The effluent total phosphorus(ETP) is an important parameter to evaluate the performance of wastewater treatment process(WWTP). In this study, a novel method, using a data-derived soft-sensor method, is proposed to ob...The effluent total phosphorus(ETP) is an important parameter to evaluate the performance of wastewater treatment process(WWTP). In this study, a novel method, using a data-derived soft-sensor method, is proposed to obtain the reliable values of ETP online. First, a partial least square(PLS) method is introduced to select the related secondary variables of ETP based on the experimental data. Second, a radial basis function neural network(RBFNN) is developed to identify the relationship between the related secondary variables and ETP. This RBFNN easily optimizes the model parameters to improve the generalization ability of the soft-sensor. Finally, a monitoring system, based on the above PLS and RBFNN, named PLS-RBFNN-based soft-sensor system, is developed and tested in a real WWTP. Experimental results show that the proposed monitoring system can obtain the values of ETP online and own better predicting performance than some existing methods.展开更多
MOFs are among the most popular precursors and templates for deriving various porous materials,where the derivatives can inherit a large surface area,abundant active sites for targeted functionalities and a high degre...MOFs are among the most popular precursors and templates for deriving various porous materials,where the derivatives can inherit a large surface area,abundant active sites for targeted functionalities and a high degree of porosity inherited from their parent MOFs.Those unique structural features make them promising candidates in multiple applications.More interestingly,the structure and properties of these MOF derivatives can be modulated by the choice of the parent MOFs and the design in the conversion process.In this overview,the transformation pathways from MOFs into their porous derivatives,the principles underlying these transformations,and the behavior of the MOF components in the transition process are discussed.Recently,there has been tremendous progress in preserving and enhancing the surface area,the amount of active sites and the level of porosity of the MOF-derived materials for targeted applications,from the perspectives of both customizing the parent MOFs and tailoring the transformation process.To develop the rationally designed MOF-derived materials and thus to elucidate the precursor-process-product correlations,some typical examples of the MOF derivatives applied in electrochemical energy storage and conversion,water treatment,gas sensing,and biomedicine are discussed to demonstrate the effectiveness of the key design strategies.展开更多
Ru （bpy）<sub>3</sub><sup>2+</sup>and its derivatives have been extensively studied during the last ten years due to their chemical stability,redox properties and excited state reactivity. In ...Ru （bpy）<sub>3</sub><sup>2+</sup>and its derivatives have been extensively studied during the last ten years due to their chemical stability,redox properties and excited state reactivity. In particular,the Ru（Ⅱ） polypyridine complexes play key roles in the development of photochemistry,photophysics,chemi-and electrochemi-luminescence and dectron energy transfer.Discovered in 1951,ferrocene and its derivatives are important for developing the knowledge of dectronic structure and photochemistry. Ligand-containing Schiff-base ferrocene derivatives have great significance for the photo molecular device because of展开更多
With dimethomorph and flumorph as the leading compounds, four novel acrylamide compounds with two types of structure were designed and synthesized by means of the method of ＂me too chemistry＂. The target compounds w...With dimethomorph and flumorph as the leading compounds, four novel acrylamide compounds with two types of structure were designed and synthesized by means of the method of ＂me too chemistry＂. The target compounds were characterized by 1H NMR, IR, MS, and elemental analysis. The influences of solvent and raw material on the yield were investigated and optimum processing conditions were determined. The results of preliminary biological tests show that all those compounds exhibit certain antifungal activities.展开更多
This paper is a generalization of the results of the previous papers. Using these results a class of evolutions of risk assets based on the geometric Brownian motion is constructed. Among these evolutions of risk asse...This paper is a generalization of the results of the previous papers. Using these results a class of evolutions of risk assets based on the geometric Brownian motion is constructed. Among these evolutions of risk assets, the important class of the random processes is the random processes with parameters built on the basis of the discrete geometric Brownian motion. For this class of random processes the interval of non-arbitrage prices are found for the wide class of contingent liabilities. In particular, for the payoff functions of standard options call and put of the European type the fair prices of super-hedge are obtained. Analogous results are obtained for the put and call of arithmetical options of Asian type. For the parameters entering in the definition of random process the description of all statistical estimates is presented. Statistical estimate for which the fair price of super-hedge for the payoff functions of standard call and put options of European type is minimal is indicated. From the formulas found it follows that the fair price of super-hedge can be less than the price of the underlying asset. In terms of estimates the simple formula for the fair price of super-hedge is found. Every estimates can be realized in the reality. This depends on the distribution function of the observed dates in the financial market.展开更多
By Analyzing the behavior and character of derivative security, the authors established a pricing model of multiattribute derivative security whose underlying asset pricing process is a mixed process, and obtained a n...By Analyzing the behavior and character of derivative security, the authors established a pricing model of multiattribute derivative security whose underlying asset pricing process is a mixed process, and obtained a new model for option pricing of multiattribute derivatives based on mixed process, and improved some original results.展开更多
基金Supported by the National Science Foundation of China(61622301,61533002)Beijing Natural Science Foundation(4172005)Major National Science and Technology Project(2017ZX07104)
文摘The effluent total phosphorus(ETP) is an important parameter to evaluate the performance of wastewater treatment process(WWTP). In this study, a novel method, using a data-derived soft-sensor method, is proposed to obtain the reliable values of ETP online. First, a partial least square(PLS) method is introduced to select the related secondary variables of ETP based on the experimental data. Second, a radial basis function neural network(RBFNN) is developed to identify the relationship between the related secondary variables and ETP. This RBFNN easily optimizes the model parameters to improve the generalization ability of the soft-sensor. Finally, a monitoring system, based on the above PLS and RBFNN, named PLS-RBFNN-based soft-sensor system, is developed and tested in a real WWTP. Experimental results show that the proposed monitoring system can obtain the values of ETP online and own better predicting performance than some existing methods.
