The transport of La(III) through a dispersion supported liquid membrane with polyvinylidene fluoride membrane as the liquid membrane support and dispersion solution including HCl solution as the stripping solution and...The transport of La(III) through a dispersion supported liquid membrane with polyvinylidene fluoride membrane as the liquid membrane support and dispersion solution including HCl solution as the stripping solution and 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (PC-88A) in kerosene as the membrane solution, was studied. As a result, the optimum transport conditions of La(Ⅲ) were obtained as that concentration of HCl solution was 4.0 mol/L, concentration of PC-88A 0.16 mol/L, and volume ratio of membrane to stripping solution 30:30 in the dispersion phase, and pH value 4.0 in the feed phase. Ionic strength had no obvious effect on the transport of La(Ⅲ). Under the optimum conditions, when initial concentration of La(Ⅲ) was 0.8×10-4 mol/L, the transport rate was up to 96.3% during the transport time of 125 min. The kinetic equation was developed based on the law of mass diffusion and theory of interface chemistry. The diffusion coefficient of La(Ⅲ) in the membrane and the thickness of diffusion layer between feed and membrane phases were obtained as 3.20×10-7 m2/s and 3.22×10-5 m, respectively. The calculated results were in good agreement with experimental results.展开更多
The transport of Tb（III） in dispersion supported liquid membrane（DSLM） with polyvinylidene fluoride membrane（PVDF） as the support and dispersion solution including HCl solution as the stripping solution and di（...The transport of Tb（III） in dispersion supported liquid membrane（DSLM） with polyvinylidene fluoride membrane（PVDF） as the support and dispersion solution including HCl solution as the stripping solution and di（2-ethylhexyl） phosphoric acid（D2EHPA） dissolved in kerosene as the membrane solution, has been studied. The effects of pH value, initial concentration of Tb（III） and different ionic strength in the feed phase, volume ratio of membrane solution to stripping solution, concentration of HCl solution, concentration of carrier, different stripping agents in the dispersion phase on the transport of Tb（III） have also been investigated, respectively. As a result, the optimum transport conditions of Tb（III） were obtained, i.e., the concentration of HCl solution was 4.0 mol/L, the concentration of D2EHPA was 0.16 mol/L, the volume ratio of membrane solution to stripping solution was 30：30 in the dispersion phase and pH value was 4.5 in the feed phase. Ionic strength had no obvious effect on the transport of Tb（III）. Under the optimum conditions, the transport percentage of Tb（III） was up to 96.1% in a transport time of 35 min when the initial concentration of Tb（IIl） was 1.0× 10 -4 mol/L. The diffusion coefficient of Tb（III） in the membrane and the thickness of diffusion layer between feed phase and membrane phase were obtained and the values were 1.82×10 -8 m2/s and 5.61 um, respectively. The calculated results were in good agreement with the literature data.展开更多
The transport of Dy（III） through a dispersion supported liquid membrane （DSLM） consisting of polyvinylidene fluoride membrane （PVDF） as the liquid membrane support and dispersion solution including HCI solution ...The transport of Dy（III） through a dispersion supported liquid membrane （DSLM） consisting of polyvinylidene fluoride membrane （PVDF） as the liquid membrane support and dispersion solution including HCI solution as the stripping solution and 2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester （PC-88A） dissolved in kerosene as the membrane solution, was studied. The effects of pH value, initial concentration of Dy（III） and different ionic strength in the feed phase, volume ratio of membrane solution and stripping solution, concentration of HCl solution, concentration of carrier, different stripping agents in the dispersion phase on transport of Dy（III） were also investigated, respectively. As a result, when the concentration of HCI solution was 4.0 mol/L, concentration of PC-88A was 0.10 mol/L, and volume ratio of membrane solution and stripping solution was 40：20 in the dispersion phase, and pH value was 5.0 in the feed phase, the transport effect of Dy（III） was the best. Ionic strength had no obvious effect on transport of Dy（III）. Under the optimum condition studied, when initial concentration of Dy（III） was 0.8×10^-4 mol/L, the transport rate of Dy（III） was up to 96.2% during the transport time of 95 rain. The kinetic equation was developed in terms of the law of mass diffusion and the theory of interface chemistry. The diffusion coefficient of Dy（III） in the membrane and the thickness of diffusion layer between feed phase and membrane phase were obtained and the values were 1.99×10^-7 m^2/s and 15.97 μm, respectively. The results were in good agreement with experimental results.展开更多
基金Supported by the National Natural Science Foundation of China (No.90401009)Research Fund for Excellent Doctoral Thesis of Xi'an University of Technology (No.602-210805)
文摘The transport of La(III) through a dispersion supported liquid membrane with polyvinylidene fluoride membrane as the liquid membrane support and dispersion solution including HCl solution as the stripping solution and 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (PC-88A) in kerosene as the membrane solution, was studied. As a result, the optimum transport conditions of La(Ⅲ) were obtained as that concentration of HCl solution was 4.0 mol/L, concentration of PC-88A 0.16 mol/L, and volume ratio of membrane to stripping solution 30:30 in the dispersion phase, and pH value 4.0 in the feed phase. Ionic strength had no obvious effect on the transport of La(Ⅲ). Under the optimum conditions, when initial concentration of La(Ⅲ) was 0.8×10-4 mol/L, the transport rate was up to 96.3% during the transport time of 125 min. The kinetic equation was developed based on the law of mass diffusion and theory of interface chemistry. The diffusion coefficient of La(Ⅲ) in the membrane and the thickness of diffusion layer between feed and membrane phases were obtained as 3.20×10-7 m2/s and 3.22×10-5 m, respectively. The calculated results were in good agreement with experimental results.
