模拟7B04铝合金表面涂层破损,采用电化学试验研究7B04铝合金在不同环境条件下的自腐蚀与点蚀行为,基于电偶腐蚀数学模型,通过有限元法分析7B04铝合金与TA15钛合金接触后发生点蚀的条件。结果表明:7B04铝合金点蚀电位受Cl^-浓度和pH值的...模拟7B04铝合金表面涂层破损,采用电化学试验研究7B04铝合金在不同环境条件下的自腐蚀与点蚀行为,基于电偶腐蚀数学模型,通过有限元法分析7B04铝合金与TA15钛合金接触后发生点蚀的条件。结果表明:7B04铝合金点蚀电位受Cl^-浓度和pH值的影响,在NaCl质量分数>10%的中性溶液及NaCl质量分数为3.5%的酸性溶液中,自腐蚀状态下7B04铝合金即可发生点蚀;7B04铝合金与TA15钛合金接触后,电位升高,增加了发生点蚀的可能性,在NaCl质量分数为3.5%的中性溶液中,当阴阳极面积比≥40时,7B04铝合金发生点蚀的萌生并进一步扩展;7B04铝合金电位随阴阳极距离的增大而下降,但幅度有限,在10 m的距离内下降不超过2 m V。展开更多
The Cr-plated coating inside a gun barrel can effectively improve the barrel’s erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gunpowder,micro-e...The Cr-plated coating inside a gun barrel can effectively improve the barrel’s erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gunpowder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel’s inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface’s ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.展开更多
为探究爆炸荷载作用下聚脲涂层对沉箱码头的保护作用,采用LS-DANA非线性动力分析平台,模拟在1 kg TNT当量炸药水中非接触爆炸时,不同涂覆厚度聚脲涂层的沉箱码头毁伤破坏特征。结果表明:无聚脲防护的沉箱码头毁伤破坏程度明显大于涂覆...为探究爆炸荷载作用下聚脲涂层对沉箱码头的保护作用,采用LS-DANA非线性动力分析平台,模拟在1 kg TNT当量炸药水中非接触爆炸时,不同涂覆厚度聚脲涂层的沉箱码头毁伤破坏特征。结果表明:无聚脲防护的沉箱码头毁伤破坏程度明显大于涂覆聚脲防护的沉箱码头,沉箱码头的毁伤主要集中在迎爆面外墙和迎爆侧上部管沟,随着聚脲涂层厚度的增加,沉箱码头各部分毁伤程度降低;随着涂覆聚脲厚度的增加,迎爆侧外墙位移逐渐降低,但降幅较小,区域空化效应会加大外墙上部位移;无聚脲防护的沉箱码头迎爆侧外墙位移和毁伤程度明显大于涂覆聚脲防护的沉箱码头,表明聚脲涂层对于沉箱码头具有较好的保护作用。展开更多
文摘模拟7B04铝合金表面涂层破损,采用电化学试验研究7B04铝合金在不同环境条件下的自腐蚀与点蚀行为,基于电偶腐蚀数学模型,通过有限元法分析7B04铝合金与TA15钛合金接触后发生点蚀的条件。结果表明:7B04铝合金点蚀电位受Cl^-浓度和pH值的影响,在NaCl质量分数>10%的中性溶液及NaCl质量分数为3.5%的酸性溶液中,自腐蚀状态下7B04铝合金即可发生点蚀;7B04铝合金与TA15钛合金接触后,电位升高,增加了发生点蚀的可能性,在NaCl质量分数为3.5%的中性溶液中,当阴阳极面积比≥40时,7B04铝合金发生点蚀的萌生并进一步扩展;7B04铝合金电位随阴阳极距离的增大而下降,但幅度有限,在10 m的距离内下降不超过2 m V。
文摘丝状腐蚀多发生于飞机蒙皮边缘及紧固件周围涂层破损处,是一类特殊的缝隙腐蚀。基于NernstPlanck方程,采用有限元法开展了丝状腐蚀头部缝隙的仿真研究。结果表明,缝隙中的p H值随时间先下降而后上升,最后稳定在5.4~6.0之间的酸性条件下;选择有O2存在且溶液p H值为6的极化曲线作为边界条件较为合适;缝隙内铝合金界面主要发生Al的阳极氧化反应;缝隙口溶液电势低于缝隙底部的溶液电势,缝隙口附近铝合金的腐蚀速率更快;固态腐蚀产物Al(OH)2Cl多集中于缝隙底部,Al(OH)2Cl浓度随反应时间的延长而升高;电位对丝状腐蚀的扩展影响很大,电位升高,缝隙内铝合金的腐蚀加剧,Al(OH)2Cl的生成速率加快;电位提高20 m V,缝隙底部的Al(OH)2Cl浓度升高5倍,极大地加速了丝状腐蚀的扩展。
文摘The Cr-plated coating inside a gun barrel can effectively improve the barrel’s erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gunpowder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel’s inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface’s ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.
文摘为探究爆炸荷载作用下聚脲涂层对沉箱码头的保护作用,采用LS-DANA非线性动力分析平台,模拟在1 kg TNT当量炸药水中非接触爆炸时,不同涂覆厚度聚脲涂层的沉箱码头毁伤破坏特征。结果表明:无聚脲防护的沉箱码头毁伤破坏程度明显大于涂覆聚脲防护的沉箱码头,沉箱码头的毁伤主要集中在迎爆面外墙和迎爆侧上部管沟,随着聚脲涂层厚度的增加,沉箱码头各部分毁伤程度降低;随着涂覆聚脲厚度的增加,迎爆侧外墙位移逐渐降低,但降幅较小,区域空化效应会加大外墙上部位移;无聚脲防护的沉箱码头迎爆侧外墙位移和毁伤程度明显大于涂覆聚脲防护的沉箱码头,表明聚脲涂层对于沉箱码头具有较好的保护作用。
