High conductivity two-dimensional(2D)materials have been proved to be potential electrode materials for flexible supercapacitors because of its outstanding chemical and physical properties.However,electrodes based on ...High conductivity two-dimensional(2D)materials have been proved to be potential electrode materials for flexible supercapacitors because of its outstanding chemical and physical properties.However,electrodes based on 2D materials always suffer from limited electrolyte-accessible surface due to the restacking of the 2D sheets,hindering the full utilization of their surface area.In this regard,an electrolyte-mediated method is used to integrate dense structure reduced graphene oxide/MXene(RGM)-electrolyte composite films.In such composite films,reduced graphene oxide(RGO)and MXene sheets are controllable assembly in compact layered structure with electrolyte filled between the layers.The electrolyte layer between RGO and MXene sheets forms continuous ion transport channels in the composite films.Therefore,the RGM-electrolyte composite films can be used directly as self-supporting electrodes for supercapacitors without additional conductive agents and binders.As a result,the composite films demonstrate enhanced volumetric specific capacity,improved volumetric energy density and higher power density compared with both pure RGO electrode and porous composite electrode prepared by traditional methods.Specifically,when the mass ratio of MXene is 30%,the electrode delivers a volumetric specific capacity of 454.9 F·cm^(−3) with a high energy density of 39.4 Wh·L^(−1).More importantly,supercapacitors based on the composite films exhibit good flexibility electrochemical performance.The investigation provides a new approach to synthesize dense structure films based on 2D materials for application in high volumetric capacitance flexible supercapacitors.展开更多
The absence of control over carriers transport during electrochemical cycling,accompanied by the deterioration of the solid electrolyte interphase(SEI)and the growth of lithium dendrites,has hindered the development o...The absence of control over carriers transport during electrochemical cycling,accompanied by the deterioration of the solid electrolyte interphase(SEI)and the growth of lithium dendrites,has hindered the development of lithium metal batteries.Herein,a separator complexion consisting of polyacrylonitrile(PAN)nanofiber and MIL-101(Cr)particles prepared by electrospinning is proposed to bind the anions from the electrolyte utilizing abundant effective open metal sites in the MIL-101(Cr)particles to modulate the transport of non-effective carriers.The binding effect of the PANM separator promotes uniform lithium metal deposition and enhances the stability of the SEI layer and long cycling stability of ultra-high nickel layered oxide cathodes.Taking PANM as the Li||NCM96 separator enables high-voltage cycling stability,maintaining 72%capacity retention after 800 cycles at a charging and discharging rate of 0.2 C at a cut-off voltage of 4.5 V and 0°C.Meanwhile,the excellent high-rate performance delivers a specific capacity of 156.3 mA h g^(-1) at 10 C.In addition,outstanding cycling performance is realized from−20 to 60°C.The separator engineering facilitates the electrochemical performance of lithium metal batteries and enlightens a facile and promising strategy to develop fast charge/discharge over a wide range of temperatures.展开更多
Traditionally, “ eddy feeds zonal flow” in the atmosphere is considered as a result of decaying unstable waves. We show that disturbances made of non-modal solutions -the continuous-spec-trum disturbances-can also e...Traditionally, “ eddy feeds zonal flow” in the atmosphere is considered as a result of decaying unstable waves. We show that disturbances made of non-modal solutions -the continuous-spec-trum disturbances-can also effectively transport zonal angular momentum and interact with the zonal basic flow. These disturbances, though stable, eventually decay, losing their energy to strengthen the westerly jets in the atmosphere. Calculations with observational data illustrate that the atmospheric zonal flow is maintained primarily by continuous-spectrum disturbances rather than by unstable waves. Angular momen-tum transport by continuous-spectrum disturbances is one order of magnitude larger than that by all kinds of normal modes (referred as discrete-spectrum disturbances) including unstable waves. Key words Maintenance of zonal flow - Continuous-spectrum - Angular momentum - Transport This research was partly supported by the Chinese Program on Basic Research and by the Institute of Atmospheric Physics, Chinese Academy of Sciences. It was also supported by NASA Grant NAGW 3517, and DOE Grant DEFG0285-ER60314 to the State University of New York at Stony Brook.展开更多
This paper presents a comprehensive review of the wave-flmction approach for derivation of the number- resolved Master equations, used for description of transport and measurement in mesoseopie systems. The review con...This paper presents a comprehensive review of the wave-flmction approach for derivation of the number- resolved Master equations, used for description of transport and measurement in mesoseopie systems. The review contains important amendments, clarifying subtle points in derivation of the Master equa- tions and their validity. This completes the earlier works on the subject. It is demonstrated that the derivation does not assume weak coupling with the environment and reservoirs, but needs only high bias condition. This condition is very essential for validity of the Markovian Master equations, widely used for a phenomenological description of different physical processes.展开更多
基金This work was supported by the Natural Science Foundation of Shandong Province(Nos.ZR2018BB038 and ZR2019BEM041)the National Natural Science Foundation of China(Nos.21805171,51802178 and 51804189).
