In order to investigate the effect of zirconia corundum on the preparation of chrome corundum castables,samples were prepared using tabular corundum,white fused corundum,active alumina micropowder,chromium oxide micro...In order to investigate the effect of zirconia corundum on the preparation of chrome corundum castables,samples were prepared using tabular corundum,white fused corundum,active alumina micropowder,chromium oxide micropowder and fused ziconia corundum particles as the main raw materials,and pure calcium aluminate cement as the binder.The effects of the fused zirconia corundum particles addition(1-0.5 mm,0,4.5%,9%,and 18%,by mass)on the linear change rate,the apparent porosity,the cold modulus of rupture,and the thermal shock resistance of chrome corundum castables were studied,and the microstructure of the samples was analyzed.The results show that:(1)with the zirconia corundum addition increasing,the permanent linear change on heating of the samples gradually increases,the apparent porosity gradually increases,the cold modulus of rupture gradually decreases,and the thermal shock resistance gradually increases;(2)according to SEM,it can be found that the phase transformation of ZrO2 after heat treatment leads to a large number of microcracks in the material.On one hand,the cold modulus of rupture of the material is reduced;on the other hand,the thermal shock resistance of the material is improved.展开更多
In order to improve the thermal shock resistance of chrome-corundum bricks,different amounts of andalusite were added to the formulation of chrome-corundum bricks to replace the equivalent white fused corundum with th...In order to improve the thermal shock resistance of chrome-corundum bricks,different amounts of andalusite were added to the formulation of chrome-corundum bricks to replace the equivalent white fused corundum with the same particle size.After mixing,shaping,drying and firing,the density,the cold strength,the cold wear resistance,the hot modulus of rupture and the thermal shock resistance were tested.XRD,SEM and elemental surface scanning were used to characterize the specimens.The results show that:(1)the volume expansion of andalusite mullitization reduces the apparent porosity of chrome-corundum bricks;(2)the density and the hardness of mullite are lower than those of corundum so the decrease of the corundum content in brick leads to the decrease of the bulk density,the strength and the cold wear resistance;(3)the cross-distributed columnar mullite in the matrix can effectively improve the hot modulus of rupture and the thermal shock resistance of the specimens;(4)considering comprehensively,the andalusite addition shall not exceed 18%.展开更多
文摘In order to investigate the effect of zirconia corundum on the preparation of chrome corundum castables,samples were prepared using tabular corundum,white fused corundum,active alumina micropowder,chromium oxide micropowder and fused ziconia corundum particles as the main raw materials,and pure calcium aluminate cement as the binder.The effects of the fused zirconia corundum particles addition(1-0.5 mm,0,4.5%,9%,and 18%,by mass)on the linear change rate,the apparent porosity,the cold modulus of rupture,and the thermal shock resistance of chrome corundum castables were studied,and the microstructure of the samples was analyzed.The results show that:(1)with the zirconia corundum addition increasing,the permanent linear change on heating of the samples gradually increases,the apparent porosity gradually increases,the cold modulus of rupture gradually decreases,and the thermal shock resistance gradually increases;(2)according to SEM,it can be found that the phase transformation of ZrO2 after heat treatment leads to a large number of microcracks in the material.On one hand,the cold modulus of rupture of the material is reduced;on the other hand,the thermal shock resistance of the material is improved.
文摘In order to improve the thermal shock resistance of chrome-corundum bricks,different amounts of andalusite were added to the formulation of chrome-corundum bricks to replace the equivalent white fused corundum with the same particle size.After mixing,shaping,drying and firing,the density,the cold strength,the cold wear resistance,the hot modulus of rupture and the thermal shock resistance were tested.XRD,SEM and elemental surface scanning were used to characterize the specimens.The results show that:(1)the volume expansion of andalusite mullitization reduces the apparent porosity of chrome-corundum bricks;(2)the density and the hardness of mullite are lower than those of corundum so the decrease of the corundum content in brick leads to the decrease of the bulk density,the strength and the cold wear resistance;(3)the cross-distributed columnar mullite in the matrix can effectively improve the hot modulus of rupture and the thermal shock resistance of the specimens;(4)considering comprehensively,the andalusite addition shall not exceed 18%.
