Hypersonic glide vehicles (HGVs) are launched by a solid booster and glide through the atmosphere at high speeds. HGVs will be important means for rapid long-range delivery in the future. Given that the glide is unp...Hypersonic glide vehicles (HGVs) are launched by a solid booster and glide through the atmosphere at high speeds. HGVs will be important means for rapid long-range delivery in the future. Given that the glide is unpowered, the initial glide conditions (IGCs) are crucial for flight. This paper aims to find the optimal IGCs to improve the maneuverability and decrease the con- straints of HGVs. By considering the IGCs as experiment factors, we design an orthogonal table with three factors that have five levels each by using the orthogonal experimental design method. Thereafter, we apply the Gauss pseudospectral method to perform glide trajectory optimization by using each test of the orthogonal table as the initial condition. Based on the analytic hierarchy process, an integrated indicator is established to evaluate the IGCs, which synthesizes the indexes of the maneuverability and constraints. The integrated indicator is calculated from the trajectory opti- mization results. Finally, optimal IGCs and valuable conclusions are obtained by using range anal- ysis, variance analysis, and regression analysis on the integrated indicator.展开更多
The extractive desulfurization of a model gaso- line containing several alkyl thiols and aromatic thiophenic compounds was investigated using two imidazolium-based ionic liquids (ILs), 1-butyl-3-methylimidazolium te...The extractive desulfurization of a model gaso- line containing several alkyl thiols and aromatic thiophenic compounds was investigated using two imidazolium-based ionic liquids (ILs), 1-butyl-3-methylimidazolium tetrachloroaluminate, and 1-octyl-3-methylimidazolium te- trafluoroborate, as extractants. A fractional factorial design of experiments was employed to evaluate the effects and possible interactions of several process variables. Analysis of variance tests indicated that the number of extraction steps and the IL/gasoline volume ratio were of statistically highly significant, but none of the interactions were significant. The results showed that the desulfurization efficiency of the model gasoline by the ILs could reach 95.2 % under the optimal conditions. The optimized conditions were applied to study the extraction of thiophenic compounds in model gasoline and several real gasoline samples; the following order was observed in their separation: benzothio- phenc 〉 thiophcne 〉 3-methylthiophene 〉 2-methylthiophene, with 96.1% removal efficiency for benzothiophene. The IL extraction was successfully applied as a complementary process to the adsorptive desulfurization with acti- vated Raney nickel and acetonitrile solvent. The results indicated that the adsorptive process combined with IL extraction could provide high efficiency and selectivity, which can be regarded as a promising energy efficient desulfurization strategy for production of low-sulfur gasoline.展开更多
Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely low permeability...Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely low permeability of the formation matrix. Injecting carbon dioxide(CO2) into oil shale formations can potentially improve oil recovery. Furthermore, the large surface area in organicrich shale could permanently store CO2 without jeopardizing the formation integrity. This work is a mechanism study of evaluating the effectiveness of CO2-enhanced oil shale recovery and shale formation CO2 sequestration capacity using numerical simulation. Petrophysical and fluid properties similar to the Bakken Formation are used to set up the base model for simulation. Result shows that the CO_2 injection could increase the oil recovery factor from7.4% to 53%. In addition, petrophysical characteristics such as in situ stress changes and presence of a natural fracture network in the shale formation are proven to have impacts on subsurface CO2 flow. A response surface modeling approach was applied to investigate the interaction between parameters and generate a proxy model for optimizing oil recovery and CO2 injectivity.展开更多
The management of municipal solid waste (MSW) is currently one of the major environmental concerns in Mexico. Therefore, municipalities must develop local programs for prevention and integrated management of MSW bas...The management of municipal solid waste (MSW) is currently one of the major environmental concerns in Mexico. Therefore, municipalities must develop local programs for prevention and integrated management of MSW based on the data of MSW generation; however, these are scarce and diffuse. It is known that the MSW generation is affected by many factors, including life level. Given the importance of having reliable data, the objective of this study was to determine the per capita MSW generation of a small urban locality in the state of Veracruz and test whether there were significant statistic differences of per capita M SW generation among the life levels. The households were randomly sampled according to the Mexican standard of reference and were classified as popular, middle and residential. The per capita MSW generation determined was 0.355 kg·inhab^-1.day^-1. This value was lower than the value estimated by the national reference, suggesting that it might be overestimated and consequently lead to errors in estimating installations costs for the MSW treatment. The result of the experimental design revealed that there were significant statistic differences in the per capita MSW generation among the three socioeconomic strata. This study will allow the municipality to establish better strategies within the municipal program and differential rate for the provision of public clean service and it also provides a solid basis for future research under similar conditions.展开更多
由于用大肠杆菌对植物乳杆菌来源的bsh基因进行胞内和胞外表达时,它们很容易形成包涵体,而且大肠杆菌的内毒素会显限制BSH的应用,所以利用毕赤酵母这一高效的表达系统对其进行了分泌表达.首先用融合PCR的方法将信号肽α-factor与BSH连接...由于用大肠杆菌对植物乳杆菌来源的bsh基因进行胞内和胞外表达时,它们很容易形成包涵体,而且大肠杆菌的内毒素会显限制BSH的应用,所以利用毕赤酵母这一高效的表达系统对其进行了分泌表达.首先用融合PCR的方法将信号肽α-factor与BSH连接,然后再克隆到质粒pPIC9K上,得到重组质粒pPIC9K-α-factor-BSH.重组质粒经过SalⅠ线性化后转化至毕赤酵母GS115.表达产物经SDS-PAGE分析和酶活测定发现,重组BSH的相对分子质量(Mr)和胞外酶活分别为37.0×103和1.08 U mL-1.通过正交实验[L9(34)]对发酵条件优化后,胞外总酶活达到2.69 U mL-1,比原来提高了1.49倍.研究为胆盐水解酶的分离纯化、酶学性质研究以及大规模生产奠定了一定的基础.展开更多
基金supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20116102120004)
文摘Hypersonic glide vehicles (HGVs) are launched by a solid booster and glide through the atmosphere at high speeds. HGVs will be important means for rapid long-range delivery in the future. Given that the glide is unpowered, the initial glide conditions (IGCs) are crucial for flight. This paper aims to find the optimal IGCs to improve the maneuverability and decrease the con- straints of HGVs. By considering the IGCs as experiment factors, we design an orthogonal table with three factors that have five levels each by using the orthogonal experimental design method. Thereafter, we apply the Gauss pseudospectral method to perform glide trajectory optimization by using each test of the orthogonal table as the initial condition. Based on the analytic hierarchy process, an integrated indicator is established to evaluate the IGCs, which synthesizes the indexes of the maneuverability and constraints. The integrated indicator is calculated from the trajectory opti- mization results. Finally, optimal IGCs and valuable conclusions are obtained by using range anal- ysis, variance analysis, and regression analysis on the integrated indicator.