基金the National Research Foundation(NRF)Singapore for funding under NRF-CRP17-2017-01(R-284-000-165-281)for the research conducted at the National University of Singapore.
文摘MOFs are among the most popular precursors and templates for deriving various porous materials,where the derivatives can inherit a large surface area,abundant active sites for targeted functionalities and a high degree of porosity inherited from their parent MOFs.Those unique structural features make them promising candidates in multiple applications.More interestingly,the structure and properties of these MOF derivatives can be modulated by the choice of the parent MOFs and the design in the conversion process.In this overview,the transformation pathways from MOFs into their porous derivatives,the principles underlying these transformations,and the behavior of the MOF components in the transition process are discussed.Recently,there has been tremendous progress in preserving and enhancing the surface area,the amount of active sites and the level of porosity of the MOF-derived materials for targeted applications,from the perspectives of both customizing the parent MOFs and tailoring the transformation process.To develop the rationally designed MOF-derived materials and thus to elucidate the precursor-process-product correlations,some typical examples of the MOF derivatives applied in electrochemical energy storage and conversion,water treatment,gas sensing,and biomedicine are discussed to demonstrate the effectiveness of the key design strategies.
基金Project supported by the Grant for Major Project from the State Science and Technology Commission the National Natural Science Foundation of China.
文摘Ru （bpy）<sub>3</sub><sup>2+</sup>and its derivatives have been extensively studied during the last ten years due to their chemical stability,redox properties and excited state reactivity. In particular,the Ru（Ⅱ） polypyridine complexes play key roles in the development of photochemistry,photophysics,chemi-and electrochemi-luminescence and dectron energy transfer.Discovered in 1951,ferrocene and its derivatives are important for developing the knowledge of dectronic structure and photochemistry. Ligand-containing Schiff-base ferrocene derivatives have great significance for the photo molecular device because of
基金the National Natural Science Foundation of China(No.20572057).
文摘With dimethomorph and flumorph as the leading compounds, four novel acrylamide compounds with two types of structure were designed and synthesized by means of the method of ＂me too chemistry＂. The target compounds were characterized by 1H NMR, IR, MS, and elemental analysis. The influences of solvent and raw material on the yield were investigated and optimum processing conditions were determined. The results of preliminary biological tests show that all those compounds exhibit certain antifungal activities.
文摘This paper is a generalization of the results of the previous papers. Using these results a class of evolutions of risk assets based on the geometric Brownian motion is constructed. Among these evolutions of risk assets, the important class of the random processes is the random processes with parameters built on the basis of the discrete geometric Brownian motion. For this class of random processes the interval of non-arbitrage prices are found for the wide class of contingent liabilities. In particular, for the payoff functions of standard options call and put of the European type the fair prices of super-hedge are obtained. Analogous results are obtained for the put and call of arithmetical options of Asian type. For the parameters entering in the definition of random process the description of all statistical estimates is presented. Statistical estimate for which the fair price of super-hedge for the payoff functions of standard call and put options of European type is minimal is indicated. From the formulas found it follows that the fair price of super-hedge can be less than the price of the underlying asset. In terms of estimates the simple formula for the fair price of super-hedge is found. Every estimates can be realized in the reality. This depends on the distribution function of the observed dates in the financial market.
基金Supported by the Natural Science Foundation of China (No. 79700022 ) and the AeronauticalFoundation of China(No. 95J55002 )
文摘By Analyzing the behavior and character of derivative security, the authors established a pricing model of multiattribute derivative security whose underlying asset pricing process is a mixed process, and obtained a new model for option pricing of multiattribute derivatives based on mixed process, and improved some original results.
