Novel 2,2-bis-C-functionalized chain glucosid-3-uloses have been synthesized in the form of ketal. The synthesis is rather convenient through one pot multistep reactions and no expensive reagents are involved. The pro...Novel 2,2-bis-C-functionalized chain glucosid-3-uloses have been synthesized in the form of ketal. The synthesis is rather convenient through one pot multistep reactions and no expensive reagents are involved. The products are formed via autoxidation-Michael addition mechanism and their structures were characterized by X-ray crystallographic analysis. Their crystal stuctures are stablilized by intermolecular hydrogen bonds and double-strand supramolecular stacking is observed.展开更多
This paper investigates a simple approach proposed towards performance-based earthquake engineering (PBEE) which has potential applications to the performance-based design (PBD) and performance-based assessment (PBA) ...This paper investigates a simple approach proposed towards performance-based earthquake engineering (PBEE) which has potential applications to the performance-based design (PBD) and performance-based assessment (PBA) fields. The simple method of PBEE encompasses three areas of seismic risk which include seismic hazard, structural analysis, and loss models. The aim of the PBEE process, entitled as FEMA P-58, is to present essential data needed to make a rational decision regarding predicted performance, where various sources of uncertainties are involved. In developing countries, the lack of suitable real ground motions corresponding to site characteristics and seismicity particularly for larger intensities and the scarcity of demands, which makes it hard to identify the seismic capacity of a structure, is the main our motivation of using the FEMA method. In this paper, the method of FEMA P-58 is investigated, in terms of available tools and required data, in such a way that it will be applicable for developing countries which are located in high seismic hazard zones. To achieve this goal, three steel moment-resisting buildings with low and high ductility, and three steel braced-frame buildings are selected as case studies. The mean annual loss is estimated by the available software, Performance Assessment Calculation Tool (PACT). The achieved results, i.e. the loss curves, will provide a simple means by which the engineers can quantify and communicate seismic performance to other stakeholders. In the case study buildings, the braced one has less annual losses in comparison with other investigated cases, and the structure with high ductility can be considered as the next ones. Execution cost of each building should be considered by contractors. Also, seismic fragility curves of structures for various limit states, as well, the corresponding loss models are identified as the most essential data towards application of the investigated PBEE process.展开更多
The maximum entropy distribution, which consists of various recognized theoretical distributions, is a better curve to estimate the design thickness of sea ice. Method of moment and empirical curve fitting method are ...The maximum entropy distribution, which consists of various recognized theoretical distributions, is a better curve to estimate the design thickness of sea ice. Method of moment and empirical curve fitting method are common-used parameter estimation methods for maximum entropy distribution. In this study, we propose to use the particle swarm optimization method as a new parameter estimation method for the maximum entropy distribution, which has the advantage to avoid deviation introduced by simplifications made in other methods. We conducted a case study to fit the hindcasted thickness of the sea ice in the Liaodong Bay of Bohai Sea using these three parameter-estimation methods for the maximum entropy distribution. All methods implemented in this study pass the K-S tests at 0.05 significant level. In terms of the average sum of deviation squares, the empirical curve fitting method provides the best fit for the original data, while the method of moment provides the worst. Among all three methods, the particle swarm optimization method predicts the largest thickness of the sea ice for a same return period. As a result, we recommend using the particle swarm optimization method for the maximum entropy distribution for offshore structures mainly influenced by the sea ice in winter, but using the empirical curve fitting method to reduce the cost in the design of temporary and economic buildings.展开更多
基金This work was supported by the National Natural Science Foundation of China （No. 20972142） and the State Key Laboratory of Bio-organic and Natural Prod- ucts Chemistry, CAS （08417）.
文摘Novel 2,2-bis-C-functionalized chain glucosid-3-uloses have been synthesized in the form of ketal. The synthesis is rather convenient through one pot multistep reactions and no expensive reagents are involved. The products are formed via autoxidation-Michael addition mechanism and their structures were characterized by X-ray crystallographic analysis. Their crystal stuctures are stablilized by intermolecular hydrogen bonds and double-strand supramolecular stacking is observed.
文摘This paper investigates a simple approach proposed towards performance-based earthquake engineering (PBEE) which has potential applications to the performance-based design (PBD) and performance-based assessment (PBA) fields. The simple method of PBEE encompasses three areas of seismic risk which include seismic hazard, structural analysis, and loss models. The aim of the PBEE process, entitled as FEMA P-58, is to present essential data needed to make a rational decision regarding predicted performance, where various sources of uncertainties are involved. In developing countries, the lack of suitable real ground motions corresponding to site characteristics and seismicity particularly for larger intensities and the scarcity of demands, which makes it hard to identify the seismic capacity of a structure, is the main our motivation of using the FEMA method. In this paper, the method of FEMA P-58 is investigated, in terms of available tools and required data, in such a way that it will be applicable for developing countries which are located in high seismic hazard zones. To achieve this goal, three steel moment-resisting buildings with low and high ductility, and three steel braced-frame buildings are selected as case studies. The mean annual loss is estimated by the available software, Performance Assessment Calculation Tool (PACT). The achieved results, i.e. the loss curves, will provide a simple means by which the engineers can quantify and communicate seismic performance to other stakeholders. In the case study buildings, the braced one has less annual losses in comparison with other investigated cases, and the structure with high ductility can be considered as the next ones. Execution cost of each building should be considered by contractors. Also, seismic fragility curves of structures for various limit states, as well, the corresponding loss models are identified as the most essential data towards application of the investigated PBEE process.
基金supported by the National Natural Science Foundation of China (Nos. 51279186, 51479183, 51509227)the Shandong Province Natural Science Foundation, China (No. ZR2014EEQ030)the Fundamental Research Funds for the Central Universities (No. 201413003)
文摘The maximum entropy distribution, which consists of various recognized theoretical distributions, is a better curve to estimate the design thickness of sea ice. Method of moment and empirical curve fitting method are common-used parameter estimation methods for maximum entropy distribution. In this study, we propose to use the particle swarm optimization method as a new parameter estimation method for the maximum entropy distribution, which has the advantage to avoid deviation introduced by simplifications made in other methods. We conducted a case study to fit the hindcasted thickness of the sea ice in the Liaodong Bay of Bohai Sea using these three parameter-estimation methods for the maximum entropy distribution. All methods implemented in this study pass the K-S tests at 0.05 significant level. In terms of the average sum of deviation squares, the empirical curve fitting method provides the best fit for the original data, while the method of moment provides the worst. Among all three methods, the particle swarm optimization method predicts the largest thickness of the sea ice for a same return period. As a result, we recommend using the particle swarm optimization method for the maximum entropy distribution for offshore structures mainly influenced by the sea ice in winter, but using the empirical curve fitting method to reduce the cost in the design of temporary and economic buildings.
