Mo_(2)C is an excellent electrocatalyst for hydrogen evolution reaction(HER).However,Mo_(2)C is a poor electrocatalyst for oxygen evolution reaction(OER).Herein,two different elements,namely Co and Fe,are incorporated...Mo_(2)C is an excellent electrocatalyst for hydrogen evolution reaction(HER).However,Mo_(2)C is a poor electrocatalyst for oxygen evolution reaction(OER).Herein,two different elements,namely Co and Fe,are incorporated in Mo_(2)C that,therefore,has a finely tuned electronic structure,which is not achievable by incorporation of any one of the metals.Consequently,the resulting electrocatalyst Co_(0.8)Fe_(0.2)-Mo_(2)C-80 displayed excellent OER catalytic performance,which is evidenced by a low overpotential of 214.0(and 246.5)mV to attain a current density of 10(and 50)mA cm^(-2),an ultralow Tafel slope of 38.4 mV dec^(-1),and longterm stability in alkaline medium.Theoretical data demonstrates that Co_(0.8)Fe_(0.2)-Mo_(2)C-80 requires the lowest overpotential(1.00 V)for OER and Co centers to be the active sites.The ultrahigh catalytic performance of the electrocatalyst is attributed to the excellent intrinsic catalytic activity due to high Brunauer-Emmett-Teller specific surface area,large electrochemically active surface area,small Tafel slope,and low chargetransfer resistance.展开更多
We derive the potential energy of gravity waves(GWs)in the upper troposphere and stratosphere at 45°S-45°N from December 2019 to November 2022 by using temperature profiles retrieved from the Constellation O...We derive the potential energy of gravity waves(GWs)in the upper troposphere and stratosphere at 45°S-45°N from December 2019 to November 2022 by using temperature profiles retrieved from the Constellation Observing System for Meteorology,Ionosphere,and Climate-2(COSMIC-2)satellite.Owing to the dense sampling of COSMIC-2,in addition to the strong peaks of gravity wave potential energy(GWPE)above the Andes and Tibetan Plateau,we found weak peaks above the Rocky,Atlas,Caucasus,and Tianshan Mountains.The land-sea contrast is responsible for the longitudinal variations of the GWPE in the lower and upper stratosphere.At 40°N/S,the peaks were mainly above the topographic regions during the winter.At 20°N/S,the peaks were a slight distance away from the topographic regions and might be the combined effect of nontopographic GWs and mountain waves.Near the Equator,the peaks were mainly above the regions with the lowest sea level altitude and may have resulted from convection.Our results indicate that even above the local regions with lower sea level altitudes compared with the Andes and Tibetan Plateau,the GWPE also exhibits fine structures in geographic distributions.We found that dissipation layers above the tropopause jet provide the body force to generate secondary waves in the upper stratosphere,especially during the winter months of each hemisphere and at latitudes of greater than 20°N/S.展开更多
Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ...Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ramp,often occurs severe SWBLIs with a large separation bubble.In this paper,experimental investigations on vortical structures and density fluctuations characteristics of supersonic FFS controlled by self-sustaining dual synthetic jets(SDSJ)are carried out in a Mach number 2.95 wind tunnel.High spatial–temporal resolution flowfield images of FFS without/with active flow control are captured by adopting nano-particle-based planar laser scattering technique.The control effects of the distance between the actuator and the step are mainly compared.The paper finds that the SDSJ can effectively change the feature of flowfield,eliminate the separation shock and the reattachment shock,compel the original shock induced by the step leading edge to distort and reduce its intensity finally.Density fluctuations analysis demonstrates that the whole flows seem to move upstream with the increase of distance(dS-J).Discrete Fourier transformation spectrums results reveal that the fluctuations are mainly located in the low-frequency region at first.High-frequency components and frequency bandwidth increase slightly after the SDSJ are applied.展开更多
The paper investigates the overall and detailed features of cosmic ray(CR) spectra in the knee region using the scenario of nuclei-photon interactions around the acceleration sources.Young supernova remnants can be th...The paper investigates the overall and detailed features of cosmic ray(CR) spectra in the knee region using the scenario of nuclei-photon interactions around the acceleration sources.Young supernova remnants can be the physical realities of such kind of CR acceleration sites.The results show that the model can well explain the following problems simultaneously with one set of source parameters:the knee of CR spectra and the sharpness of the knee,the detailed irregular structures of CR spectra,the so-called"component B"of Galactic CRs,and the electron/positron excesses reported by recent observations.The coherent explanation serves as evidence that at least a portion of CRs might be accelerated at the sources similar to young supernova remnants,and one set of source parameters indicates that this portion mainly comes from standard sources or from a single source.展开更多
