LiNi0.8Co0.1Mn0.1O_(2)(NCM811),a Ni-rich layered oxide,is a promising cathode material for high-energy density lithium-ion batteries(LIBs).However,its structural instability,caused by adverse phase transitions and con...LiNi0.8Co0.1Mn0.1O_(2)(NCM811),a Ni-rich layered oxide,is a promising cathode material for high-energy density lithium-ion batteries(LIBs).However,its structural instability,caused by adverse phase transitions and continuous oxygen release,as well as deteriorated interfacial stability due to excessive electrolyte oxidative decomposition,limits its widespread application.To address these issues,a new concept is proposed that surface targeted precise functionalization(STPF)of the NCM811 cathode using a synergistic slurry additive(SSA)approach.This approach involves coating the NCM811 particle surface with 3-aminopropyl dimethoxy methyl silane(3-ADMS),followed by the precise deposition of ascorbic acid via an acid-base interaction.The slurry additives induce the formation of an ultra-thin spinel surface layer and a stable cathode–electrolyte interface(CEI),which enhances the electrochemical kinetics and inhibits crack propagation.The STPF strategy implemented by the SSA approach significantly improves the cyclic stability and rate performance of the NCM811 cathode in both half-cell and full-cell configurations.This work establishes a promising strategy to enhance the structural stability and electrochemical performance of nickel-rich cathodes and provides a feasible route to promote practical applications of high-energy density lithium-ion battery technology.展开更多
This paper presents the effects of both poly vinylidene fluoride(PVDF)/carbon black(CB)ratio(m PVDF:m CB)and mixing time t on the dispersion mechanism of the cathode slurry of lithium-ion battery(LIB).The dispersion m...This paper presents the effects of both poly vinylidene fluoride(PVDF)/carbon black(CB)ratio(m PVDF:m CB)and mixing time t on the dispersion mechanism of the cathode slurry of lithium-ion battery(LIB).The dispersion mechanism is deduced from the electrochemical,morphological and rheological properties of the cathode slurry by using electrical impedance spectroscopy(EIS),scanning electron microscopy and rheology methods,respectively.From the perspective of EIS method,static simulation models are established in the COMSOL Multiphysics software;meanwhile,the simulated results are used to verify the correctness of the electrochemical properties of the cathode slurry.As a result,the following conclusions are able to be obtained.Firstly,in the case of the mass ratio m_(PVDF):m_(CB)=5:10,LiCoO_(2) particles are completely coated by the mixture of CB and PVDF to form a stable polymer gel structure.Higher or lower m_(PVDF):m_(CB) leads to the larger impedance and worse dispersion status for the cathode slurry.Secondly,when t=6 min,a good gel-like conductive network structure is formed by coating the thinner evenly dispersed CB–PVDF double layer around LiCoO_(2) particles.Finally,a strategy regarding to both m_(PVDF):m_(CB) and t in experimental scale is proposed,which has the capability of improving the performance of LIB.展开更多
With high effective screen-printing technique, a new triode field emission display (FED)with enhanced petaling cold cathode was fabricated. For enhancing the field emission performance,a series of improved measures wa...With high effective screen-printing technique, a new triode field emission display (FED)with enhanced petaling cold cathode was fabricated. For enhancing the field emission performance,a series of improved measures was adopted in the fabrication course. Seen from the fabrication structure of enhanced petaling cold cathode,the bar conducting electrode and the petaling bottom electrode were fabricated with the sintered silver slurry on cathode glass faceplate. The luminescence image with green phosphor was displayed for the sealed enhanced petaling cold cathode FED. The measured results showed that the enhanced petaling cold cathode had good field emission performance. The enhanced petaling cold cathode FED possessed low turn-on electric-field of 1. 95 V /μm,large emission current of 1 389. 6 μA,and high luminance brightness of 1 520 cd /m2 .展开更多
The La0.8Sr0.04Ca0.16Co0.6Fe0.4O3-δ (LSCCoF) and La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) powders were synthesized by glycine-nitrate combustion process and conventional solid-state reaction method, respectively. The LSCCoF-LSG...The La0.8Sr0.04Ca0.16Co0.6Fe0.4O3-δ (LSCCoF) and La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) powders were synthesized by glycine-nitrate combustion process and conventional solid-state reaction method, respectively. The LSCCoF-LSGM composite cathode material was successfully elaborated and deposited on dense pellets of the LSGM electrolyte by means of slurry spin-coating process. The cathode films with the best surface morphology and microstructure were obtained when the operating parameters fixed as follows: the content of ethyl cellulose which acted as pore former and binder is 10 wt.%, the content of terpineol which acted as modifier is 5 wt.%, the speed of rotation rate is 3200 r/min and the best post-deposition sintering temperature is 1000°C.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21965034,52061135110,U1903217,52162036,22065033,21905242,and 22075305)the Key Project of Nature Science Foundation of Xinjiang Province(No.2021D01D08)+4 种基金the Xinjiang Autonomous Region Major Projects(Nos.2022A01005-4 and 2021A01001-1)the Natural Science Foundation of Zhejiang Province(No.LD22E020003)the Ningbo Science&Technology Innovation 2025 Major Project(No.2020Z024)the Foundation of State Key Laboratory of Chemistry and Utilization of Carbon-based Energy Resource(No.KFKT2022004)Key Laboratory of Bio-based Polymeric Materials of Zhejiang Province.
