The crystal structure of 2-(2-pyridyl) benzimidazole was determined by single- crystal X-ray diffraction at 193(2) K. It crystallizes in orthorhombic system, space group Pbca with unit cell constants a = 10.6204(7), b...The crystal structure of 2-(2-pyridyl) benzimidazole was determined by single- crystal X-ray diffraction at 193(2) K. It crystallizes in orthorhombic system, space group Pbca with unit cell constants a = 10.6204(7), b = 10.1407(4), c = 18.6327(8) , Z = 8, V = 2006.7(2) 3, Dc = 1.292 g/cm3, F(000) = 816 and m(MoK) = 0.081 mm-1. The structure was refined to R = 0.0317 and wR = 0.0454 for 795 observed reflections with I > 2s(I). In the solid state, it has an emission maximum at 369 nm, while in solution (DMSO), the maximum excitation is at 372 nm. Quantum chemistry calculation was performed by the method of density functional theory. Theoretical results show that atom N is the reactive site when coordinating with a metal, and the electronic structure of the title compound presents excellent carrier transport properties.展开更多
Numerical analysis of three-dimensional(3-D)two-phase reacting flowfield in an annular combustor wity the dump diffuser is developed in arbitrary curvilinear coordi-nates.Combustor performances are estimated by the em...Numerical analysis of three-dimensional(3-D)two-phase reacting flowfield in an annular combustor wity the dump diffuser is developed in arbitrary curvilinear coordi-nates.Combustor performances are estimated by the em-pirical-analytical desing method.Ths influence of three inlet velocity profiles of the prediffuser and two operating conditions on combustor preformance and flow character-istic is predicted.展开更多
Current-carrying coils are basic elements in electromagnetic equipments, for example, in high field magnets from high temperature superconducting wires or tapes. In the assembly of these systems and their current-carr...Current-carrying coils are basic elements in electromagnetic equipments, for example, in high field magnets from high temperature superconducting wires or tapes. In the assembly of these systems and their current-carrying operation, unavoidable mis- alignment and shift from the original position can be induced by disturbances such as the imbalance of magnetic force due to safety problems. For two current-carrying coils with non-coplanar axes, the analytic expression of the magnetic force between the two coils is presented according to the rule of Ampere circulation and the Biot-Savart law. Based on the expression, the dependence of the magnetic force on the size and the relative position of each other is further investigated, and the variation of the magnetic force is obtained with the above parameters.展开更多
Reaction of laser ablated zinc and cadmium atoms with SO2 molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M（SO2） and anion M（SO2）-（M=Zn, Cd） were produced in excess argon ...Reaction of laser ablated zinc and cadmium atoms with SO2 molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M（SO2） and anion M（SO2）-（M=Zn, Cd） were produced in excess argon and neon, which were identified by 34SO2 and S18O2 isotopic substitutions. The observed infrared spectra and molecular structures were confirmed by density functional theoretical calculations. Natural charge distributions indicated significant electron transfer from s orbitals of zinc or cadmium metal atom to S02 ligand and cyclic M（SO2） complexes favored ＂ion pair＂ M＋（SO2）-formation, which were trapped in low temperature matrices. In addition Zn-O or Cd-O bond in M（SO2） exhibited strong polarized covalent character. Reaction of Hg atom with SO2 was also investigated, but no reaction product was observed, due to the relativistic effect that resulted in the contraction of 6s valence shell and high ionization potential of Hg atom.展开更多
A practical neural network model for morphological filtering and a simulated annealing optimal algorithm for the network parameters training are proposed in this paper. It is pointed out that the opti- mal designing p...A practical neural network model for morphological filtering and a simulated annealing optimal algorithm for the network parameters training are proposed in this paper. It is pointed out that the opti- mal designing process of the morphological filtering network in fact is the optimal learning process of adjusting network parameters (structuring element, or SE for short) to accommodate image environment. Then the network structure may possess the characteristics of image targets, and so give specific infor- mation to the SE. Morphological filters formed in this way become certainly intelligent and can provide good filtering results and robust adaptability to complex changing image. For application to motional image target detection, dynamic training algorithm is applied to the designing process using asymptotic shrinking error and appropriate network weights adjusting. Experimental results show that the algorithm has invariant property with respect to shift, scale and rotation of moving target in continuing detection of moving targets.展开更多
