The present paper should be considered as a review of the application of Fourier Transform Infra-Red for surface clay characterization. The application of surface clay materials for water treatment, oil adsorption, ex...The present paper should be considered as a review of the application of Fourier Transform Infra-Red for surface clay characterization. The application of surface clay materials for water treatment, oil adsorption, excipients or as active in drugs has largely increased these recent years. The surface clay material presents hydroxyl groups, which can link very easily water molecules. These hydroxyl groups can react with organic groups and by their vibration in the infra-red region, FT-IR can be easily used as a technical method for surface clay characterization. In this paper, we focus on the determination of Lewis and Bronsted acid sites on the clay surface, a critical review of the sample preparation, the surface characterization of bulk clay and the modified surface clay samples using FT-IR spectroscopy.展开更多
Requirements for the respect of the environment encourage to reduce the impact of human activity on the nature. Civil engineering answers these requirements by the development of ecological construction materials. Thi...Requirements for the respect of the environment encourage to reduce the impact of human activity on the nature. Civil engineering answers these requirements by the development of ecological construction materials. This paper deals with the transformation of clay raw materials which enable the processing of environmentally friendly construction materials: in addition to their biodegradability, the alveolar fired clay materials allow energy saving in home heating thanks to their thermal isolation properties. But their manufacturing is a high energy consumption process, in particular during compaction, drying and firing which contribute to the emission of greenhouse gases. The goal of this paper is to study the rheology of clay pastes in order to develop low energy in manufacturing processes. For this purpose, theoretical and experimental approaches were carried out on six clay varieties. In the theoretical approach, a finite element (FE) simulation model has been developed for pressing a non-rigid material predicting deformations and stresses occurring within the clay structure. Experiments have then been carried out to validate the finite element modelling. In this experimental approach, the clay pastes were transformed with water content respecting the Atterberg limits which determine the plasticity of clays. The samples compaction has been carried out under variable loadings in order to determine the suitable low energy consumption loading.展开更多
This study aims at evaluating the potential suitability of Tetouan and Meknes (central Morocco) clay material as raw materials in various ceramic applications by investigating their textural, chemical, thermal and fir...This study aims at evaluating the potential suitability of Tetouan and Meknes (central Morocco) clay material as raw materials in various ceramic applications by investigating their textural, chemical, thermal and firing characteristics. Textural properties were identified by specific surface area, cation exchange capacity (CEC) and bulk density (ρs). Chemical and thermal properties were assessed using XRF and TG/DTA techniques, respectively. Firing characteristics at temperatures from 800℃ to 1100℃ were determined by linear firing shrinkage, loss on weight and water absorption capacity. The Meknes clays are characterised by medium cation exchange capacity (CEC) and specific surface area (SSA) values due to their moderate smectite content. The Tetouan clays have medium to low CEC and medium SSA values. The main oxides in the clayey samples are SiO2 (35 - 54.3 wt%), Al2O3 (20.6 - 43.9 wt%), and Fe2O3 (9.7 - 22.4 wt%). The amount of CaO in Meknes clays ranges from 8 to 12 wt%, whereas CaO is only present in some Tetouan clay (TE4, TE7, TN4 and TN5). A significant densification of ceramic behaviour could be noticed for most of Tetouan clays at firing temperatures above 1000℃. Meknes clays show earlier densification from 800℃. The chemical, textural and ceramic properties of Tetouan and Meknes clays indicate their suitability as raw materials for the production of structural ceramics. The high amount of Fe2O3 in all clays makes them inappropriate in fine ceramics.展开更多
Particle size analysis, Atterberg limits, X-ray diffraction, X-ray fluorescence and firing tests were used to determine physico-chemical, mineralogical and technological characteristics of residual lateritic (K1M, Ma2...Particle size analysis, Atterberg limits, X-ray diffraction, X-ray fluorescence and firing tests were used to determine physico-chemical, mineralogical and technological characteristics of residual lateritic (K1M, Ma2) and alluvial (KB3, KG3) clays from Foumban (West-Cameroon). For technological properties, the samples were pressed and fired over a temperature range of 900°C - 1200°C to determine the open porosity, linear shrinkage, bulk density and compressive strength. Kaolinite (31% - 65%) and quartz (35% - 50%) are dominant in Foumban clays with accessory K-feldspar, plagioclase, illite, smectite, rutile, and goethite. But their