For transportation of solid backfill material such as waste and fly ash from the surface to the bottom of the shaft in a fully mechanized backfilling coal backfilling coal mining technology, we developed a new vertica...For transportation of solid backfill material such as waste and fly ash from the surface to the bottom of the shaft in a fully mechanized backfilling coal backfilling coal mining technology, we developed a new vertical transportation system to transport this type of solid backfill material. Given the demands imposed on safely in feeding this material, we also investigated the structure and basic parameter of this system. For a mine in the Xingtai mining area the results show that: (1) a vertical transportation system should include three main parts, i.e., a feeding borehole, a maintenance chamber and a storage silo; (2) we determined that 486 mm is a suitable diameter for bore holes, the diameter of the storage silo is 6 m and its height 30 m in this vertical transportation system; (3) a conical buffer was developed to absorb the impact during the feeding process. To ensure normal implementation of fully mechanized backfilling coal mining technology and the safety of underground personnel, we propose a series of security technologies for anti-blockage, storage silo cleaning, high pressure air release and aspiration. This vertical transporting system has been applied in one this particular mine, which has fed about 4 million tons solid material with a feeding depth of 350 m and safely exploited 3 million tons of coal.展开更多
In recent years,the perovskite solar cells have gained much attention because of their ever-increasing power conversion efficiency(PCE),simple solution fabrication process,flyable,light-weight wearable and deployable ...In recent years,the perovskite solar cells have gained much attention because of their ever-increasing power conversion efficiency(PCE),simple solution fabrication process,flyable,light-weight wearable and deployable for ultra-lightweight space and low-cost materials constituents etc.Over the last few years,the efficiency of perovskite solar cells has surpassed 25%due to high-quality perovskite-film accomplished through low-temperature synthesis techniques along with developing suitable interface and electrode-materials.Besides,the stability of perovskite solar cells has attracted much well-deserved attention.In this article we have focused on recent progress of the perovskite solar cells regarding their crystallinity,morphology and synthesis techniques.Also,demonstrated different layers such as electron transport-layers(ETLs),hole transport-layers(HTLs)and buffer-layers utilized in perovskite solar-cells,considering their band gap,carrier mobility,transmittance etc.Outlook of various tin(Sn),carbon and polymer-based perovskite solar cells and their potential of commercialization feasibility has also been discussed.展开更多
Inserting a hole-buffer layer is an effective way to enhance emission efficiency of electroluminescence devices. We have successfully synthesized a new hole-buffer material PSB composed of pyrene, Schiff base and trih...Inserting a hole-buffer layer is an effective way to enhance emission efficiency of electroluminescence devices. We have successfully synthesized a new hole-buffer material PSB composed of pyrene, Schiff base and trihydroxy tert-butyl groups by the Suzuki-coupling reaction. The HOMO and LUMO lev-els were -6.33 eV and -2.55 eV, respectively, as estimated from cyclic volt-ammograms. In addition, homogeneous films (rms roughness ~2 nm) were readily obtained by spin-coating process. Multilayer polymer light-emitting diodes, ITO/PEDOT:PSS/PSB/SY/LiF/Al, have been fabricated using PSB as hole-buffer layer (HBL). Inserting PSB as HBL significantly enhances the per-formance (maximum luminance: 26,439 cd/m2, maximum current efficiency: 7.03 cd/A), compared with the one without PSB (9802 cd/m2, 2.43 cd/A). It is also superior to the device with conventional BCP as hole-blocking layer (ITO/PEDOT:PSS/SY/BCP/LiF/Al: 15,496 cd/m2, 5.56 cd/A). Current results strongly indicate that the PSB is a potential hole-buffer material for electrolu-minescent devices.展开更多
The enhanced performance of a squaraine compound, with 2,4-bis[4-（N,N-diisobutylamino）-2,6-dihydroxyphenyl] squaraine as the donor and [6,6]-phenyl-C71-butyric acid methyl ester （PC71BM） as the acceptor, in soluti...The enhanced performance of a squaraine compound, with 2,4-bis[4-（N,N-diisobutylamino）-2,6-dihydroxyphenyl] squaraine as the donor and [6,6]-phenyl-C71-butyric acid methyl ester （PC71BM） as the acceptor, in solution-processed or- ganic photovoltaic devices is obtained by using UV-ozone-treated MoO3 as the hole-collecting buffer layer. The optimized thickness of the MoO3 layer is 8 nm, at which the device shows the best power conversion efficiency （PCE） among all devices, resulting from a balance of optical absorption and charge transport. After being treated by UV-ozone for 10 min, the transmittance of the MoO3 film is almost unchanged. Atomic force microscopy results show that the treated surface morphology is improved. A high PCE of 3.99% under AM 1.5 G illumination （100 mW/cm2） is obtained.展开更多
