Decomposition experiments conducted with and without microbial processes are commonly used to study the effects of environmental microorganisms on the degradation of organic pollutants.However,the effects of biologica...Decomposition experiments conducted with and without microbial processes are commonly used to study the effects of environmental microorganisms on the degradation of organic pollutants.However,the effects of biological pretreatment （sterilization） on organic matter often have a negative impact on such experiments.Based on the principle of water total organic carbon （TOC） analysis,the effects of physical sterilization treatments on determination of TOC and other water quality parameters were investigated.The results revealed that two conventional physical sterilization treatments,autoclaving and 60 Co γ-radiation sterilization,led to the direct decomposition of some organic pollutants,resulting in remarkable errors in the analysis of TOC in water samples.Furthermore,the extent of the errors varied with the intensity and the duration of sterilization treatments.Accordingly,a novel sterilization method for water samples,0.45 μm micro-filtration coupled with ultraviolet radiation （MCUR）,was developed in the present study.The results indicated that the MCUR method was capable of exerting a high bactericidal effect on the water sample while significantly decreasing the negative impact on the analysis of TOC and other water quality parameters.Before and after sterilization treatments,the relative errors of TOC determination could be controlled to lower than 3% for water samples with different categories and concentrations of organic pollutants by using MCUR.展开更多
Synthetic membranes have gained an important place in chemical technology and are used in a broad range of applications. UV irradiation is an age old process used for disinfection as well as for sterilization purposes...Synthetic membranes have gained an important place in chemical technology and are used in a broad range of applications. UV irradiation is an age old process used for disinfection as well as for sterilization purposes. It is used for sterilizing equipment in which polysulfone (PSf) membranes are used. As a result, short time UV irradiation of polymer membranes has acquired importance in recent times. In the present study, microporous polysulfone membranes with0.108 mmthickness have been prepared using phase inversion method. Effect of UV irradiation on the membranes for short time intervals (0 - 60 minutes) has been investigated using UV-Vis and FTIR spectrophotometer, and SEM. The performance of the membranes has studied by filtration techniques. UV-Vis and IR spectra analysis and SEM images obtained suggest that chains scission and crosslink have occurred simultaneously in the irradiated membranes by UV radiation in a dose dependant manner. The pure water flux (PWF) values of irradiated membranes obtained from filtration studies were higher compared to that of the control membrane. These results show that a very short UV irradiation (2 minutes) affected the physicochemical characteristics of microporous polysulfone membrane which it increases with increase in time.展开更多
The IMO(International Maritime Organization)recognized the problem of invasive species invasion and adopted the“International Convention for the Control and Management of Ships’Ballast Water and Sediments”in 2004,w...The IMO(International Maritime Organization)recognized the problem of invasive species invasion and adopted the“International Convention for the Control and Management of Ships’Ballast Water and Sediments”in 2004,which came into force on September 8,2017.In 2011,the IMO approved the“Guidelines for the Control and Management of Ships’Biofouling to Minimize the Transfer of Invasive Aquatic Species”to minimize the movement of invasive species by hull-attached organisms and required ships to manage the organisms attached to their hulls.Invasive species enter new environments through ships’ballast water and hull attachment.However,several obstacles to implementing these guidelines have been identified,including a lack of underwater cleaning equipment,regulations on underwater cleaning activities in ports,and difficulty in accessing crevices in underwater areas.The shipping industry,which is the party responsible for understanding these guidelines,wants to implement them for fuel cost savings resulting from the removal of organisms attached to the hull,but they anticipate significant difficulties in implementing the guidelines due to the obstacles mentioned above.Robots or people remove the organisms attached to the hull underwater,and the resulting wastewater includes various species of organisms and particles of paint and other pollutants.Currently,there is no technology available to sterilize the organisms in the wastewater or stabilize the heavy metals in the paint particles.In this study,we aim to analyse the characteristics of the wastewater generated from the removal of hull-attached organisms and select the optimal treatment technology.The organisms in the wastewater generated from the removal of the attached organisms meet the biological treatment standard(D-2)using the sterilization technology applied in the ships’ballast water treatment system.The heavy metals and other pollutants in the paint particles generated during removal are treated using stabilization technologies such as thermal deco展开更多
基金supported by the National Natural Science Foundation of China (No. 40821140540)the National High Technology Research and Development Program (863) of China (No. 2007AA10Z218)
文摘Decomposition experiments conducted with and without microbial processes are commonly used to study the effects of environmental microorganisms on the degradation of organic pollutants.However,the effects of biological pretreatment （sterilization） on organic matter often have a negative impact on such experiments.Based on the principle of water total organic carbon （TOC） analysis,the effects of physical sterilization treatments on determination of TOC and other water quality parameters were investigated.The results revealed that two conventional physical sterilization treatments,autoclaving and 60 Co γ-radiation sterilization,led to the direct decomposition of some organic pollutants,resulting in remarkable errors in the analysis of TOC in water samples.Furthermore,the extent of the errors varied with the intensity and the duration of sterilization treatments.Accordingly,a novel sterilization method for water samples,0.45 μm micro-filtration coupled with ultraviolet radiation （MCUR）,was developed in the present study.The results indicated that the MCUR method was capable of exerting a high bactericidal effect on the water sample while significantly decreasing the negative impact on the analysis of TOC and other water quality parameters.Before and after sterilization treatments,the relative errors of TOC determination could be controlled to lower than 3% for water samples with different categories and concentrations of organic pollutants by using MCUR.
