Red mud is a type of highly alkaline waste residue produced in the process of alumina smelting by the Bayer process.Based on the idea of medium calcium content,solid wastes such as red mud and fly ash were used to pre...Red mud is a type of highly alkaline waste residue produced in the process of alumina smelting by the Bayer process.Based on the idea of medium calcium content,solid wastes such as red mud and fly ash were used to prepare non-burnt bricks;and the mass ratio of CaO/SiO2 was selected in the range of 0.88–1.42.Mechanical properties and durability were investigated with a compressive strength test.X-ray diffractometry(XRD),scanning electron microscope(SEM),and Fourier transform infrared spectroscopy(FTIR)techniques were used to characterize the hydration characteristic.The environmental performance was analyzed by Inductively Coupled Plasma Mass Spectrometry(ICP).The results indicated that the mechanical properties and the durability were optimal when the mass ratio of CaO/SiO2 was 1.23.The hydration products were mostly C–S–H gel,ettringite,Na4Ca(Si10All6)O32·12H2O and Ca3Al2(SiO4)(OH)8.They were responsible for the strength development,and the CaO/SiO2 mass ratio of 1.23 had the best polymerized structure.The results of an environmental performance test showed that the heavy metals in the raw materials were well-solidified in the brick.Therefore,this paper provides an effective solution for use of solid wastes in building material.展开更多
Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction wa...Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction waste.The fluidity and bleeding of the fresh CLSM mixtures were measured via the modified test methods, and the hardened CLSM mixtures were then molded to evaluate their compressive strength and durability. The results showthat the fluidity of the fresh CLSM mixtures is 105 to 227 mm with the corresponding bleeding rate of 3. 7% to 15. 5%, which increases with the increase in fluidity. After aging for 28 d,the compressive strength of the hardened CLSM mixtures reaches 1. 15 to 13. 96 M Pa, and their strength can be further enhanced with longer curing ages. Additionally, the strength increases with the increase of the C/Sa ratio, and decreases with the increase of the W/So ratio under the same curing age. Based on the obtained compressive strength, a fitting model for accurately predicting the compressive strength of the CLSM mixtures was established, which takes into account the above two independent variables( C/Sa and W/So ratios).M oreover, the durability of the hardened CLSM mixtures is enhanced for samples with higher C/Sa ratios.展开更多
基金the financial support from the National Natural Science Foundation of China (No.51574024)Fundamental Research Funds for the Central Universities (FRF-TP-18-005B1)Technological Research and Development Programs of China Railways Corporation (No.2017G006-J)
文摘Red mud is a type of highly alkaline waste residue produced in the process of alumina smelting by the Bayer process.Based on the idea of medium calcium content,solid wastes such as red mud and fly ash were used to prepare non-burnt bricks;and the mass ratio of CaO/SiO2 was selected in the range of 0.88–1.42.Mechanical properties and durability were investigated with a compressive strength test.X-ray diffractometry(XRD),scanning electron microscope(SEM),and Fourier transform infrared spectroscopy(FTIR)techniques were used to characterize the hydration characteristic.The environmental performance was analyzed by Inductively Coupled Plasma Mass Spectrometry(ICP).The results indicated that the mechanical properties and the durability were optimal when the mass ratio of CaO/SiO2 was 1.23.The hydration products were mostly C–S–H gel,ettringite,Na4Ca(Si10All6)O32·12H2O and Ca3Al2(SiO4)(OH)8.They were responsible for the strength development,and the CaO/SiO2 mass ratio of 1.23 had the best polymerized structure.The results of an environmental performance test showed that the heavy metals in the raw materials were well-solidified in the brick.Therefore,this paper provides an effective solution for use of solid wastes in building material.
基金The National Science and Technology Support Program of China(No.2014BAC07B03)the Science and Technology Project of Transportation Committee of Beijing Government(No.2016-LZJKJ-01-006)the National Natural Science Foundation of China(No.51278016)
文摘Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction waste.The fluidity and bleeding of the fresh CLSM mixtures were measured via the modified test methods, and the hardened CLSM mixtures were then molded to evaluate their compressive strength and durability. The results showthat the fluidity of the fresh CLSM mixtures is 105 to 227 mm with the corresponding bleeding rate of 3. 7% to 15. 5%, which increases with the increase in fluidity. After aging for 28 d,the compressive strength of the hardened CLSM mixtures reaches 1. 15 to 13. 96 M Pa, and their strength can be further enhanced with longer curing ages. Additionally, the strength increases with the increase of the C/Sa ratio, and decreases with the increase of the W/So ratio under the same curing age. Based on the obtained compressive strength, a fitting model for accurately predicting the compressive strength of the CLSM mixtures was established, which takes into account the above two independent variables( C/Sa and W/So ratios).M oreover, the durability of the hardened CLSM mixtures is enhanced for samples with higher C/Sa ratios.
