Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated d...Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency.In this work,an innovative DBD thermally-conducted catalysis(DBD-TCC)system,integrating high-frequency AC-DBD plasma and its generated thermal effects to activate the Co/SBA-15 catalyst,was employed for toluene removal.Specifically,Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 k V.At12.4 k V,the temperature in the catalyst zone reached 261℃ in the DBD-TCC system,resulting in an increase in toluene degradation efficiency of 17%,CO_(2)selectivity of 21.2%,and energy efficiency of 27%,respectively,compared to the DBD system alone.In contrast,the DBD thermally-unconducted catalysis(DBD-TUC)system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation,highlighting the crucial role of AC-DBD generated heat in the activation of the catalyst.Furthermore,the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized.This work is expected to provide an energy-efficient approach for high-frequency AC-DBD plasma removal of VOCs.展开更多
高频变压器在提升电能传输效率的同时,也会加速油纸绝缘系统缺陷的劣化进程。为研究油纸绝缘系统在高频电压下的劣化特性,采用柱板模型模拟油纸绝缘的沿面放电缺陷,搭建高频局部放电试验平台,在10、20、30 k Hz电压下采用恒压法进行多...高频变压器在提升电能传输效率的同时,也会加速油纸绝缘系统缺陷的劣化进程。为研究油纸绝缘系统在高频电压下的劣化特性,采用柱板模型模拟油纸绝缘的沿面放电缺陷,搭建高频局部放电试验平台,在10、20、30 k Hz电压下采用恒压法进行多组局部放电试验。利用摄像机和罗氏线圈分别记录试验现象和放电信号,分析高频电压下局部放电图谱和产气特性,并与工频局部放电试验的结果进行对比。结果表明:随着频率的提高,油纸绝缘系统的局部放电起始电压显著降低,单位时间内关键气体的产气量明显提高;但在高频电压下,绝缘油的劣化比绝缘纸板的劣化更为严重,因此提高了关键气体中H2的比例。由于空间电荷效应,放电相位集中于电压极性反转相位附近,且高频电压下的放电相位比工频电压下的放电相位宽;同时,在高频电压下,电压的上升速率、单周波内的有效放电时延受到频率的影响,使单周波内的平均放电幅值、平均放电次数在20 k Hz附近出现极大值。展开更多
The influence of different factors on the plasma chemical reactions is widely studied today. However, insufficient consideration is given to the research of paramagnetic phenomena which takes place in plasma systems. ...The influence of different factors on the plasma chemical reactions is widely studied today. However, insufficient consideration is given to the research of paramagnetic phenomena which takes place in plasma systems. The results of modeling the process of redistribution carbon isotopes between different phases while oxidizing it in high-frequency low-temperature plasma in an external magnetic field are shown in the article. The equilibrium concentrations of components involved in the oxidation process in a plasma system are defined. A principle possibility of isotope-selective plasma chemical reactions in a magnetic field was experimentally determined. The increase of concentration of 13C in the gas phase up to 1.3 times relative to natural abundance was obtained. It was found that the content of the carbon heavy isotope in the gas phase depends on the magnetic field action area. The best results were achieved with the combination of magnetic field impact area and the priority area of the appearance of plasma chemical reactions products.展开更多
基金supported by National Natural Science Foundation of China(No.52177130)the Key Projects for Industrial Prospects and Core Technology Research in Suzhou City(No.SYC2022029)。
文摘Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency.In this work,an innovative DBD thermally-conducted catalysis(DBD-TCC)system,integrating high-frequency AC-DBD plasma and its generated thermal effects to activate the Co/SBA-15 catalyst,was employed for toluene removal.Specifically,Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 k V.At12.4 k V,the temperature in the catalyst zone reached 261℃ in the DBD-TCC system,resulting in an increase in toluene degradation efficiency of 17%,CO_(2)selectivity of 21.2%,and energy efficiency of 27%,respectively,compared to the DBD system alone.In contrast,the DBD thermally-unconducted catalysis(DBD-TUC)system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation,highlighting the crucial role of AC-DBD generated heat in the activation of the catalyst.Furthermore,the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized.This work is expected to provide an energy-efficient approach for high-frequency AC-DBD plasma removal of VOCs.
文摘高频变压器在提升电能传输效率的同时,也会加速油纸绝缘系统缺陷的劣化进程。为研究油纸绝缘系统在高频电压下的劣化特性,采用柱板模型模拟油纸绝缘的沿面放电缺陷,搭建高频局部放电试验平台,在10、20、30 k Hz电压下采用恒压法进行多组局部放电试验。利用摄像机和罗氏线圈分别记录试验现象和放电信号,分析高频电压下局部放电图谱和产气特性,并与工频局部放电试验的结果进行对比。结果表明:随着频率的提高,油纸绝缘系统的局部放电起始电压显著降低,单位时间内关键气体的产气量明显提高;但在高频电压下,绝缘油的劣化比绝缘纸板的劣化更为严重,因此提高了关键气体中H2的比例。由于空间电荷效应,放电相位集中于电压极性反转相位附近,且高频电压下的放电相位比工频电压下的放电相位宽;同时,在高频电压下,电压的上升速率、单周波内的有效放电时延受到频率的影响,使单周波内的平均放电幅值、平均放电次数在20 k Hz附近出现极大值。
文摘The influence of different factors on the plasma chemical reactions is widely studied today. However, insufficient consideration is given to the research of paramagnetic phenomena which takes place in plasma systems. The results of modeling the process of redistribution carbon isotopes between different phases while oxidizing it in high-frequency low-temperature plasma in an external magnetic field are shown in the article. The equilibrium concentrations of components involved in the oxidation process in a plasma system are defined. A principle possibility of isotope-selective plasma chemical reactions in a magnetic field was experimentally determined. The increase of concentration of 13C in the gas phase up to 1.3 times relative to natural abundance was obtained. It was found that the content of the carbon heavy isotope in the gas phase depends on the magnetic field action area. The best results were achieved with the combination of magnetic field impact area and the priority area of the appearance of plasma chemical reactions products.
