Wanbaogou Group-complex is a suit of melange aggregation of the EasternKunlun orogenic belt, which is divided into two parts, i.e. the exotic blocks and the matrix strata.Based on stromatolite fossils yielded in the e...Wanbaogou Group-complex is a suit of melange aggregation of the EasternKunlun orogenic belt, which is divided into two parts, i.e. the exotic blocks and the matrix strata.Based on stromatolite fossils yielded in the exotic blocks, the age of this group-complex was oncedefined to the Precambrian. Recently, two Paleogene palynological assemblages have been found insamples from the matrix strata of the Upper Part in this group-complex by the authors: in ascendingorder, the Al-nipollenites-Quercoidites assemblage of Late Eocene and theCaryapollenites-Pinuspollenites assemblage of Early Oligocene. Those results show that the matrixstrata of this melange were mainly formed in Paleogene, and the event causing mixture should be aHimalayan Movement Phase. This paper is designed to provide some detailed evidence for determiningthe age of the matrix strata in this group-complex based upon study at the Kunlunqiao Section, whichwould be of important geological significance for further understanding this group-complex as asuit of melange aggregation and establishing or improving the stratigraphic framework of the studiedregion. The new finding will certainly benefit from now on the investigation on geotectonic andsedimentary evolution of Eastern Kunlun.展开更多
An inclusion complex (1) has been prepared by β-cyclodextrin with α-aminopyridine. The result of X-ray crystallographic analyses showed that the α-aminopyridine molecules in the β-cyclodextrin cavities possess two...An inclusion complex (1) has been prepared by β-cyclodextrin with α-aminopyridine. The result of X-ray crystallographic analyses showed that the α-aminopyridine molecules in the β-cyclodextrin cavities possess two opposite orientations, i.e. the amine group of α-aminopyridine pointing to the primary side (1a, occupancy: 41.2%) or the secondary side (1b, occupancy: 58.8%) of β-cyclodextrin, forming two scalelike supramolecular aggregations. The studies of 2D NMR and circular dichroism spectra indicated that the α-aminopyridine molecule is deeply embedded in the β-cyclodextrin cavity to form host-guest inclusion complex, showing a circular dichroism spectrum induced by the chiral cavity of cyclodextrin. The results obtained are helpful for understanding the molecular recognition and aggregation mechanism between the host and guest.展开更多
We propose a model of weighted networks in which the structural evolution is coupled with weight dynamics. Based on a simple merging and regeneration process, the model gives powel-law distributions of degree, strengt...We propose a model of weighted networks in which the structural evolution is coupled with weight dynamics. Based on a simple merging and regeneration process, the model gives powel-law distributions of degree, strength and weight, as observed in many real networks. It should be emphasized that, in our model, the nontrivial degree-strength correlation can be reproduced and in agreement with empirical data. Moreover, the size-growing evolution model is also presented to meet the properties of real-world systems.展开更多
Thermally stable, solid-state luminescent organic materials are highly desired for the development of practical applications.Herein we synthesized new gold(I) complexes with N-heterocyclic carbene ligands, which have ...Thermally stable, solid-state luminescent organic materials are highly desired for the development of practical applications.Herein we synthesized new gold(I) complexes with N-heterocyclic carbene ligands, which have the ability to form strong metalorganic bond. Consequently, their thermochemical stability is enhanced at temperatures around 300 °C. Precise design of the molecular structure of the ligands, with a focus on ensuring low steric hindrance around Au atoms in order to limit disturbances to Au/Au interactions, provided a complex with a densely packed crystal with a shorter intermolecular Au–Au distance(3.17 ?)than the typical distance. In the solid state, this complex exhibited strong aurophilic interactions, which generated intense phosphorescence even in air at room temperature(quantum yield=16%) in spite of absence of any phosphorescence in solution.This behavior is characteristic for solid-state luminescence referred to as aggregation-controlled emission. Furthermore, the gold(I) complex displays capacity for mechano-and vapo-chromism—that is, the ability to change color reversibly in response to the application of external stimuli. We believe that the proposed design framework, which involves controlling thermal stability and luminescence property separately, provides a new opportunity for the development of practical applications using solid-state luminescent organic molecules.展开更多
The ternary interaction of 1, 5 bis(2 hydroxy 5 chlorphenyl) 3 cyanoformazan (HCPCF) with cetyltrimethylammonium bromide (CTAB) and rare earths (RE: Yb, Dy, Er and Eu) was investigated at pH 9.84 by the microsur...The ternary interaction of 1, 5 bis(2 hydroxy 5 chlorphenyl) 3 cyanoformazan (HCPCF) with cetyltrimethylammonium bromide (CTAB) and rare earths (RE: Yb, Dy, Er and Eu) was investigated at pH 9.84 by the microsurface adsorption spectral correction technique (MSASC). The aggregation of HCPCF on CTAB obeys the Langmuir isothermal adsorption and the interaction of RE with the HCPCF CTAB aggregate was first found to accord with the monolayer binding. The effects of temperature and ionic strength of solution on the aggregations were made. The binary aggregate and the ternary complex were characterized.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.40272019)the China Geological Survey(Grant No.200313000054).