proportion changes from one sample to another, having a significant effect on the behaviour of the clay materials: highest proportion of quartz (50%) in sample K1M;relative high feldspars (20%) and illite contents (10%) in KB3 and MA2;high smectite content in KG3 (up to 20%). Chemical analyses indicate high SiO2 (49% - 77%) and low Al2O3 (14% - 23%) contents in the four samples, with comparatively low contents of iron oxides (4% - 7% in samples KB3 and KG3, 2.5% in MA2 and ~1.5% in sample K1M). The particle size distribution of the alluvial clays (KG3 and KB3) differs considerably: 7% to 37% of clay fraction, 20% to 78% of silt, and 15% to 58% of sand, while residual clays (K1M and MA2) present on average 12% of clay, 51% of silt and 37% of sand. Two raw clays (KB3 and MA2) can be used for bricks/tiles production without beneficiation or addition. K1M requires some flux addition to decrease the sintering temperature while KG3 presents poor properties due to the combined occurrence of smectite and a high clayey fraction (37%). Such mineralogical composition is responsible for very high plasticity (PI: 50), high shrinkage (LS: 5% - 16%), low porosity (OP: up to 21%) and high flexural strength (FS: 16 - 23 N/mm2) above 1050°C. This last clay is therefore less appropriate for bricks and roofing tiles production since degreasers must be added to the raw material.展开更多
This study reports the investigation of the influence of adding waste glass on the properties of fired clay specimen. Four different particle sizes (smaller than 100 μm, 300μm, 500μm, and 800 μm) of waste glass we...This study reports the investigation of the influence of adding waste glass on the properties of fired clay specimen. Four different particle sizes (smaller than 100 μm, 300μm, 500μm, and 800 μm) of waste glass were mixed with a clay material at contents of 0%, 2%, 6% and 10% per weight. Specimen samples were fired at 750℃ in an electrical furnace for 6 hours, at a heating rate of 5℃/min. The physical and mechanical properties of terracotta are studied. The chemical analysis revealed that the clays were dominated by kaolinite and montmorillonite with small proportion of mixed layers clay. The fine grained texture (0.002 mm > 25%) and high plasticity (WP > 30%) of the clays were responsible for the moderate and high values of shrinkage upon oven drying and firing. The firing color variation from reddish brown shade was due to the amounts of iron and titanium oxides present in the obtained material. The water absorption was varied between 17.40% and 13.70%, while the linear shrinkage was estimated to be between 0.70% and 1.20% and the flexural strength from 5.30 to 8.10 MPa. These results showed that mixing clay with waste glass at 750℃ is an interesting approach to obtain reddish brown ceramics destined for bricks or roofing tiles.展开更多
文摘The present paper should be considered as a review of the application of Fourier Transform Infra-Red for surface clay characterization. The application of surface clay materials for water treatment, oil adsorption, excipients or as active in drugs has largely increased these recent years. The surface clay material presents hydroxyl groups, which can link very easily water molecules. These hydroxyl groups can react with organic groups and by their vibration in the infra-red region, FT-IR can be easily used as a technical method for surface clay characterization. In this paper, we focus on the determination of Lewis and Bronsted acid sites on the clay surface, a critical review of the sample preparation, the surface characterization of bulk clay and the modified surface clay samples using FT-IR spectroscopy.
基金supported by the Key Research and Development Projects of Anhui Province (202004a06020053)National Natural Science Foundation of China (51876001, 51906001)
文摘Requirements for the respect of the environment encourage to reduce the impact of human activity on the nature. Civil engineering answers these requirements by the development of ecological construction materials. This paper deals with the transformation of clay raw materials which enable the processing of environmentally friendly construction materials: in addition to their biodegradability, the alveolar fired clay materials allow energy saving in home heating thanks to their thermal isolation properties. But their manufacturing is a high energy consumption process, in particular during compaction, drying and firing which contribute to the emission of greenhouse gases. The goal of this paper is to study the rheology of clay pastes in order to develop low energy in manufacturing processes. For this purpose, theoretical and experimental approaches were carried out on six clay varieties. In the theoretical approach, a finite element (FE) simulation model has been developed for pressing a non-rigid material predicting deformations and stresses occurring within the clay structure. Experiments have then been carried out to validate the finite element modelling. In this experimental approach, the clay pastes were transformed with water content respecting the Atterberg limits which determine the plasticity of clays. The samples compaction has been carried out under variable loadings in order to determine the suitable low energy consumption loading.