文摘Synthetic membranes have gained an important place in chemical technology and are used in a broad range of applications. UV irradiation is an age old process used for disinfection as well as for sterilization purposes. It is used for sterilizing equipment in which polysulfone (PSf) membranes are used. As a result, short time UV irradiation of polymer membranes has acquired importance in recent times. In the present study, microporous polysulfone membranes with0.108 mmthickness have been prepared using phase inversion method. Effect of UV irradiation on the membranes for short time intervals (0 - 60 minutes) has been investigated using UV-Vis and FTIR spectrophotometer, and SEM. The performance of the membranes has studied by filtration techniques. UV-Vis and IR spectra analysis and SEM images obtained suggest that chains scission and crosslink have occurred simultaneously in the irradiated membranes by UV radiation in a dose dependant manner. The pure water flux (PWF) values of irradiated membranes obtained from filtration studies were higher compared to that of the control membrane. These results show that a very short UV irradiation (2 minutes) affected the physicochemical characteristics of microporous polysulfone membrane which it increases with increase in time.
基金supported by IITP(Institute of Information&Communications Technology Planning&Evaluation)grant funded by the Korea government(MSIT)(RS-2023-0022378,Development of industry-level technology bridging ICT for coal2biomethane)and KIMST(Korea Institute of Marine Science&Technology Promotion)funded by the Ministry of Oceans and Fisheries,Korea(No.20210500,Development of treatment technology of marine bio-fouling on ship hull).
文摘The IMO(International Maritime Organization)recognized the problem of invasive species invasion and adopted the“International Convention for the Control and Management of Ships’Ballast Water and Sediments”in 2004,which came into force on September 8,2017.In 2011,the IMO approved the“Guidelines for the Control and Management of Ships’Biofouling to Minimize the Transfer of Invasive Aquatic Species”to minimize the movement of invasive species by hull-attached organisms and required ships to manage the organisms attached to their hulls.Invasive species enter new environments through ships’ballast water and hull attachment.However,several obstacles to implementing these guidelines have been identified,including a lack of underwater cleaning equipment,regulations on underwater cleaning activities in ports,and difficulty in accessing crevices in underwater areas.The shipping industry,which is the party responsible for understanding these guidelines,wants to implement them for fuel cost savings resulting from the removal of organisms attached to the hull,but they anticipate significant difficulties in implementing the guidelines due to the obstacles mentioned above.Robots or people remove the organisms attached to the hull underwater,and the resulting wastewater includes various species of organisms and particles of paint and other pollutants.Currently,there is no technology available to sterilize the organisms in the wastewater or stabilize the heavy metals in the paint particles.In this study,we aim to analyse the characteristics of the wastewater generated from the removal of hull-attached organisms and select the optimal treatment technology.The organisms in the wastewater generated from the removal of the attached organisms meet the biological treatment standard(D-2)using the sterilization technology applied in the ships’ballast water treatment system.The heavy metals and other pollutants in the paint particles generated during removal are treated using stabilization technologies such as thermal deco