基金support for this work provided by the National Natural Science Foundation of China (No. 51074165)the major program of the National Natural Science Foundation of China (No. 50834004)the Innovation Project of Graduate Students of Jiangsu Province (No. CXZZ11-0308)
文摘For transportation of solid backfill material such as waste and fly ash from the surface to the bottom of the shaft in a fully mechanized backfilling coal backfilling coal mining technology, we developed a new vertical transportation system to transport this type of solid backfill material. Given the demands imposed on safely in feeding this material, we also investigated the structure and basic parameter of this system. For a mine in the Xingtai mining area the results show that: (1) a vertical transportation system should include three main parts, i.e., a feeding borehole, a maintenance chamber and a storage silo; (2) we determined that 486 mm is a suitable diameter for bore holes, the diameter of the storage silo is 6 m and its height 30 m in this vertical transportation system; (3) a conical buffer was developed to absorb the impact during the feeding process. To ensure normal implementation of fully mechanized backfilling coal mining technology and the safety of underground personnel, we propose a series of security technologies for anti-blockage, storage silo cleaning, high pressure air release and aspiration. This vertical transporting system has been applied in one this particular mine, which has fed about 4 million tons solid material with a feeding depth of 350 m and safely exploited 3 million tons of coal.
文摘In recent years,the perovskite solar cells have gained much attention because of their ever-increasing power conversion efficiency(PCE),simple solution fabrication process,flyable,light-weight wearable and deployable for ultra-lightweight space and low-cost materials constituents etc.Over the last few years,the efficiency of perovskite solar cells has surpassed 25%due to high-quality perovskite-film accomplished through low-temperature synthesis techniques along with developing suitable interface and electrode-materials.Besides,the stability of perovskite solar cells has attracted much well-deserved attention.In this article we have focused on recent progress of the perovskite solar cells regarding their crystallinity,morphology and synthesis techniques.Also,demonstrated different layers such as electron transport-layers(ETLs),hole transport-layers(HTLs)and buffer-layers utilized in perovskite solar-cells,considering their band gap,carrier mobility,transmittance etc.Outlook of various tin(Sn),carbon and polymer-based perovskite solar cells and their potential of commercialization feasibility has also been discussed.
文摘Inserting a hole-buffer layer is an effective way to enhance emission efficiency of electroluminescence devices. We have successfully synthesized a new hole-buffer material PSB composed of pyrene, Schiff base and trihydroxy tert-butyl groups by the Suzuki-coupling reaction. The HOMO and LUMO lev-els were -6.33 eV and -2.55 eV, respectively, as estimated from cyclic volt-ammograms. In addition, homogeneous films (rms roughness ~2 nm) were readily obtained by spin-coating process. Multilayer polymer light-emitting diodes, ITO/PEDOT:PSS/PSB/SY/LiF/Al, have been fabricated using PSB as hole-buffer layer (HBL). Inserting PSB as HBL significantly enhances the per-formance (maximum luminance: 26,439 cd/m2, maximum current efficiency: 7.03 cd/A), compared with the one without PSB (9802 cd/m2, 2.43 cd/A). It is also superior to the device with conventional BCP as hole-blocking layer (ITO/PEDOT:PSS/SY/BCP/LiF/Al: 15,496 cd/m2, 5.56 cd/A). Current results strongly indicate that the PSB is a potential hole-buffer material for electrolu-minescent devices.
基金Project supported by the Program for New Century Excellent Talents in University of Ministry of Education of China(Grant No.NCET-10-0220)the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20120009130005)the Fundamental Research Funds for the Central Universities of Ministry of Education of China(Grant No.2012JBZ001)
文摘The enhanced performance of a squaraine compound, with 2,4-bis[4-（N,N-diisobutylamino）-2,6-dihydroxyphenyl] squaraine as the donor and [6,6]-phenyl-C71-butyric acid methyl ester （PC71BM） as the acceptor, in solution-processed or- ganic photovoltaic devices is obtained by using UV-ozone-treated MoO3 as the hole-collecting buffer layer. The optimized thickness of the MoO3 layer is 8 nm, at which the device shows the best power conversion efficiency （PCE） among all devices, resulting from a balance of optical absorption and charge transport. After being treated by UV-ozone for 10 min, the transmittance of the MoO3 film is almost unchanged. Atomic force microscopy results show that the treated surface morphology is improved. A high PCE of 3.99% under AM 1.5 G illumination （100 mW/cm2） is obtained.