文摘High conductivity two-dimensional(2D)materials have been proved to be potential electrode materials for flexible supercapacitors because of its outstanding chemical and physical properties.However,electrodes based on 2D materials always suffer from limited electrolyte-accessible surface due to the restacking of the 2D sheets,hindering the full utilization of their surface area.In this regard,an electrolyte-mediated method is used to integrate dense structure reduced graphene oxide/MXene(RGM)-electrolyte composite films.In such composite films,reduced graphene oxide(RGO)and MXene sheets are controllable assembly in compact layered structure with electrolyte filled between the layers.The electrolyte layer between RGO and MXene sheets forms continuous ion transport channels in the composite films.Therefore,the RGM-electrolyte composite films can be used directly as self-supporting electrodes for supercapacitors without additional conductive agents and binders.As a result,the composite films demonstrate enhanced volumetric specific capacity,improved volumetric energy density and higher power density compared with both pure RGO electrode and porous composite electrode prepared by traditional methods.Specifically,when the mass ratio of MXene is 30%,the electrode delivers a volumetric specific capacity of 454.9 F·cm^(−3) with a high energy density of 39.4 Wh·L^(−1).More importantly,supercapacitors based on the composite films exhibit good flexibility electrochemical performance.The investigation provides a new approach to synthesize dense structure films based on 2D materials for application in high volumetric capacitance flexible supercapacitors.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB2400300)the IPE Talent Start-up Program of Institute of Process Engineering of Chinese Academy of Sciences(Grant No.E0293507)。
文摘The absence of control over carriers transport during electrochemical cycling,accompanied by the deterioration of the solid electrolyte interphase(SEI)and the growth of lithium dendrites,has hindered the development of lithium metal batteries.Herein,a separator complexion consisting of polyacrylonitrile(PAN)nanofiber and MIL-101(Cr)particles prepared by electrospinning is proposed to bind the anions from the electrolyte utilizing abundant effective open metal sites in the MIL-101(Cr)particles to modulate the transport of non-effective carriers.The binding effect of the PANM separator promotes uniform lithium metal deposition and enhances the stability of the SEI layer and long cycling stability of ultra-high nickel layered oxide cathodes.Taking PANM as the Li||NCM96 separator enables high-voltage cycling stability,maintaining 72%capacity retention after 800 cycles at a charging and discharging rate of 0.2 C at a cut-off voltage of 4.5 V and 0°C.Meanwhile,the excellent high-rate performance delivers a specific capacity of 156.3 mA h g^(-1) at 10 C.In addition,outstanding cycling performance is realized from−20 to 60°C.The separator engineering facilitates the electrochemical performance of lithium metal batteries and enlightens a facile and promising strategy to develop fast charge/discharge over a wide range of temperatures.
文摘Traditionally, “ eddy feeds zonal flow” in the atmosphere is considered as a result of decaying unstable waves. We show that disturbances made of non-modal solutions -the continuous-spec-trum disturbances-can also effectively transport zonal angular momentum and interact with the zonal basic flow. These disturbances, though stable, eventually decay, losing their energy to strengthen the westerly jets in the atmosphere. Calculations with observational data illustrate that the atmospheric zonal flow is maintained primarily by continuous-spectrum disturbances rather than by unstable waves. Angular momen-tum transport by continuous-spectrum disturbances is one order of magnitude larger than that by all kinds of normal modes (referred as discrete-spectrum disturbances) including unstable waves. Key words Maintenance of zonal flow - Continuous-spectrum - Angular momentum - Transport This research was partly supported by the Chinese Program on Basic Research and by the Institute of Atmospheric Physics, Chinese Academy of Sciences. It was also supported by NASA Grant NAGW 3517, and DOE Grant DEFG0285-ER60314 to the State University of New York at Stony Brook.
文摘This paper presents a comprehensive review of the wave-flmction approach for derivation of the number- resolved Master equations, used for description of transport and measurement in mesoseopie systems. The review contains important amendments, clarifying subtle points in derivation of the Master equa- tions and their validity. This completes the earlier works on the subject. It is demonstrated that the derivation does not assume weak coupling with the environment and reservoirs, but needs only high bias condition. This condition is very essential for validity of the Markovian Master equations, widely used for a phenomenological description of different physical processes.
文摘目的通过腹膜平衡试验(PET)探讨我国慢性腹膜透析(PD)儿童腹膜转运特性特点。方法对6例持续性非卧床腹膜透析(cAPD)患儿(2～14岁)行10次儿童标准 PET,参照 Twardowski和儿科腹膜透析联盟(PPDSC)标准评价腹膜溶质转运类型。结果本组患儿首次 PET 于 PD 开始后平均(38.7±15.6)d 进行。4 h 肌酐清除率(4 h-D/P)和4 h 葡萄糖吸收率(4 h-D/D_0)分别为(0.85±0.24)、(0.34±0.19)。依 Twardowski 和 PPDSC 腹膜转运类型评价标准,本组腹膜溶质转运类型分别为高转运型6例(6/10)、高平均转运型1例(1/10)、低平均转运型3例(3/10),无一例低转运型;两种标准分型的总符合率100%。本组腹膜葡萄糖转运类型分别为高转运型3例(3/10)、高平均转运型4例(4/10)、低平均转运型1例(1/10),低转运型2例(2/10);两种标准分型的总符合率90%。连续 PET 显示转运类型变化不一,腹膜炎后4 h-D/P 升高。结论本组 CAPD 儿童腹膜溶质和葡萄糖转运类型均以高转运和高平均转运为主(7/10),呈偏态分布,提示儿童腹透溶质清除充分,但水超滤能力不足;标准儿童 PET 及其评价标准完全符合 Twardowski 标准 PET 要求。腹膜炎后溶质转运能力提高。
