In this context,four specimens,i.e.(i)circumferentially notched cylindrical torsion(CNCT),(ii)circum-ferentially notched cylindrical direct tension(CNCDT),(iii)edge notch disc bend(ENDB)and(iv)three-point bend beam(3P...In this context,four specimens,i.e.(i)circumferentially notched cylindrical torsion(CNCT),(ii)circum-ferentially notched cylindrical direct tension(CNCDT),(iii)edge notch disc bend(ENDB)and(iv)three-point bend beam(3PBB),were utilized to measure the modesⅠandⅢfracture toughness values of gypsum.While the CNCT specimen provides pure modeⅢloading in a direct manner,this pure mode condition is indirectly produced by the ENDB specimen.The ENDB specimen provided lower KⅢc and a non-coplanar(i.e.twisted)fracture surface compared with the CNCT specimen,which showed a planar modeⅢfracture surface.The ENDB specimen is also employed for conducting pure modeⅠ(with different crack depths)and mixed modeⅠ/Ⅲtests.KIc value was independent of the notch depth,and it was consistent with the RILEM and ASTM standard methods.But the modeⅢfracture results were highly sensitive to the notch depth.While the fracture resistance against modeⅢwas significantly lower than that of modeⅠ,the greater work of fracture under modeⅢwas noticeable.展开更多
Direct formic acid fuel cells （DFAFCs） allow highly efficient low temperature conversion of chemical energy into electricity and are expected to play a vital role in our future sustainable society. However, the mass...Direct formic acid fuel cells （DFAFCs） allow highly efficient low temperature conversion of chemical energy into electricity and are expected to play a vital role in our future sustainable society. However, the massive precious metal usage in current membrane electrode assembly （MEA） technology greatly inhibits their actual applications. Here we demonstrate a new type of anode constructed by confining highly active nanoengineered catalysts into an ultra-thin catalyst layer with thickness around 100 nm. Specifically, an atomic layer of platinum is first deposited onto nanoporous gold （NPG） leaf to achieve high utilization of Pt and easy accessibility of both reactants and electrons to active sites. These NPG-Pt core/shell nanostructures are further decorated by a sub-monolayer of Bi to create highly active reaction sites for formic acid electro-oxidation. Thus obtained layer-structured NPG-Pt-Bi thin films allow a dramatic decrease in Pt usage down to 3 ~tg.cm-2, while maintaining very high electrode activity and power performance at sufficiently low overall precious metal loading. Moreover, these electrode materials show superior durability during half-year test in actual DFAFCs, with remarkable resistance to common impurities in formic acid, which together imply their great potential in applications in actual devices.展开更多
For estimating the long-term stability of underground framework,it is vital to learn the mechanical and rheological characteristics of rock in multiple water saturation conditions.However,the majority of previous stud...For estimating the long-term stability of underground framework,it is vital to learn the mechanical and rheological characteristics of rock in multiple water saturation conditions.However,the majority of previous studies explored the rheological properties of rock in air-dried and water saturated conditions,as well as the water effects on compressive and tensile strengths.In this study,andesite was subjected to direct shear tests under five water saturation conditions,which were controlled by varying the wetting and drying time.The tests were conducted at alternating displacement rates under three vertical stresses.The results reveal that the shear strength decreases exponentially as water saturation increases,and that the increase in shear strength with a tenfold increase in displacement rate is nearly constant for each of the vertical stresses.Based on the findings of the shear tests in this study and the compression and tension tests in previous studies,the influences of both water saturation and loading rate on the Hoek-Brown failure criterion for the andesite was examined.These results indicate that the brittleness index of the andesite,which is defined as the ratio of uniaxial compressive strength to tensile strength,is independent of both water saturation and loading rate and that the influences of the water saturation dependence and the loading rate dependence of the failure criterion can be converted between each other.展开更多
PtRu supported on TiO2-embedded carbon nanofibers(PtRu/TECNF),which was recently reported as a highly-active catalyst for methanol oxidation,was applied to a direct methanol fuel cell(DMFC),and the power generation pe...PtRu supported on TiO2-embedded carbon nanofibers(PtRu/TECNF),which was recently reported as a highly-active catalyst for methanol oxidation,was applied to a direct methanol fuel cell(DMFC),and the power generation performance was compared to that using the commercial PtRu/C.Before the comparison,the effect of the catalyst loading on the power density of the DMFC was investigated using PtRu(18 wt%)/TECNF.The DMFC power density showed a maximum at about a 1.5 mg cm2 PtRu loading that corresponds to about an 80 mm layer thickness.A catalyst layer thicker than this value reduced the power density probably due to the concentration overvoltage.The PtRu content in the PtRu/TECNF was then increased to 30 wt%or more to reduce the layer thickness and to increase the power density.The DMFC performance was compared to that of different anode catalysts at a 1 mg cm2 PtRu loading.The power density was maximized using the PtRu30 wt%/TECNF,which showed a 173 mW cm2 at 353 K and had 66 mm layer thick,that was 26%higher than that of commercial PtRu/C.The current–voltage curve of the DMFC with the PtRu/TECNF suggested an improved mass transport overvoltage,but a little improvement in the activation one despite using the catalyst with about a 2 times higher activity compared to that of the commercial PtRu/C.This was attributed to the lower Pt utilization of the nanofiber catalyst layer.展开更多
