major depressions are different, it is important to determine the most abundant hydrocarbon-generation depressions in terms of exploration effectiveness. Based on an analysis of organic matter characteristics of the source rocks, in combination with drilling data and seismic data, this paper establishes a model to evaluate the hydrocarbon-generation depressions in the deepwater area of Qiongdongnan Basin. First of all, by using the method of seismic-facies model analysis, the distribution of sedimentary facies was determined. Then, the sedimentary facies were correlated with the organic facies, and the distribution of organic facies was predicted. Meanwhile, the thickness of source rocks for all the depressions was calculated on the basis of a quantitative analysis of seismic velocity and lithology. The relationship between mudstone porosity and vitrinite reflectance（Ro） was used to predict the maturity of source rocks. Second, using the parameters such as thickness and maturity of source rocks, the quantity and intensity of gas generation for Yacheng and Lingshui Formations were calculated. Finally, in combination with the identified hydrocarbon resources, the quantity and intensity of gas generation were used as a guide to establish an evaluation standard for hydrocarbon-generation depressions, which was optimized for the main depressions in the Central Depression Belt. It is proposed that Lingshui, Ledong, Baodao and Changchang Depressions are the most abundant hydrocarbon depressions, whilst Songnan and Beijiao Depressions are rich hydrocarbon depressions. Such an evaluation procedure is beneficial to the next stage of exploration in the deep-water area of Qiongdongnan Basin.
基金This work was supported by National Key Basic Research Program of China(973 Program)(No.2012CB214704-02)National Science and Technology Major Project of China(No.2011ZX05008-002)and Key Laboratory Project of Gansu(No.1309RTSA041).
文摘For exploration and potential evaluation of deep shale reservoirs with high maturity,hydrocarbon generation and pore evolution of muddy shale in deep high evolution stage were investigated by the high-temperature high-pressure simulation experiment.Results indicated that under high pressure condition,nano-scale micropores in organic matter-rich muddy shale constantly increased as rise of temperature and pressure,leading to increase of shale porosity.However,in the high mature-overmature stage,shale porosity decreased with further increase of temperature and pressure.In contrast to micropores,micro-scale capillary pores and megapores in shale constantly decreased as rise of simulation temperature or pressure,indicating that deep-burial reservoirs was not favorable for free-gas storage;but significant increase of micropores and surface area during this stage could make up for a loss of adsorbed natural gas in shale due to decrease of adsorption capacity which was induced by increase of temperature and pressure,thus leading to high shale gas potential in deep layers.A large number of secondary micropores were developed in the simulated samples such as pyrite and dolomite,demonstrating that shale clasts and mineral matrix could also form abundant secondary micropores during the deep evolution stage;during the evolution process,shale as hydrocarbon source rock could generate a large amount of acidic fluid which was favorable for development of secondary porosity.
