Su FEx点击反应自2014年被提出以后取得了快速的进展,分别从小分子制备与聚合物合成方面介绍硅醚与有机硫(VI)氟化合物之间的点击化学反应,对目前发展的硅醚与硫(Ⅵ)氟化合物Su FEx典型点击反应重点按照底物类型进行了梳理,探讨了未来...Su FEx点击反应自2014年被提出以后取得了快速的进展,分别从小分子制备与聚合物合成方面介绍硅醚与有机硫(VI)氟化合物之间的点击化学反应,对目前发展的硅醚与硫(Ⅵ)氟化合物Su FEx典型点击反应重点按照底物类型进行了梳理,探讨了未来的研究方向.展开更多
A convenient and efficient procedure for the synthesis ofN, N-bicyclic pyrazolidinone derivatives has been developed via the reaction of azomethine imines with terminal alkynes under the ball milling condition without...A convenient and efficient procedure for the synthesis ofN, N-bicyclic pyrazolidinone derivatives has been developed via the reaction of azomethine imines with terminal alkynes under the ball milling condition without sol- vent, which was promoted by calcium fluoride with a catalyst of copper（I） salt. The cyclization reactions exhibited moderate to high yields.展开更多
The postsynthetic modification （PSM） of metal-organic frameworks （MOFs） has emerged as a powerful tool to chemically tailor the interior of MOFs. In this review, we summarize the research progress of PSM of MOFs t...The postsynthetic modification （PSM） of metal-organic frameworks （MOFs） has emerged as a powerful tool to chemically tailor the interior of MOFs. In this review, we summarize the research progress of PSM of MOFs through click chemistry, including azide-alkyne click reaction and thiol-ene reaction.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.21261008, 21471069）, the Special Integration Fund of Industry and Research of Hainan Province, China（No.CXY20130010）, the Natural Science Foundation of Hainan Province, China（No.213014） and the International Science and Technology Cooperation Projects of Hainan Province, China（No. KJI-IZ2014-05）.
文摘A convenient and efficient procedure for the synthesis ofN, N-bicyclic pyrazolidinone derivatives has been developed via the reaction of azomethine imines with terminal alkynes under the ball milling condition without sol- vent, which was promoted by calcium fluoride with a catalyst of copper（I） salt. The cyclization reactions exhibited moderate to high yields.
基金We thank the funding supported by National Natural Science Foundation of China （No. 21572170）, the Research Fund for the Doctoral Program of Higher Education of China （No. 20130141110008）, and the Outstanding Youth Foundation of Hubei Province （No. 2015CFA045）.
文摘The postsynthetic modification （PSM） of metal-organic frameworks （MOFs） has emerged as a powerful tool to chemically tailor the interior of MOFs. In this review, we summarize the research progress of PSM of MOFs through click chemistry, including azide-alkyne click reaction and thiol-ene reaction.
