Froth flotation is used widely for upgrading raw phosphate.The flotation recovery of coarse phosphate(-1.18+0.425 mm) is much lower than that achieved on the-0.425+0.15 mm size fraction.Enhanced recovery of coarse pho...Froth flotation is used widely for upgrading raw phosphate.The flotation recovery of coarse phosphate(-1.18+0.425 mm) is much lower than that achieved on the-0.425+0.15 mm size fraction.Enhanced recovery of coarse phosphate particles is of great economic and environmental importance for phosphate industry.In this investigation,four different phosphate samples were aquired,characterized and tested in a specially designed laboratory-scale flotation column.Significant recovery improvement of coarse phosphate flotation was achieved using cavitation-generated nanobubble though its effects differ among the four testing phosphate samples.The laboratory-scale flotation column test results indicate that nanobubble increased P_2O_5 recovery by up to 10%~30%for a given Acid Insoluble(A.I.) rejection,depending on the characteristic of phosphate samples.The improvement effect of nanobubble on the hard-to-float particles was more significant than that on easy-to-float particles,especially at lower collector dosages.Nanobubbles reduced the collector dosage by 1/3 to 1/2.Nanobubbles almost doubled the coarse phosphate flotation rate constant and increased the flotation selectivity index by up to 25%.展开更多
Coal is the world's most abundant fossil fuel.Coal froth flotation is a widely used cleaning process to separate coal from mineral impurities.Flotation of coarse coal particles,ultrafine coal particles and oxidize...Coal is the world's most abundant fossil fuel.Coal froth flotation is a widely used cleaning process to separate coal from mineral impurities.Flotation of coarse coal particles,ultrafine coal particles and oxidized coal particles is well known to be difficult and complex.In this paper,the nanobubbles' effects on the flotation of the varying particle size,particle density and floatability coal samples were evaluated using a bank of pilot scale flotation cells,a laboratory scale and a pilot scale specially designed flotation column.The parameters evaluated during this study include the flow rate ratio between the nanobubble generator and the conventional size bubble generator,the superficial air velocity,collector dosage,frother concentration,flotation feed rate,feed solids concentration,feed particle size,and the superficial wash water flow rate,etc.The results show that the use of nanobubbles in a bank of mechanical cells flotation and column flotation increased the flotation recovery by 8%~27% at a given product grade.Nanobubbles increased the flotation rate constants of 600~355,355~180,180~75,and 75~0 microns size coal particles by 98.0%,98.4%,50.0% and 41.6%,respectively.The separation selectivity index was increased by up to 34%,depending on the flotation feed characteristics and the flotation conditions.展开更多
This study was performed in two phases of work.In the first stage,four conventional first-order flotation kinetics models were fitted to the measured recoveries data and the best model were selected.In the second stag...This study was performed in two phases of work.In the first stage,four conventional first-order flotation kinetics models were fitted to the measured recoveries data and the best model were selected.In the second stage,influence of pH,solid concentration,water chemistry and the amount of collector dosage were investigated on kinetics parameters including flotation rate constant and ultimate recovery.The results indicated that that perfectly mixed reactor model and Kelsall model gave the best and the weakest fit to the experimental data,respectively.It was observed that flotation rate constant and ultimate recovery were strongly affected by chemical factors investigated especially water quality.The flotation rate constant decreased with increasing the solids content,while ultimate recovery increased to certain value and thereafter reduced.It was also found that the most values of flotation rate constant and ultimate recovery obtained in dosage of collector are 30 and 40 g/t,respectively.展开更多
Surface roughness and shape play an important role on the behavior of particles in various processes such as flotation. In this re- search, the influence of different grinding methods on the surface roughness and shap...Surface roughness and shape play an important role on the behavior of particles in various processes such as flotation. In this re- search, the influence of different grinding methods on the surface roughness and shape characteristics of quartz particles as well as the effect of these parameters on the flotation of the particles was investigated. The surface roughness of the particles was determined by measuring their specific surface area via the gas adsorption method. The shape characteristics of the particles were measured and calculated by images obtained by scanning electron microscopy via an image analysis system. The flotation kinetics was determined using a laboratory flotation cell. The results showed that the particles of rod mill products have higher roughness and elongation ratio and lower roundness than the parti- cles of ball mill products. The flotation kinetics constant of the particles increased with their surface roughness increasing. Particles with higher elongation and lower roundness indicated higher floatability. In addition, the influence of the surface roughness on the flotation kinet- ics was greater than that of shape parameters.展开更多
基金the Florida Institute of Phosphate Research(FIPR),The Center for Advanced Separation Technologies(CAST) and the National Natural Science Foundation of China (Nos.50921002 and 90510002) for the financial supportCF Industry Inc and Mosaic Company for supplying specimens and ArrMaz Custom Chemicals Inc.for providing chemicals employed in this study.