The distribution transformer is the mainstay of the power system.Its internal temperature study is desirable for its safe operation in the power system.The purpose of the present study is to determine direct comprehen...The distribution transformer is the mainstay of the power system.Its internal temperature study is desirable for its safe operation in the power system.The purpose of the present study is to determine direct comprehensive thermal distribution in the distribution transformers for different loading conditions.To achieve this goal,the temperature distribution in the oil,core,and windings are studied at each loading.An experimental study is performed with a 10/0.38 kV,10 kVA oil–immersed transformer equipped with forty–two PT100 sensors(PTs)for temperature measurement installed inside during its manufacturing process.All possible locations for the hottest spot temperature(HST)are considered that made by finite element analysis(FEA)simulation and losses calculations.A resistive load is made to achieve 80%to 120%loading of the test transformer for this experiment.Working temperature is measured in each part of the transformer at all provided loading conditions.It is observed that temperature varies with loading throughout the transformer,and a detailed map of temperature is obtained in the whole test transformer.From these results,the HST stays in the critical section of the primary winding at all loading conditions.This work is helpful to understand the complete internal temperature layout and the location of the HST in distribution transformers.展开更多
对具有不同拉伸应变特性(应变强化和应变软化)的超高性能混凝土(Ultra high performance concrete,UHPC)进行了单调和循环荷载作用下的直接拉伸试验。试验结果表明:应变强化UHPC基体开裂后进入多点微裂纹分布的应变强化段,达到极限抗拉...对具有不同拉伸应变特性(应变强化和应变软化)的超高性能混凝土(Ultra high performance concrete,UHPC)进行了单调和循环荷载作用下的直接拉伸试验。试验结果表明:应变强化UHPC基体开裂后进入多点微裂纹分布的应变强化段,达到极限抗拉强度后进入单缝开裂的应变软化段;应变软化UHPC基体开裂后直接进入单缝开裂的应变软化段;循环荷载下两种类型UHPC的轴拉应力-应变曲线包络线与单调荷载下的应力-应变曲线基本一致;基于刚度退化过程建立了两种类型UHPC的轴拉损伤演化方程,根据实测应力-应变曲线和试件的裂缝分布形态建立了两种类型UHPC的轴拉本构关系模型,与试验结果基本吻合;采用能量法研究了应变强化UHPC两阶段轴拉本构关系在数值计算时的等效方法。最后,通过无筋应变强化UHPC抗弯试验梁的数值模拟对本文建立的应变强化UHPC轴拉本构关系模型和损伤演化方程及相关假定进行了验证,结果表明本文建立的应变强化UHPC轴拉本构模型能较好地预测UHPC弯拉构件的极限承载力,轴拉损伤变量能在宏观层面上较好地反应试件的裂缝分布状态。展开更多
文摘In this context,four specimens,i.e.(i)circumferentially notched cylindrical torsion(CNCT),(ii)circum-ferentially notched cylindrical direct tension(CNCDT),(iii)edge notch disc bend(ENDB)and(iv)three-point bend beam(3PBB),were utilized to measure the modesⅠandⅢfracture toughness values of gypsum.While the CNCT specimen provides pure modeⅢloading in a direct manner,this pure mode condition is indirectly produced by the ENDB specimen.The ENDB specimen provided lower KⅢc and a non-coplanar(i.e.twisted)fracture surface compared with the CNCT specimen,which showed a planar modeⅢfracture surface.The ENDB specimen is also employed for conducting pure modeⅠ(with different crack depths)and mixed modeⅠ/Ⅲtests.KIc value was independent of the notch depth,and it was consistent with the RILEM and ASTM standard methods.But the modeⅢfracture results were highly sensitive to the notch depth.While the fracture resistance against modeⅢwas significantly lower than that of modeⅠ,the greater work of fracture under modeⅢwas noticeable.
文摘Direct formic acid fuel cells （DFAFCs） allow highly efficient low temperature conversion of chemical energy into electricity and are expected to play a vital role in our future sustainable society. However, the massive precious metal usage in current membrane electrode assembly （MEA） technology greatly inhibits their actual applications. Here we demonstrate a new type of anode constructed by confining highly active nanoengineered catalysts into an ultra-thin catalyst layer with thickness around 100 nm. Specifically, an atomic layer of platinum is first deposited onto nanoporous gold （NPG） leaf to achieve high utilization of Pt and easy accessibility of both reactants and electrons to active sites. These NPG-Pt core/shell nanostructures are further decorated by a sub-monolayer of Bi to create highly active reaction sites for formic acid electro-oxidation. Thus obtained layer-structured NPG-Pt-Bi thin films allow a dramatic decrease in Pt usage down to 3 ~tg.cm-2, while maintaining very high electrode activity and power performance at sufficiently low overall precious metal loading. Moreover, these electrode materials show superior durability during half-year test in actual DFAFCs, with remarkable resistance to common impurities in formic acid, which together imply their great potential in applications in actual devices.
