TiO2/graphene composite photocatalysts have been prepared by a simple liquid phase deposition method using titanium tetrafluoride and electron beam （EB） irradiation-pretreated graphene as the raw materials. The prod...TiO2/graphene composite photocatalysts have been prepared by a simple liquid phase deposition method using titanium tetrafluoride and electron beam （EB） irradiation-pretreated graphene as the raw materials. The products were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The effects of varying the synthesis parameters such as graphene content, concentration of titanium tetrafluoride solution and irradiation dose were investigated. It was found that the preparation conditions had a significant effect on the structure and properties of the final products. The irradiated graphene was covered with petal-like anatase TiO2 nanoparticles, which were more uniform and smaller in size than those in products synthesized without EB irradiation-pretreated graphene. The photocatalytic activities of the products were evaluated using the photocatalytic degradation of methyl orange as a probe reaction. The results showed that the products synthesized using EB irradiation-pretreated graphene exhibited higher photocatalytic activities than those using graphene without EB irradiation pretreatment.展开更多
为确定三文鱼电子束辐照的最佳剂量,以生鲜三文鱼为研究对象,采用0(未辐照)、0.5、1.0、2.0k Gy 4种不同剂量的电子束进行辐照处理,贮藏于0℃下,通过检测贮藏过程中鱼体的挥发性盐基氮、菌落总数、酸价、失重率、色差及质构等指标,研究...为确定三文鱼电子束辐照的最佳剂量,以生鲜三文鱼为研究对象,采用0(未辐照)、0.5、1.0、2.0k Gy 4种不同剂量的电子束进行辐照处理,贮藏于0℃下,通过检测贮藏过程中鱼体的挥发性盐基氮、菌落总数、酸价、失重率、色差及质构等指标,研究电子束辐照剂量对三文鱼品质及其货架期的影响。结果表明,电子束辐照可以抑制三文鱼挥发性盐基氮的产生和菌落总数的增长,且辐照剂量越大,效果越明显;辐照剂量越大,贮藏初期的酸价越高,但在贮藏期间较未辐照组稳定,无明显的增大趋势;1.0 k Gy和2.0 k Gy剂量使三文鱼颜色变暗,0.5 k Gy较未辐照组差异不显著;贮藏末期,经过辐照的三文鱼的黏附性相对未辐照组小,硬度、弹性以及咀嚼性与未辐照组无显著差异,各剂量之间也无显著差异。综合各指标,0.5 k Gy剂量的电子束可以更好地保持三文鱼的品质。本研究结果为三文鱼的保鲜提供了有效的技术手段和一定的参考依据。展开更多
为减少有害微生物对小麦粉的污染,本文研究了电子束辐照对小麦粉的杀菌效果以及对其理化性质、流变学品质的影响。结果表明:电子束辐照处理可显著降低小麦粉中的微生物含量,且随着辐照剂量的增加,杀菌效果越显著;菌落总数、霉菌、酵母...为减少有害微生物对小麦粉的污染,本文研究了电子束辐照对小麦粉的杀菌效果以及对其理化性质、流变学品质的影响。结果表明:电子束辐照处理可显著降低小麦粉中的微生物含量,且随着辐照剂量的增加,杀菌效果越显著;菌落总数、霉菌、酵母、蜡样芽孢杆菌、需氧芽孢菌的辐照杀菌剂量D10值分别为1.94、2.12、2.69、2.51和2.46 k Gy;剂量为1~5 kGy时,辐照对小麦粉基本营养成分及氨基酸含量无明显影响;辐照后小麦粉的湿面筋含量、面筋持水率也无明显变化,但面筋指数、降落数值随着剂量增加有所减小;辐照可提高小麦粉面团的吸水率,降低形成时间和稳定时间等;面团的拉伸面积、拉伸阻力和拉伸比例等面团流变学特性参数,均呈现先升高后降低趋势,但变化幅度很小。展开更多
基金The work was co-supported by the National Natural Science Foundation of China （No. 20871081）, the Science and Technology Commission of Shanghai Municipality （Nos. 10QH1401000 and 10DZ0500100）, the Research Funding of the State Key Laboratory of Chemical Engineering （ECUST）, the Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry （ECNU）, and Shanghai Leading Academic Disciplines （No. $30109）.
文摘TiO2/graphene composite photocatalysts have been prepared by a simple liquid phase deposition method using titanium tetrafluoride and electron beam （EB） irradiation-pretreated graphene as the raw materials. The products were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The effects of varying the synthesis parameters such as graphene content, concentration of titanium tetrafluoride solution and irradiation dose were investigated. It was found that the preparation conditions had a significant effect on the structure and properties of the final products. The irradiated graphene was covered with petal-like anatase TiO2 nanoparticles, which were more uniform and smaller in size than those in products synthesized without EB irradiation-pretreated graphene. The photocatalytic activities of the products were evaluated using the photocatalytic degradation of methyl orange as a probe reaction. The results showed that the products synthesized using EB irradiation-pretreated graphene exhibited higher photocatalytic activities than those using graphene without EB irradiation pretreatment.
文摘为确定三文鱼电子束辐照的最佳剂量,以生鲜三文鱼为研究对象,采用0(未辐照)、0.5、1.0、2.0k Gy 4种不同剂量的电子束进行辐照处理,贮藏于0℃下,通过检测贮藏过程中鱼体的挥发性盐基氮、菌落总数、酸价、失重率、色差及质构等指标,研究电子束辐照剂量对三文鱼品质及其货架期的影响。结果表明,电子束辐照可以抑制三文鱼挥发性盐基氮的产生和菌落总数的增长,且辐照剂量越大,效果越明显;辐照剂量越大,贮藏初期的酸价越高,但在贮藏期间较未辐照组稳定,无明显的增大趋势;1.0 k Gy和2.0 k Gy剂量使三文鱼颜色变暗,0.5 k Gy较未辐照组差异不显著;贮藏末期,经过辐照的三文鱼的黏附性相对未辐照组小,硬度、弹性以及咀嚼性与未辐照组无显著差异,各剂量之间也无显著差异。综合各指标,0.5 k Gy剂量的电子束可以更好地保持三文鱼的品质。本研究结果为三文鱼的保鲜提供了有效的技术手段和一定的参考依据。
文摘为减少有害微生物对小麦粉的污染,本文研究了电子束辐照对小麦粉的杀菌效果以及对其理化性质、流变学品质的影响。结果表明:电子束辐照处理可显著降低小麦粉中的微生物含量,且随着辐照剂量的增加,杀菌效果越显著;菌落总数、霉菌、酵母、蜡样芽孢杆菌、需氧芽孢菌的辐照杀菌剂量D10值分别为1.94、2.12、2.69、2.51和2.46 k Gy;剂量为1~5 kGy时,辐照对小麦粉基本营养成分及氨基酸含量无明显影响;辐照后小麦粉的湿面筋含量、面筋持水率也无明显变化,但面筋指数、降落数值随着剂量增加有所减小;辐照可提高小麦粉面团的吸水率,降低形成时间和稳定时间等;面团的拉伸面积、拉伸阻力和拉伸比例等面团流变学特性参数,均呈现先升高后降低趋势,但变化幅度很小。