AIM: To find suitable solutions having lesser granules and keeping erythrocytes in normal shapes under atomic force microscopy (AFM). METHODS: Eight kinds of solutions, 1% formaldehyde, PBS buffer (pH7.2), citrate buf...AIM: To find suitable solutions having lesser granules and keeping erythrocytes in normal shapes under atomic force microscopy (AFM). METHODS: Eight kinds of solutions, 1% formaldehyde, PBS buffer (pH7.2), citrate buffer (pH6.0), 0.9% NaCl, 5% dextrose, TAE, 1640 medium and 5% EDTA-K2, were selected from commonly used laboratory solutions, and venous blood from a healthy human volunteer was drawn and anticoagulated with EDTA-K2. Before scanned by AFM (NanoScopeIIIa SPM, Digital Instruments, Santa Barbara, CA), a kind of intermixture was deposited on freshly cleaved mica and then dried in the constant temperature cabinet (37 ℃). RESULTS: One percent formaldehyde, citrate buffer, 5% dextrose, TAE, were found to keep human erythrocytes in normal shape with few particles. Processed by these solutions, fine structures of human erythrocyte membrane were obtained. CONCLUSION: One percent formaldehyde, citrate buffer, 5% dextrose and TAE may be applied to dispose erythrocytes in AFM. The results may offer meaningful data for clinical diagnosis of blood by AFM.展开更多
Spin pumping(SP)and inverse spin Hall effect(ISHE)driven by parametrically-excited dipole-exchange spin waves in a yttrium iron garnet film have been systematically investigated.The measured voltage spectrum exhibits ...Spin pumping(SP)and inverse spin Hall effect(ISHE)driven by parametrically-excited dipole-exchange spin waves in a yttrium iron garnet film have been systematically investigated.The measured voltage spectrum exhibits a feature of the field-induced transition from parallel pumping to perpendicular pumping because of the inhomogeneous excitation geometry.Thanks to the high precision of the SP-ISHE detection,two sets of fine structures in the voltage spectrum are observed,which can correspond well to two kinds of critical points in the multimode spin-wave spectrum for magnetic films.One is the q=0 point of each higher-order dispersion branch,and the other is the local minimum due to the interplay between the dipolar and exchange interactions.These fine structures on the voltage spectrum confirm the spin pumping by higher-order dipole-exchange spin-wave modes,and are helpful for probing the multimode spin-wave spectrum.展开更多
The microphase separation extent of biomedical segmented polyetherurethanes were greatly enhanced due to the presence of sulfoalkyl pendant groups contained in the hard segments,and the hard segments were more orderly...The microphase separation extent of biomedical segmented polyetherurethanes were greatly enhanced due to the presence of sulfoalkyl pendant groups contained in the hard segments,and the hard segments were more orderly aggregated through ionic interaction.展开更多
基金financial support from the SERB-SURE under file number of SUR/2022/003129Jong Hyeok Park acknowledges the support of the National Research Foundation of Korea (NRF)funded by the Ministry of Science and ICT (RS-2023-00302697,RS-2023-00268523).
文摘Mo_(2)C is an excellent electrocatalyst for hydrogen evolution reaction(HER).However,Mo_(2)C is a poor electrocatalyst for oxygen evolution reaction(OER).Herein,two different elements,namely Co and Fe,are incorporated in Mo_(2)C that,therefore,has a finely tuned electronic structure,which is not achievable by incorporation of any one of the metals.Consequently,the resulting electrocatalyst Co_(0.8)Fe_(0.2)-Mo_(2)C-80 displayed excellent OER catalytic performance,which is evidenced by a low overpotential of 214.0(and 246.5)mV to attain a current density of 10(and 50)mA cm^(-2),an ultralow Tafel slope of 38.4 mV dec^(-1),and longterm stability in alkaline medium.Theoretical data demonstrates that Co_(0.8)Fe_(0.2)-Mo_(2)C-80 requires the lowest overpotential(1.00 V)for OER and Co centers to be the active sites.The ultrahigh catalytic performance of the electrocatalyst is attributed to the excellent intrinsic catalytic activity due to high Brunauer-Emmett-Teller specific surface area,large electrochemically active surface area,small Tafel slope,and low chargetransfer resistance.
基金the National Natural Science Foundation of China(Grant Nos.41831073,42174196,and 42374205)the Project of Stable Support for Youth Team in Basic Research Field,Chinese Academy of Sciences(CAS+4 种基金Grant No.YSBR-018)the Informatization Plan of CAS(Grant No.CAS-WX2021PY-0101)the Youth Cross Team Scientific Research project of the Chinese Academy of Sciences(Grant No.JCTD-2021-10)the Open Research Project of Large Research Infrastructures of CAS titled“Study on the Interaction Between Low-/Mid-Latitude Atmosphere and Ionosphere Based on the Chinese Meridian Project.”This work was also supported in part by the Specialized Research Fund and the Open Research Program of the State Key Laboratory of Space Weather.
