The formation of nanoporous Pd was studied by electro-chemical dealloying a rapidly-quenched Al70Pd17Fe13 quasicrystal alloy in dilute NaCl aqueous solution,and the electro-catalytic activity of the nanoporous Pd towa...The formation of nanoporous Pd was studied by electro-chemical dealloying a rapidly-quenched Al70Pd17Fe13 quasicrystal alloy in dilute NaCl aqueous solution,and the electro-catalytic activity of the nanoporous Pd towards methanol electro-oxidation was evaluated by cyclic voltammetry in 1 mol/L KOH solution.XRD and TEM analyses revealed that nano-decomposition of quasicrystal grains occurred in the initial stage of dealloying,and the fully dealloyed sample was composed of FCC-Pd phase.Scanning electron microscopy observation indicated that a maze-like nanoporous pattern was formed in the dealloyed sample,consisting of percolated pores of 5.20 nm in diameter in a skeleton of randomly-orientated Pd nano-ligaments with a uniform thickness of^5 nm.A retention of^12 at.%Al in the Pd nano-ligments was determined by energy dispersive X-ray spectroscopy(EDS).The nanoporous Pd demonstrated obvious electro-catalytic activity towards methanol electro-oxidation in alkaline environment.展开更多
基金supported by the National Natural Science Foundation of China(21103055)Special Fund of Basic Scientific Research Business Expenses of Huaqiao University,China(JB-ZR1139)~~
基金Foundation item:Project(51671045)supported by the National Natural Science Foundation of ChinaProject(DUT18GF112)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(TZ2016004)supported by the Science Challenge Project,China
文摘The formation of nanoporous Pd was studied by electro-chemical dealloying a rapidly-quenched Al70Pd17Fe13 quasicrystal alloy in dilute NaCl aqueous solution,and the electro-catalytic activity of the nanoporous Pd towards methanol electro-oxidation was evaluated by cyclic voltammetry in 1 mol/L KOH solution.XRD and TEM analyses revealed that nano-decomposition of quasicrystal grains occurred in the initial stage of dealloying,and the fully dealloyed sample was composed of FCC-Pd phase.Scanning electron microscopy observation indicated that a maze-like nanoporous pattern was formed in the dealloyed sample,consisting of percolated pores of 5.20 nm in diameter in a skeleton of randomly-orientated Pd nano-ligaments with a uniform thickness of^5 nm.A retention of^12 at.%Al in the Pd nano-ligments was determined by energy dispersive X-ray spectroscopy(EDS).The nanoporous Pd demonstrated obvious electro-catalytic activity towards methanol electro-oxidation in alkaline environment.
