Functional groups on the rim of open-cage fullerenes usually exhibit different reactivity from those in classical organic molecules due to the unique spherical structure of fullerenes.The present work shows a sequence...Functional groups on the rim of open-cage fullerenes usually exhibit different reactivity from those in classical organic molecules due to the unique spherical structure of fullerenes.The present work shows a sequence of lactone opening,imino hydrolysis,aminal formation and imine formation processes during the reaction of aniline with the open-cage compound 1 with functional groups including lactone on the rim of the orifice.Single crystal X-ray diffraction analysis confirmed the structure of the product.展开更多
基金the National Natural Science Foundation of China(Nos.21272013 and 21132007)the Major State Basic Research Development Program(No.2011CB808401).
文摘Functional groups on the rim of open-cage fullerenes usually exhibit different reactivity from those in classical organic molecules due to the unique spherical structure of fullerenes.The present work shows a sequence of lactone opening,imino hydrolysis,aminal formation and imine formation processes during the reaction of aniline with the open-cage compound 1 with functional groups including lactone on the rim of the orifice.Single crystal X-ray diffraction analysis confirmed the structure of the product.