文摘We derive the potential energy of gravity waves(GWs)in the upper troposphere and stratosphere at 45°S-45°N from December 2019 to November 2022 by using temperature profiles retrieved from the Constellation Observing System for Meteorology,Ionosphere,and Climate-2(COSMIC-2)satellite.Owing to the dense sampling of COSMIC-2,in addition to the strong peaks of gravity wave potential energy(GWPE)above the Andes and Tibetan Plateau,we found weak peaks above the Rocky,Atlas,Caucasus,and Tianshan Mountains.The land-sea contrast is responsible for the longitudinal variations of the GWPE in the lower and upper stratosphere.At 40°N/S,the peaks were mainly above the topographic regions during the winter.At 20°N/S,the peaks were a slight distance away from the topographic regions and might be the combined effect of nontopographic GWs and mountain waves.Near the Equator,the peaks were mainly above the regions with the lowest sea level altitude and may have resulted from convection.Our results indicate that even above the local regions with lower sea level altitudes compared with the Andes and Tibetan Plateau,the GWPE also exhibits fine structures in geographic distributions.We found that dissipation layers above the tropopause jet provide the body force to generate secondary waves in the upper stratosphere,especially during the winter months of each hemisphere and at latitudes of greater than 20°N/S.
基金The present research was supported by the National Natural Science Foundation of China(Grants 11972369,51809271,11872374 and 11602299).
文摘Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ramp,often occurs severe SWBLIs with a large separation bubble.In this paper,experimental investigations on vortical structures and density fluctuations characteristics of supersonic FFS controlled by self-sustaining dual synthetic jets(SDSJ)are carried out in a Mach number 2.95 wind tunnel.High spatial–temporal resolution flowfield images of FFS without/with active flow control are captured by adopting nano-particle-based planar laser scattering technique.The control effects of the distance between the actuator and the step are mainly compared.The paper finds that the SDSJ can effectively change the feature of flowfield,eliminate the separation shock and the reattachment shock,compel the original shock induced by the step leading edge to distort and reduce its intensity finally.Density fluctuations analysis demonstrates that the whole flows seem to move upstream with the increase of distance(dS-J).Discrete Fourier transformation spectrums results reveal that the fluctuations are mainly located in the low-frequency region at first.High-frequency components and frequency bandwidth increase slightly after the SDSJ are applied.
基金supported by the Ministry of Science and Technology of China,the National Natural Sciences Foundation of China (Grant Nos. 10725524 and 10773011)the Chinese Academy of Sciences (Grant Nos. KJCX2-YW-N13, KJCX3-SYW-N2 and GJHZ1004)
文摘The paper investigates the overall and detailed features of cosmic ray(CR) spectra in the knee region using the scenario of nuclei-photon interactions around the acceleration sources.Young supernova remnants can be the physical realities of such kind of CR acceleration sites.The results show that the model can well explain the following problems simultaneously with one set of source parameters:the knee of CR spectra and the sharpness of the knee,the detailed irregular structures of CR spectra,the so-called"component B"of Galactic CRs,and the electron/positron excesses reported by recent observations.The coherent explanation serves as evidence that at least a portion of CRs might be accelerated at the sources similar to young supernova remnants,and one set of source parameters indicates that this portion mainly comes from standard sources or from a single source.
基金Supported by the National Natural Science Foundation of China,No. 30171036
文摘AIM: To find suitable solutions having lesser granules and keeping erythrocytes in normal shapes under atomic force microscopy (AFM). METHODS: Eight kinds of solutions, 1% formaldehyde, PBS buffer (pH7.2), citrate buffer (pH6.0), 0.9% NaCl, 5% dextrose, TAE, 1640 medium and 5% EDTA-K2, were selected from commonly used laboratory solutions, and venous blood from a healthy human volunteer was drawn and anticoagulated with EDTA-K2. Before scanned by AFM (NanoScopeIIIa SPM, Digital Instruments, Santa Barbara, CA), a kind of intermixture was deposited on freshly cleaved mica and then dried in the constant temperature cabinet (37 ℃). RESULTS: One percent formaldehyde, citrate buffer, 5% dextrose, TAE, were found to keep human erythrocytes in normal shape with few particles. Processed by these solutions, fine structures of human erythrocyte membrane were obtained. CONCLUSION: One percent formaldehyde, citrate buffer, 5% dextrose and TAE may be applied to dispose erythrocytes in AFM. The results may offer meaningful data for clinical diagnosis of blood by AFM.
基金the National Natural Science Foundation of China(Grant No.11904194).
文摘Spin pumping(SP)and inverse spin Hall effect(ISHE)driven by parametrically-excited dipole-exchange spin waves in a yttrium iron garnet film have been systematically investigated.The measured voltage spectrum exhibits a feature of the field-induced transition from parallel pumping to perpendicular pumping because of the inhomogeneous excitation geometry.Thanks to the high precision of the SP-ISHE detection,two sets of fine structures in the voltage spectrum are observed,which can correspond well to two kinds of critical points in the multimode spin-wave spectrum for magnetic films.One is the q=0 point of each higher-order dispersion branch,and the other is the local minimum due to the interplay between the dipolar and exchange interactions.These fine structures on the voltage spectrum confirm the spin pumping by higher-order dipole-exchange spin-wave modes,and are helpful for probing the multimode spin-wave spectrum.
文摘The microphase separation extent of biomedical segmented polyetherurethanes were greatly enhanced due to the presence of sulfoalkyl pendant groups contained in the hard segments,and the hard segments were more orderly aggregated through ionic interaction.