文摘For estimating the long-term stability of underground framework,it is vital to learn the mechanical and rheological characteristics of rock in multiple water saturation conditions.However,the majority of previous studies explored the rheological properties of rock in air-dried and water saturated conditions,as well as the water effects on compressive and tensile strengths.In this study,andesite was subjected to direct shear tests under five water saturation conditions,which were controlled by varying the wetting and drying time.The tests were conducted at alternating displacement rates under three vertical stresses.The results reveal that the shear strength decreases exponentially as water saturation increases,and that the increase in shear strength with a tenfold increase in displacement rate is nearly constant for each of the vertical stresses.Based on the findings of the shear tests in this study and the compression and tension tests in previous studies,the influences of both water saturation and loading rate on the Hoek-Brown failure criterion for the andesite was examined.These results indicate that the brittleness index of the andesite,which is defined as the ratio of uniaxial compressive strength to tensile strength,is independent of both water saturation and loading rate and that the influences of the water saturation dependence and the loading rate dependence of the failure criterion can be converted between each other.
基金the Element Innovation Project,Ministry of Education,Japan,and by KAKENHI(26289300).
文摘PtRu supported on TiO2-embedded carbon nanofibers(PtRu/TECNF),which was recently reported as a highly-active catalyst for methanol oxidation,was applied to a direct methanol fuel cell(DMFC),and the power generation performance was compared to that using the commercial PtRu/C.Before the comparison,the effect of the catalyst loading on the power density of the DMFC was investigated using PtRu(18 wt%)/TECNF.The DMFC power density showed a maximum at about a 1.5 mg cm2 PtRu loading that corresponds to about an 80 mm layer thickness.A catalyst layer thicker than this value reduced the power density probably due to the concentration overvoltage.The PtRu content in the PtRu/TECNF was then increased to 30 wt%or more to reduce the layer thickness and to increase the power density.The DMFC performance was compared to that of different anode catalysts at a 1 mg cm2 PtRu loading.The power density was maximized using the PtRu30 wt%/TECNF,which showed a 173 mW cm2 at 353 K and had 66 mm layer thick,that was 26%higher than that of commercial PtRu/C.The current–voltage curve of the DMFC with the PtRu/TECNF suggested an improved mass transport overvoltage,but a little improvement in the activation one despite using the catalyst with about a 2 times higher activity compared to that of the commercial PtRu/C.This was attributed to the lower Pt utilization of the nanofiber catalyst layer.
文摘The distribution transformer is the mainstay of the power system.Its internal temperature study is desirable for its safe operation in the power system.The purpose of the present study is to determine direct comprehensive thermal distribution in the distribution transformers for different loading conditions.To achieve this goal,the temperature distribution in the oil,core,and windings are studied at each loading.An experimental study is performed with a 10/0.38 kV,10 kVA oil–immersed transformer equipped with forty–two PT100 sensors(PTs)for temperature measurement installed inside during its manufacturing process.All possible locations for the hottest spot temperature(HST)are considered that made by finite element analysis(FEA)simulation and losses calculations.A resistive load is made to achieve 80%to 120%loading of the test transformer for this experiment.Working temperature is measured in each part of the transformer at all provided loading conditions.It is observed that temperature varies with loading throughout the transformer,and a detailed map of temperature is obtained in the whole test transformer.From these results,the HST stays in the critical section of the primary winding at all loading conditions.This work is helpful to understand the complete internal temperature layout and the location of the HST in distribution transformers.
文摘对具有不同拉伸应变特性(应变强化和应变软化)的超高性能混凝土(Ultra high performance concrete,UHPC)进行了单调和循环荷载作用下的直接拉伸试验。试验结果表明:应变强化UHPC基体开裂后进入多点微裂纹分布的应变强化段,达到极限抗拉强度后进入单缝开裂的应变软化段;应变软化UHPC基体开裂后直接进入单缝开裂的应变软化段;循环荷载下两种类型UHPC的轴拉应力-应变曲线包络线与单调荷载下的应力-应变曲线基本一致;基于刚度退化过程建立了两种类型UHPC的轴拉损伤演化方程,根据实测应力-应变曲线和试件的裂缝分布形态建立了两种类型UHPC的轴拉本构关系模型,与试验结果基本吻合;采用能量法研究了应变强化UHPC两阶段轴拉本构关系在数值计算时的等效方法。最后,通过无筋应变强化UHPC抗弯试验梁的数值模拟对本文建立的应变强化UHPC轴拉本构关系模型和损伤演化方程及相关假定进行了验证,结果表明本文建立的应变强化UHPC轴拉本构模型能较好地预测UHPC弯拉构件的极限承载力,轴拉损伤变量能在宏观层面上较好地反应试件的裂缝分布状态。