文摘Wanbaogou Group-complex is a suit of melange aggregation of the EasternKunlun orogenic belt, which is divided into two parts, i.e. the exotic blocks and the matrix strata.Based on stromatolite fossils yielded in the exotic blocks, the age of this group-complex was oncedefined to the Precambrian. Recently, two Paleogene palynological assemblages have been found insamples from the matrix strata of the Upper Part in this group-complex by the authors: in ascendingorder, the Al-nipollenites-Quercoidites assemblage of Late Eocene and theCaryapollenites-Pinuspollenites assemblage of Early Oligocene. Those results show that the matrixstrata of this melange were mainly formed in Paleogene, and the event causing mixture should be aHimalayan Movement Phase. This paper is designed to provide some detailed evidence for determiningthe age of the matrix strata in this group-complex based upon study at the Kunlunqiao Section, whichwould be of important geological significance for further understanding this group-complex as asuit of melange aggregation and establishing or improving the stratigraphic framework of the studiedregion. The new finding will certainly benefit from now on the investigation on geotectonic andsedimentary evolution of Eastern Kunlun.
基金supported by the National Natural Science Foundation of China (Grant Nos. 20272028 and 90306009).
文摘An inclusion complex (1) has been prepared by β-cyclodextrin with α-aminopyridine. The result of X-ray crystallographic analyses showed that the α-aminopyridine molecules in the β-cyclodextrin cavities possess two opposite orientations, i.e. the amine group of α-aminopyridine pointing to the primary side (1a, occupancy: 41.2%) or the secondary side (1b, occupancy: 58.8%) of β-cyclodextrin, forming two scalelike supramolecular aggregations. The studies of 2D NMR and circular dichroism spectra indicated that the α-aminopyridine molecule is deeply embedded in the β-cyclodextrin cavity to form host-guest inclusion complex, showing a circular dichroism spectrum induced by the chiral cavity of cyclodextrin. The results obtained are helpful for understanding the molecular recognition and aggregation mechanism between the host and guest.
基金Supported by the National 0utstanding Young Investigator Foundation of China under Grant No 70225005, the National Natural Science Foundation of China under Grant No 70471088.
文摘We propose a model of weighted networks in which the structural evolution is coupled with weight dynamics. Based on a simple merging and regeneration process, the model gives powel-law distributions of degree, strength and weight, as observed in many real networks. It should be emphasized that, in our model, the nontrivial degree-strength correlation can be reproduced and in agreement with empirical data. Moreover, the size-growing evolution model is also presented to meet the properties of real-world systems.
基金supported by the JSPS KAKENSHI (18K05265)JST Matching Planner Program (VP29117941122)+1 种基金JICA Collaboration Kick-starter Program (RU and IITH)the Cooperative Research Program of the Network Joint Research Center for Materials and Devices (Tokyo Institute of Technology)
文摘Thermally stable, solid-state luminescent organic materials are highly desired for the development of practical applications.Herein we synthesized new gold(I) complexes with N-heterocyclic carbene ligands, which have the ability to form strong metalorganic bond. Consequently, their thermochemical stability is enhanced at temperatures around 300 °C. Precise design of the molecular structure of the ligands, with a focus on ensuring low steric hindrance around Au atoms in order to limit disturbances to Au/Au interactions, provided a complex with a densely packed crystal with a shorter intermolecular Au–Au distance(3.17 ?)than the typical distance. In the solid state, this complex exhibited strong aurophilic interactions, which generated intense phosphorescence even in air at room temperature(quantum yield=16%) in spite of absence of any phosphorescence in solution.This behavior is characteristic for solid-state luminescence referred to as aggregation-controlled emission. Furthermore, the gold(I) complex displays capacity for mechano-and vapo-chromism—that is, the ability to change color reversibly in response to the application of external stimuli. We believe that the proposed design framework, which involves controlling thermal stability and luminescence property separately, provides a new opportunity for the development of practical applications using solid-state luminescent organic molecules.
基金ProjectsupportedbytheNaturalScienceFoundationofAnhuiProvince (No .0 1 0 45 30 1 )andtheAnhuiProvincialScienceandTechnologyforExcellentYouths
文摘The ternary interaction of 1, 5 bis(2 hydroxy 5 chlorphenyl) 3 cyanoformazan (HCPCF) with cetyltrimethylammonium bromide (CTAB) and rare earths (RE: Yb, Dy, Er and Eu) was investigated at pH 9.84 by the microsurface adsorption spectral correction technique (MSASC). The aggregation of HCPCF on CTAB obeys the Langmuir isothermal adsorption and the interaction of RE with the HCPCF CTAB aggregate was first found to accord with the monolayer binding. The effects of temperature and ionic strength of solution on the aggregations were made. The binary aggregate and the ternary complex were characterized.