基金The report was supported by the funds of Ministry of Education Scientific and Technical Committee in Jilin province (20005511) and NENU Testing Fund [2001]3
文摘The crystal structure of 2-(2-pyridyl) benzimidazole was determined by single- crystal X-ray diffraction at 193(2) K. It crystallizes in orthorhombic system, space group Pbca with unit cell constants a = 10.6204(7), b = 10.1407(4), c = 18.6327(8) , Z = 8, V = 2006.7(2) 3, Dc = 1.292 g/cm3, F(000) = 816 and m(MoK) = 0.081 mm-1. The structure was refined to R = 0.0317 and wR = 0.0454 for 795 observed reflections with I > 2s(I). In the solid state, it has an emission maximum at 369 nm, while in solution (DMSO), the maximum excitation is at 372 nm. Quantum chemistry calculation was performed by the method of density functional theory. Theoretical results show that atom N is the reactive site when coordinating with a metal, and the electronic structure of the title compound presents excellent carrier transport properties.
文摘Numerical analysis of three-dimensional(3-D)two-phase reacting flowfield in an annular combustor wity the dump diffuser is developed in arbitrary curvilinear coordi-nates.Combustor performances are estimated by the em-pirical-analytical desing method.Ths influence of three inlet velocity profiles of the prediffuser and two operating conditions on combustor preformance and flow character-istic is predicted.
基金Project supported by the National Natural Science Foundation of China(No.11372096)the Program for Research Fund for the Doctoral Program of Higher Education of China
文摘Current-carrying coils are basic elements in electromagnetic equipments, for example, in high field magnets from high temperature superconducting wires or tapes. In the assembly of these systems and their current-carrying operation, unavoidable mis- alignment and shift from the original position can be induced by disturbances such as the imbalance of magnetic force due to safety problems. For two current-carrying coils with non-coplanar axes, the analytic expression of the magnetic force between the two coils is presented according to the rule of Ampere circulation and the Biot-Savart law. Based on the expression, the dependence of the magnetic force on the size and the relative position of each other is further investigated, and the variation of the magnetic force is obtained with the above parameters.
文摘Reaction of laser ablated zinc and cadmium atoms with SO2 molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M（SO2） and anion M（SO2）-（M=Zn, Cd） were produced in excess argon and neon, which were identified by 34SO2 and S18O2 isotopic substitutions. The observed infrared spectra and molecular structures were confirmed by density functional theoretical calculations. Natural charge distributions indicated significant electron transfer from s orbitals of zinc or cadmium metal atom to S02 ligand and cyclic M（SO2） complexes favored ＂ion pair＂ M＋（SO2）-formation, which were trapped in low temperature matrices. In addition Zn-O or Cd-O bond in M（SO2） exhibited strong polarized covalent character. Reaction of Hg atom with SO2 was also investigated, but no reaction product was observed, due to the relativistic effect that resulted in the contraction of 6s valence shell and high ionization potential of Hg atom.
文摘A practical neural network model for morphological filtering and a simulated annealing optimal algorithm for the network parameters training are proposed in this paper. It is pointed out that the opti- mal designing process of the morphological filtering network in fact is the optimal learning process of adjusting network parameters (structuring element, or SE for short) to accommodate image environment. Then the network structure may possess the characteristics of image targets, and so give specific infor- mation to the SE. Morphological filters formed in this way become certainly intelligent and can provide good filtering results and robust adaptability to complex changing image. For application to motional image target detection, dynamic training algorithm is applied to the designing process using asymptotic shrinking error and appropriate network weights adjusting. Experimental results show that the algorithm has invariant property with respect to shift, scale and rotation of moving target in continuing detection of moving targets.
