根据低温推进剂长时间在轨贮存的要求,设计并搭建了绝热系统地面验证测试装置,对绝热系统的热力学性能进行测试。针对55L贮箱,采用了泡沫绝热(spray on foam insulation,SOFI)和多层绝热(multilayer insulation,MLI)结合的复合绝热系统...根据低温推进剂长时间在轨贮存的要求,设计并搭建了绝热系统地面验证测试装置,对绝热系统的热力学性能进行测试。针对55L贮箱,采用了泡沫绝热(spray on foam insulation,SOFI)和多层绝热(multilayer insulation,MLI)结合的复合绝热系统,分别在高真空(5×10^-3Pa以上)和大气压条件下进行了验证实验(液氮作为替代工质)。贮箱外绝热系统为15m m厚泡沫绝热层和45组多层绝热时,高真空条件下液氮日蒸发率为0.77%,多层绝热层表观热导率为1.29×10^-4W/(m·K),据此折算为液氧时日蒸发率为0.55%。将高真空和大气压条件下的实验结果比较发现,泡沫绝热层所占热阻分别为总热阻的0.19%和45.14%。展开更多
Cryogenic insulation material rigid polyurethane(PU)foams were developed using bio-based and recycled feedstock.Polyols obtained from tall oil fatty acids produced as a side stream of wood biomass pulping and recycled...Cryogenic insulation material rigid polyurethane(PU)foams were developed using bio-based and recycled feedstock.Polyols obtained from tall oil fatty acids produced as a side stream of wood biomass pulping and recycled polyethylene terephthalate were used to develop rigid PU foam formulations.The 4th generation physical blowing agents with low global warming potential and low ozone depletion potential were used to develop rigid PU foam cryogenic insulation with excellent mechanical and thermal properties.Obtained rigid PU foams had a thermal conductivity coefficient as low as 0.0171 W/m·K and an apparent density of 37-40 kg/m^(3).The developed rigid PU foams had anisotropic compression strength properties,which were higher parallel to the foaming direction.Moreover,the compression strength was also influenced by the type of applied bio-based polyol.The bio-based polyols with higher OH group functionality delivered higher crosslinking density of polymer matrix;thus,the mechanical properties were also higher.The mechanical strength of the foams increased when materials were tested at liquid nitrogen temperature due to the stiffening of the polymer matrix.The thermal properties of the developed materials were determined using differential scanning calorimetry,dynamic mechanical analysis,and thermogravimetric analysis methods.Lastly,the developed rigid PU foams had good adhesion to the aluminium substrate before and after applying cyroshock and an excellent safety coefficient of 4-5.Rigid PU foams developed using Solstice LBA delivered adhesion strength of~0.5 MPa and may be considered for application as cryogenic insulation in the aerospace industry.展开更多
基金funded by projects“Smart Materials,Photonics,Technologies and Engineering Ecosystem(MOTE)”(Contract No.VPP-EM-FOTONIKA-2022/1-0001)“Bio-Based Cryogenic Insulation for Aerospace Application(BioSpace)”(Contract No.4000135271/21/NL/SC).
文摘Cryogenic insulation material rigid polyurethane(PU)foams were developed using bio-based and recycled feedstock.Polyols obtained from tall oil fatty acids produced as a side stream of wood biomass pulping and recycled polyethylene terephthalate were used to develop rigid PU foam formulations.The 4th generation physical blowing agents with low global warming potential and low ozone depletion potential were used to develop rigid PU foam cryogenic insulation with excellent mechanical and thermal properties.Obtained rigid PU foams had a thermal conductivity coefficient as low as 0.0171 W/m·K and an apparent density of 37-40 kg/m^(3).The developed rigid PU foams had anisotropic compression strength properties,which were higher parallel to the foaming direction.Moreover,the compression strength was also influenced by the type of applied bio-based polyol.The bio-based polyols with higher OH group functionality delivered higher crosslinking density of polymer matrix;thus,the mechanical properties were also higher.The mechanical strength of the foams increased when materials were tested at liquid nitrogen temperature due to the stiffening of the polymer matrix.The thermal properties of the developed materials were determined using differential scanning calorimetry,dynamic mechanical analysis,and thermogravimetric analysis methods.Lastly,the developed rigid PU foams had good adhesion to the aluminium substrate before and after applying cyroshock and an excellent safety coefficient of 4-5.Rigid PU foams developed using Solstice LBA delivered adhesion strength of~0.5 MPa and may be considered for application as cryogenic insulation in the aerospace industry.
