Direct reduction of high-phosphorus oolitic hematite ore based on biomass pyrolysis gases （CO, H2, and CH4 ）, tar, and char was conducted to investigate the effects of reduction temperature, iron ore-biomass mass ra...Direct reduction of high-phosphorus oolitic hematite ore based on biomass pyrolysis gases （CO, H2, and CH4 ）, tar, and char was conducted to investigate the effects of reduction temperature, iron ore-biomass mass ratio, and reduction time on the metallization rate. In addition, the effect of particle size on the dephosphorization and iron recovery rate was studied by magnetic separation. It was determined that the metallization rate of the hematite ore could reach 99.35 % at iron ore-biomass mass ratio of 1 ： 0.6, reduction temperature of 1100℃, and reduction time of 55 min. The metallization rate and the aggregation degree of iron particles increase with the increase of reduction temperature. The particle size of direct reduced iron （DRI） has a great influence on the quality of the iron concentrate during magnetic separation. The separation degree of slag and iron was improved by the addition of 15 mass% sodium carbonate. DRI with iron grade of 89.11%, iron recovery rate of 83.47%, and phosphorus content of 0.28% can be obtained when ore fines with particle size of -10μm account for 78.15%.展开更多
Iron was recovered from blast furnace dust and high-phosphorus oolitic hematite in the presence of Na2CO3 and CaCO3 additives. The functions of Na2CO3 and CaCO3 during the coreduction roasting process were investigate...Iron was recovered from blast furnace dust and high-phosphorus oolitic hematite in the presence of Na2CO3 and CaCO3 additives. The functions of Na2CO3 and CaCO3 during the coreduction roasting process were investigated by XRD and SEM-EDS analyses. Results indicate that these additives not only hinder the reduction of fluorapatite, CaCO3 also decreases the P content of direct reduced iron（DRI） by increasing the reduction alkalinity. P remains as fluorapatite in the slag, which can be removed by grinding and magnetic separation under optimal conditions. The Na2CO3 promotes hematite reduction and improves the iron recovery（εFe） by replacing the FeO from fayalite, which results in quick growth and aggregation of metallic iron and improvement of ε（Fe） in DRI. A DRI with 91.88 mass% Fe, and 0.065 mass% P can be achieved at a recovery of 87.86 mass% under the optimal condition.展开更多
基金Project(2021YFC2902404)supported by the National Key Research and Development Program of ChinaProject(2023JH3/10200010)supported by the Excellent Youth Natural Science Foundation of Liaoning Province,China+2 种基金Project(XLYC2203167)supported by the Liaoning Revitalization Talents Program,ChinaProject(CNMRCUKF2301)supported by the Open Foundation of State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization,ChinaProject(52274253)supported by the National Natural Science Foundation of China。
基金Sponsored by National Natural Science Foundation of China(51574024,51274042)China Postdoctoral Science Foundation(2015M580987,2016T90034)
文摘Direct reduction of high-phosphorus oolitic hematite ore based on biomass pyrolysis gases （CO, H2, and CH4 ）, tar, and char was conducted to investigate the effects of reduction temperature, iron ore-biomass mass ratio, and reduction time on the metallization rate. In addition, the effect of particle size on the dephosphorization and iron recovery rate was studied by magnetic separation. It was determined that the metallization rate of the hematite ore could reach 99.35 % at iron ore-biomass mass ratio of 1 ： 0.6, reduction temperature of 1100℃, and reduction time of 55 min. The metallization rate and the aggregation degree of iron particles increase with the increase of reduction temperature. The particle size of direct reduced iron （DRI） has a great influence on the quality of the iron concentrate during magnetic separation. The separation degree of slag and iron was improved by the addition of 15 mass% sodium carbonate. DRI with iron grade of 89.11%, iron recovery rate of 83.47%, and phosphorus content of 0.28% can be obtained when ore fines with particle size of -10μm account for 78.15%.
基金Funded by National Natural Science Foundation of China(No.51134002)
文摘Iron was recovered from blast furnace dust and high-phosphorus oolitic hematite in the presence of Na2CO3 and CaCO3 additives. The functions of Na2CO3 and CaCO3 during the coreduction roasting process were investigated by XRD and SEM-EDS analyses. Results indicate that these additives not only hinder the reduction of fluorapatite, CaCO3 also decreases the P content of direct reduced iron（DRI） by increasing the reduction alkalinity. P remains as fluorapatite in the slag, which can be removed by grinding and magnetic separation under optimal conditions. The Na2CO3 promotes hematite reduction and improves the iron recovery（εFe） by replacing the FeO from fayalite, which results in quick growth and aggregation of metallic iron and improvement of ε（Fe） in DRI. A DRI with 91.88 mass% Fe, and 0.065 mass% P can be achieved at a recovery of 87.86 mass% under the optimal condition.