基金National Iranian Oil Refining & Distribution Company(NIORDC) and Research & Development (R&D) center of this company for their financial support during the completion of this work
文摘The extractive desulfurization of a model gaso- line containing several alkyl thiols and aromatic thiophenic compounds was investigated using two imidazolium-based ionic liquids (ILs), 1-butyl-3-methylimidazolium tetrachloroaluminate, and 1-octyl-3-methylimidazolium te- trafluoroborate, as extractants. A fractional factorial design of experiments was employed to evaluate the effects and possible interactions of several process variables. Analysis of variance tests indicated that the number of extraction steps and the IL/gasoline volume ratio were of statistically highly significant, but none of the interactions were significant. The results showed that the desulfurization efficiency of the model gasoline by the ILs could reach 95.2 % under the optimal conditions. The optimized conditions were applied to study the extraction of thiophenic compounds in model gasoline and several real gasoline samples; the following order was observed in their separation: benzothio- phenc 〉 thiophcne 〉 3-methylthiophene 〉 2-methylthiophene, with 96.1% removal efficiency for benzothiophene. The IL extraction was successfully applied as a complementary process to the adsorptive desulfurization with acti- vated Raney nickel and acetonitrile solvent. The results indicated that the adsorptive process combined with IL extraction could provide high efficiency and selectivity, which can be regarded as a promising energy efficient desulfurization strategy for production of low-sulfur gasoline.
基金support from the Warwick Energy Group and University of Oklahoma to publish this work
文摘Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely low permeability of the formation matrix. Injecting carbon dioxide(CO2) into oil shale formations can potentially improve oil recovery. Furthermore, the large surface area in organicrich shale could permanently store CO2 without jeopardizing the formation integrity. This work is a mechanism study of evaluating the effectiveness of CO2-enhanced oil shale recovery and shale formation CO2 sequestration capacity using numerical simulation. Petrophysical and fluid properties similar to the Bakken Formation are used to set up the base model for simulation. Result shows that the CO_2 injection could increase the oil recovery factor from7.4% to 53%. In addition, petrophysical characteristics such as in situ stress changes and presence of a natural fracture network in the shale formation are proven to have impacts on subsurface CO2 flow. A response surface modeling approach was applied to investigate the interaction between parameters and generate a proxy model for optimizing oil recovery and CO2 injectivity.
文摘The management of municipal solid waste (MSW) is currently one of the major environmental concerns in Mexico. Therefore, municipalities must develop local programs for prevention and integrated management of MSW based on the data of MSW generation; however, these are scarce and diffuse. It is known that the MSW generation is affected by many factors, including life level. Given the importance of having reliable data, the objective of this study was to determine the per capita MSW generation of a small urban locality in the state of Veracruz and test whether there were significant statistic differences of per capita M SW generation among the life levels. The households were randomly sampled according to the Mexican standard of reference and were classified as popular, middle and residential. The per capita MSW generation determined was 0.355 kg·inhab^-1.day^-1. This value was lower than the value estimated by the national reference, suggesting that it might be overestimated and consequently lead to errors in estimating installations costs for the MSW treatment. The result of the experimental design revealed that there were significant statistic differences in the per capita MSW generation among the three socioeconomic strata. This study will allow the municipality to establish better strategies within the municipal program and differential rate for the provision of public clean service and it also provides a solid basis for future research under similar conditions.
文摘由于用大肠杆菌对植物乳杆菌来源的bsh基因进行胞内和胞外表达时,它们很容易形成包涵体,而且大肠杆菌的内毒素会显限制BSH的应用,所以利用毕赤酵母这一高效的表达系统对其进行了分泌表达.首先用融合PCR的方法将信号肽α-factor与BSH连接,然后再克隆到质粒pPIC9K上,得到重组质粒pPIC9K-α-factor-BSH.重组质粒经过SalⅠ线性化后转化至毕赤酵母GS115.表达产物经SDS-PAGE分析和酶活测定发现,重组BSH的相对分子质量(Mr)和胞外酶活分别为37.0×103和1.08 U mL-1.通过正交实验[L9(34)]对发酵条件优化后,胞外总酶活达到2.69 U mL-1,比原来提高了1.49倍.研究为胆盐水解酶的分离纯化、酶学性质研究以及大规模生产奠定了一定的基础.