文摘LiNi0.8Co0.1Mn0.1O_(2)(NCM811),a Ni-rich layered oxide,is a promising cathode material for high-energy density lithium-ion batteries(LIBs).However,its structural instability,caused by adverse phase transitions and continuous oxygen release,as well as deteriorated interfacial stability due to excessive electrolyte oxidative decomposition,limits its widespread application.To address these issues,a new concept is proposed that surface targeted precise functionalization(STPF)of the NCM811 cathode using a synergistic slurry additive(SSA)approach.This approach involves coating the NCM811 particle surface with 3-aminopropyl dimethoxy methyl silane(3-ADMS),followed by the precise deposition of ascorbic acid via an acid-base interaction.The slurry additives induce the formation of an ultra-thin spinel surface layer and a stable cathode–electrolyte interface(CEI),which enhances the electrochemical kinetics and inhibits crack propagation.The STPF strategy implemented by the SSA approach significantly improves the cyclic stability and rate performance of the NCM811 cathode in both half-cell and full-cell configurations.This work establishes a promising strategy to enhance the structural stability and electrochemical performance of nickel-rich cathodes and provides a feasible route to promote practical applications of high-energy density lithium-ion battery technology.
基金support from National Natural Science Foundation of China(grant No.52006176 and 62101438)the Key Research and Development Project of Shaanxi Province(grant No.2022kw-18)+1 种基金the Ministry of Education's“Chunhui Plan”Collaborative Research project(grant No.202200491)Science and Technology Program of Xi'an(grant No.22GXFW0095)。
文摘This paper presents the effects of both poly vinylidene fluoride(PVDF)/carbon black(CB)ratio(m PVDF:m CB)and mixing time t on the dispersion mechanism of the cathode slurry of lithium-ion battery(LIB).The dispersion mechanism is deduced from the electrochemical,morphological and rheological properties of the cathode slurry by using electrical impedance spectroscopy(EIS),scanning electron microscopy and rheology methods,respectively.From the perspective of EIS method,static simulation models are established in the COMSOL Multiphysics software;meanwhile,the simulated results are used to verify the correctness of the electrochemical properties of the cathode slurry.As a result,the following conclusions are able to be obtained.Firstly,in the case of the mass ratio m_(PVDF):m_(CB)=5:10,LiCoO_(2) particles are completely coated by the mixture of CB and PVDF to form a stable polymer gel structure.Higher or lower m_(PVDF):m_(CB) leads to the larger impedance and worse dispersion status for the cathode slurry.Secondly,when t=6 min,a good gel-like conductive network structure is formed by coating the thinner evenly dispersed CB–PVDF double layer around LiCoO_(2) particles.Finally,a strategy regarding to both m_(PVDF):m_(CB) and t in experimental scale is proposed,which has the capability of improving the performance of LIB.
基金National Natural Science Foundations of China(No.60976058,No.61274078)Natural Science Research Project of Henan Province Education Department,China(No.2009B510019)
文摘With high effective screen-printing technique, a new triode field emission display (FED)with enhanced petaling cold cathode was fabricated. For enhancing the field emission performance,a series of improved measures was adopted in the fabrication course. Seen from the fabrication structure of enhanced petaling cold cathode,the bar conducting electrode and the petaling bottom electrode were fabricated with the sintered silver slurry on cathode glass faceplate. The luminescence image with green phosphor was displayed for the sealed enhanced petaling cold cathode FED. The measured results showed that the enhanced petaling cold cathode had good field emission performance. The enhanced petaling cold cathode FED possessed low turn-on electric-field of 1. 95 V /μm,large emission current of 1 389. 6 μA,and high luminance brightness of 1 520 cd /m2 .
基金Project supported by the Natural Science Foundation of Yunnan Province (2009ZC027M)Program for New Century Excellent Talents in University (NCET-07-0387)
文摘The La0.8Sr0.04Ca0.16Co0.6Fe0.4O3-δ (LSCCoF) and La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) powders were synthesized by glycine-nitrate combustion process and conventional solid-state reaction method, respectively. The LSCCoF-LSGM composite cathode material was successfully elaborated and deposited on dense pellets of the LSGM electrolyte by means of slurry spin-coating process. The cathode films with the best surface morphology and microstructure were obtained when the operating parameters fixed as follows: the content of ethyl cellulose which acted as pore former and binder is 10 wt.%, the content of terpineol which acted as modifier is 5 wt.%, the speed of rotation rate is 3200 r/min and the best post-deposition sintering temperature is 1000°C.
