Sensitive and reliable X-ray detectors are essential for medical radiography,industrial inspection and security screening.Lowering the radiation dose allows reduced health risks and increased frequency and fidelity of...Sensitive and reliable X-ray detectors are essential for medical radiography,industrial inspection and security screening.Lowering the radiation dose allows reduced health risks and increased frequency and fidelity of diagnostic technologies for earlier detection of disease and its recurrence.Three-dimensional(3 D)organic-inorganic hybrid lead halide perovskites are promising for direct X-ray detection-they show improved sensitivity compared to conventional X-ray detectors.However,their high and unstable dark current,caused by ion migration and high dark carrier concentration in the 3 D hybrid perovskites,limits their performance and long-term operation stability.Here we report ultrasensitive,stable X-ray detectors made using zero-dimensional(0 D)methylammonium bismuth iodide perovskite(MA3Bi2I9)single crystals.The 0 D crystal structure leads to a high activation energy(Ea)for ion migration(0.46 e V)and is also accompanied by a low dark carrier concentration(~10^6 cm^-3).The X-ray detectors exhibit sensitivity of 10,620μC Gy-1 air cm-2,a limit of detection(Lo D)of 0.62 nG yairs-1,and stable operation even under high applied biases;no deterioration in detection performance was observed following sensing of an integrated X-ray irradiation dose of^23,800 m Gyair,equivalent to>200,000 times the dose required for a single commercial X-ray chest radiograph.Regulating the ion migration channels and decreasing the dark carrier concentration in perovskites provide routes for stable and ultrasensitive X-ray detectors.展开更多
鉴于科技的进步和实验经验,ISO/TC 209出台ISO14644-1:2015《按粒子浓度划出空气洁净度等级》Classification of air cleanliness by particle concentration比ISO14644-1:1999《空气洁净度等级》Classification of air cleanliness技...鉴于科技的进步和实验经验,ISO/TC 209出台ISO14644-1:2015《按粒子浓度划出空气洁净度等级》Classification of air cleanliness by particle concentration比ISO14644-1:1999《空气洁净度等级》Classification of air cleanliness技术概念更清晰,使用更方便;实事求是,更赋灵活性:分级表中,所有浓度值都是累积,包括所有大于等于关注粒径(Considered particle size)的粒子的最大允许浓度值(Maximun allowable concentration siae),浓度限值。区域粒子浓度太高,浓度限值不适用;或者由于低浓度时采样和统计方法的局限性区域分级不适用。按统计学技术概念,决定检测洁净度最少采样点数N_(L);N_(L)值与洁净度无直接关联。作为标准应用的补充,超净环境检测需关注超高过滤器滤材最易穿透粒径MPPS,Most penetrating particle size。展开更多
基金supported by the National Natural Science Foundation of China(Grant nos.21773218,61974063)the Sichuan Province(Grant no.2018JY0206)the China Academy of Engineering Physics(Grant no.YZJJLX2018007)。
文摘Sensitive and reliable X-ray detectors are essential for medical radiography,industrial inspection and security screening.Lowering the radiation dose allows reduced health risks and increased frequency and fidelity of diagnostic technologies for earlier detection of disease and its recurrence.Three-dimensional(3 D)organic-inorganic hybrid lead halide perovskites are promising for direct X-ray detection-they show improved sensitivity compared to conventional X-ray detectors.However,their high and unstable dark current,caused by ion migration and high dark carrier concentration in the 3 D hybrid perovskites,limits their performance and long-term operation stability.Here we report ultrasensitive,stable X-ray detectors made using zero-dimensional(0 D)methylammonium bismuth iodide perovskite(MA3Bi2I9)single crystals.The 0 D crystal structure leads to a high activation energy(Ea)for ion migration(0.46 e V)and is also accompanied by a low dark carrier concentration(~10^6 cm^-3).The X-ray detectors exhibit sensitivity of 10,620μC Gy-1 air cm-2,a limit of detection(Lo D)of 0.62 nG yairs-1,and stable operation even under high applied biases;no deterioration in detection performance was observed following sensing of an integrated X-ray irradiation dose of^23,800 m Gyair,equivalent to>200,000 times the dose required for a single commercial X-ray chest radiograph.Regulating the ion migration channels and decreasing the dark carrier concentration in perovskites provide routes for stable and ultrasensitive X-ray detectors.
文摘鉴于科技的进步和实验经验,ISO/TC 209出台ISO14644-1:2015《按粒子浓度划出空气洁净度等级》Classification of air cleanliness by particle concentration比ISO14644-1:1999《空气洁净度等级》Classification of air cleanliness技术概念更清晰,使用更方便;实事求是,更赋灵活性:分级表中,所有浓度值都是累积,包括所有大于等于关注粒径(Considered particle size)的粒子的最大允许浓度值(Maximun allowable concentration siae),浓度限值。区域粒子浓度太高,浓度限值不适用;或者由于低浓度时采样和统计方法的局限性区域分级不适用。按统计学技术概念,决定检测洁净度最少采样点数N_(L);N_(L)值与洁净度无直接关联。作为标准应用的补充,超净环境检测需关注超高过滤器滤材最易穿透粒径MPPS,Most penetrating particle size。