文摘Froth flotation is used widely for upgrading raw phosphate.The flotation recovery of coarse phosphate(-1.18+0.425 mm) is much lower than that achieved on the-0.425+0.15 mm size fraction.Enhanced recovery of coarse phosphate particles is of great economic and environmental importance for phosphate industry.In this investigation,four different phosphate samples were aquired,characterized and tested in a specially designed laboratory-scale flotation column.Significant recovery improvement of coarse phosphate flotation was achieved using cavitation-generated nanobubble though its effects differ among the four testing phosphate samples.The laboratory-scale flotation column test results indicate that nanobubble increased P_2O_5 recovery by up to 10%~30%for a given Acid Insoluble(A.I.) rejection,depending on the characteristic of phosphate samples.The improvement effect of nanobubble on the hard-to-float particles was more significant than that on easy-to-float particles,especially at lower collector dosages.Nanobubbles reduced the collector dosage by 1/3 to 1/2.Nanobubbles almost doubled the coarse phosphate flotation rate constant and increased the flotation selectivity index by up to 25%.
文摘Coal is the world's most abundant fossil fuel.Coal froth flotation is a widely used cleaning process to separate coal from mineral impurities.Flotation of coarse coal particles,ultrafine coal particles and oxidized coal particles is well known to be difficult and complex.In this paper,the nanobubbles' effects on the flotation of the varying particle size,particle density and floatability coal samples were evaluated using a bank of pilot scale flotation cells,a laboratory scale and a pilot scale specially designed flotation column.The parameters evaluated during this study include the flow rate ratio between the nanobubble generator and the conventional size bubble generator,the superficial air velocity,collector dosage,frother concentration,flotation feed rate,feed solids concentration,feed particle size,and the superficial wash water flow rate,etc.The results show that the use of nanobubbles in a bank of mechanical cells flotation and column flotation increased the flotation recovery by 8%~27% at a given product grade.Nanobubbles increased the flotation rate constants of 600~355,355~180,180~75,and 75~0 microns size coal particles by 98.0%,98.4%,50.0% and 41.6%,respectively.The separation selectivity index was increased by up to 34%,depending on the flotation feed characteristics and the flotation conditions.
文摘This study was performed in two phases of work.In the first stage,four conventional first-order flotation kinetics models were fitted to the measured recoveries data and the best model were selected.In the second stage,influence of pH,solid concentration,water chemistry and the amount of collector dosage were investigated on kinetics parameters including flotation rate constant and ultimate recovery.The results indicated that that perfectly mixed reactor model and Kelsall model gave the best and the weakest fit to the experimental data,respectively.It was observed that flotation rate constant and ultimate recovery were strongly affected by chemical factors investigated especially water quality.The flotation rate constant decreased with increasing the solids content,while ultimate recovery increased to certain value and thereafter reduced.It was also found that the most values of flotation rate constant and ultimate recovery obtained in dosage of collector are 30 and 40 g/t,respectively.
文摘Surface roughness and shape play an important role on the behavior of particles in various processes such as flotation. In this re- search, the influence of different grinding methods on the surface roughness and shape characteristics of quartz particles as well as the effect of these parameters on the flotation of the particles was investigated. The surface roughness of the particles was determined by measuring their specific surface area via the gas adsorption method. The shape characteristics of the particles were measured and calculated by images obtained by scanning electron microscopy via an image analysis system. The flotation kinetics was determined using a laboratory flotation cell. The results showed that the particles of rod mill products have higher roughness and elongation ratio and lower roundness than the parti- cles of ball mill products. The flotation kinetics constant of the particles increased with their surface roughness increasing. Particles with higher elongation and lower roundness indicated higher floatability. In addition, the influence of the surface roughness on the flotation kinet- ics was greater than that of shape parameters.