基金Supported by the National Natural Science Foundation of China(No90401009)the Natural Science Foundation of Shaanxi Province, China(NoSJ08B16)+1 种基金the Science Research Program of Education Department of Shaanxi Province, China (No06JK215)the Research Fund for Excellent Doctoral Thesis of Xi'an University of Technology, China (No602-210805)
文摘The transport of Tb（III） in dispersion supported liquid membrane（DSLM） with polyvinylidene fluoride membrane（PVDF） as the support and dispersion solution including HCl solution as the stripping solution and di（2-ethylhexyl） phosphoric acid（D2EHPA） dissolved in kerosene as the membrane solution, has been studied. The effects of pH value, initial concentration of Tb（III） and different ionic strength in the feed phase, volume ratio of membrane solution to stripping solution, concentration of HCl solution, concentration of carrier, different stripping agents in the dispersion phase on the transport of Tb（III） have also been investigated, respectively. As a result, the optimum transport conditions of Tb（III） were obtained, i.e., the concentration of HCl solution was 4.0 mol/L, the concentration of D2EHPA was 0.16 mol/L, the volume ratio of membrane solution to stripping solution was 30：30 in the dispersion phase and pH value was 4.5 in the feed phase. Ionic strength had no obvious effect on the transport of Tb（III）. Under the optimum conditions, the transport percentage of Tb（III） was up to 96.1% in a transport time of 35 min when the initial concentration of Tb（IIl） was 1.0× 10 -4 mol/L. The diffusion coefficient of Tb（III） in the membrane and the thickness of diffusion layer between feed phase and membrane phase were obtained and the values were 1.82×10 -8 m2/s and 5.61 um, respectively. The calculated results were in good agreement with the literature data.
基金supported by the National Natural Science Foundation of China (90401009)Research Fund for Excellent Doctoral Thesis of Xi'an University of Technology (602-210805)
文摘The transport of Dy（III） through a dispersion supported liquid membrane （DSLM） consisting of polyvinylidene fluoride membrane （PVDF） as the liquid membrane support and dispersion solution including HCI solution as the stripping solution and 2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester （PC-88A） dissolved in kerosene as the membrane solution, was studied. The effects of pH value, initial concentration of Dy（III） and different ionic strength in the feed phase, volume ratio of membrane solution and stripping solution, concentration of HCl solution, concentration of carrier, different stripping agents in the dispersion phase on transport of Dy（III） were also investigated, respectively. As a result, when the concentration of HCI solution was 4.0 mol/L, concentration of PC-88A was 0.10 mol/L, and volume ratio of membrane solution and stripping solution was 40：20 in the dispersion phase, and pH value was 5.0 in the feed phase, the transport effect of Dy（III） was the best. Ionic strength had no obvious effect on transport of Dy（III）. Under the optimum condition studied, when initial concentration of Dy（III） was 0.8×10^-4 mol/L, the transport rate of Dy（III） was up to 96.2% during the transport time of 95 rain. The kinetic equation was developed in terms of the law of mass diffusion and the theory of interface chemistry. The diffusion coefficient of Dy（III） in the membrane and the thickness of diffusion layer between feed phase and membrane phase were obtained and the values were 1.99×10^-7 m^2/s and 15.97 μm, respectively. The results were in good agreement with experimental results.
