FT-IR spectroscopy online was used to investigate DECP(Diethyl chlorophosphite)degraded by photocatalytic oxidation on nano-TiO2(P25).GC-MS spectrograph was used to analyze the products.It is possible to predict the m...FT-IR spectroscopy online was used to investigate DECP(Diethyl chlorophosphite)degraded by photocatalytic oxidation on nano-TiO2(P25).GC-MS spectrograph was used to analyze the products.It is possible to predict the mechanism of gas-solid phase photocatalytic degradation of DECP.The reaction may be take place by follow pathway:electron-hole couple was produced in illuminated TiO2 by UV irradiated,and the couple evoke reactions with DECP,H2O,-OH to produce various radicals.DECP can be degraded to inorganic compounds by the chain-reaction of radicals.The products include CO2,H2O,CO,HCl,et al.The chain-reaction will be terminated when radicals vanish,and the intermediates were produced,such as methane,alcohol,ethanal,DEHP(Diethyl hydroxyphosphonate),DEP(Diethyl phosphate),TEP(Triethyl phosphate),et al.展开更多
文摘FT-IR spectroscopy online was used to investigate DECP(Diethyl chlorophosphite)degraded by photocatalytic oxidation on nano-TiO2(P25).GC-MS spectrograph was used to analyze the products.It is possible to predict the mechanism of gas-solid phase photocatalytic degradation of DECP.The reaction may be take place by follow pathway:electron-hole couple was produced in illuminated TiO2 by UV irradiated,and the couple evoke reactions with DECP,H2O,-OH to produce various radicals.DECP can be degraded to inorganic compounds by the chain-reaction of radicals.The products include CO2,H2O,CO,HCl,et al.The chain-reaction will be terminated when radicals vanish,and the intermediates were produced,such as methane,alcohol,ethanal,DEHP(Diethyl hydroxyphosphonate),DEP(Diethyl phosphate),TEP(Triethyl phosphate),et al.