文摘This study aims at evaluating the potential suitability of Tetouan and Meknes (central Morocco) clay material as raw materials in various ceramic applications by investigating their textural, chemical, thermal and firing characteristics. Textural properties were identified by specific surface area, cation exchange capacity (CEC) and bulk density (ρs). Chemical and thermal properties were assessed using XRF and TG/DTA techniques, respectively. Firing characteristics at temperatures from 800℃ to 1100℃ were determined by linear firing shrinkage, loss on weight and water absorption capacity. The Meknes clays are characterised by medium cation exchange capacity (CEC) and specific surface area (SSA) values due to their moderate smectite content. The Tetouan clays have medium to low CEC and medium SSA values. The main oxides in the clayey samples are SiO2 (35 - 54.3 wt%), Al2O3 (20.6 - 43.9 wt%), and Fe2O3 (9.7 - 22.4 wt%). The amount of CaO in Meknes clays ranges from 8 to 12 wt%, whereas CaO is only present in some Tetouan clay (TE4, TE7, TN4 and TN5). A significant densification of ceramic behaviour could be noticed for most of Tetouan clays at firing temperatures above 1000℃. Meknes clays show earlier densification from 800℃. The chemical, textural and ceramic properties of Tetouan and Meknes clays indicate their suitability as raw materials for the production of structural ceramics. The high amount of Fe2O3 in all clays makes them inappropriate in fine ceramics.
文摘Particle size analysis, Atterberg limits, X-ray diffraction, X-ray fluorescence and firing tests were used to determine physico-chemical, mineralogical and technological characteristics of residual lateritic (K1M, Ma2) and alluvial (KB3, KG3) clays from Foumban (West-Cameroon). For technological properties, the samples were pressed and fired over a temperature range of 900°C - 1200°C to determine the open porosity, linear shrinkage, bulk density and compressive strength. Kaolinite (31% - 65%) and quartz (35% - 50%) are dominant in Foumban clays with accessory K-feldspar, plagioclase, illite, smectite, rutile, and goethite. But their proportion changes from one sample to another, having a significant effect on the behaviour of the clay materials: highest proportion of quartz (50%) in sample K1M;relative high feldspars (20%) and illite contents (10%) in KB3 and MA2;high smectite content in KG3 (up to 20%). Chemical analyses indicate high SiO2 (49% - 77%) and low Al2O3 (14% - 23%) contents in the four samples, with comparatively low contents of iron oxides (4% - 7% in samples KB3 and KG3, 2.5% in MA2 and ~1.5% in sample K1M). The particle size distribution of the alluvial clays (KG3 and KB3) differs considerably: 7% to 37% of clay fraction, 20% to 78% of silt, and 15% to 58% of sand, while residual clays (K1M and MA2) present on average 12% of clay, 51% of silt and 37% of sand. Two raw clays (KB3 and MA2) can be used for bricks/tiles production without beneficiation or addition. K1M requires some flux addition to decrease the sintering temperature while KG3 presents poor properties due to the combined occurrence of smectite and a high clayey fraction (37%). Such mineralogical composition is responsible for very high plasticity (PI: 50), high shrinkage (LS: 5% - 16%), low porosity (OP: up to 21%) and high flexural strength (FS: 16 - 23 N/mm2) above 1050°C. This last clay is therefore less appropriate for bricks and roofing tiles production since degreasers must be added to the raw material.
文摘This study reports the investigation of the influence of adding waste glass on the properties of fired clay specimen. Four different particle sizes (smaller than 100 μm, 300μm, 500μm, and 800 μm) of waste glass were mixed with a clay material at contents of 0%, 2%, 6% and 10% per weight. Specimen samples were fired at 750℃ in an electrical furnace for 6 hours, at a heating rate of 5℃/min. The physical and mechanical properties of terracotta are studied. The chemical analysis revealed that the clays were dominated by kaolinite and montmorillonite with small proportion of mixed layers clay. The fine grained texture (0.002 mm > 25%) and high plasticity (WP > 30%) of the clays were responsible for the moderate and high values of shrinkage upon oven drying and firing. The firing color variation from reddish brown shade was due to the amounts of iron and titanium oxides present in the obtained material. The water absorption was varied between 17.40% and 13.70%, while the linear shrinkage was estimated to be between 0.70% and 1.20% and the flexural strength from 5.30 to 8.10 MPa. These results showed that mixing clay with waste glass at 750℃ is an interesting approach to obtain reddish brown ceramics destined for bricks or roofing tiles.
