In order to prepare ornamental and anti-corrosive coating on aluminum alloys, preparation technology of black micro-arc ceramic coatings on Al alloys in silicate based electrolyte was studied. The influence of content...In order to prepare ornamental and anti-corrosive coating on aluminum alloys, preparation technology of black micro-arc ceramic coatings on Al alloys in silicate based electrolyte was studied. The influence of content of Na2WO4 and combination additive in solution on the performance of black ceramic coatings was studied; the anticorrosion performances of black ceramic coatings were evaluated through whole-immersion test and electrochemical method in 3.5% NaCl solution at different pH value; SEM and XRD were used to analyze the surface morphology and phase constitutes of the black ceramic coatings. Experimental results indicated that, without combination additives, with the increasing of Na2WO4 content in the electrolyte, ceramic coating became darker and thicker, but the color was not black; after adding combination additive, the coating turned to be black; the black ceramic coating was multi-hole form in surface. There was a small quantity of tungsten existing in the black ceramic coating beside α-Al2O3 phase and β-Al2O3 phase. And aluminum alloy with black ceramic coating exhibited excellent anti-corrosion property in acid, basic and neutral 3.5% NaCl solution.展开更多
The optical properties of coatings pigmented with different black colorants were systematically investigated and their surface temperatures and cooling energy savings were estimated. The black coatings pigmented with ...The optical properties of coatings pigmented with different black colorants were systematically investigated and their surface temperatures and cooling energy savings were estimated. The black coatings pigmented with chromite iron nickel black and manganese ferrite black spinel colorants are not cool enough to be energy efficient cool black coatings. The cool black coatings pigmented with NIR-transmitting perylene black and dioxazine purple colorants possess a green shade and a violet shade, respectively. The estimated surface temperature reduction values and annual cooling energy savings in Beijing range from 3.0°C and 1.21 kWhm-2yr-1 for the black coating pigmented with chromite iron nickel colorant to 13.8°C and 5.52 kWhm-2yr-1 for the black coating pigmented with dioxazine purple colorant, respectively.展开更多
基金This work was financially supported bythe Doctoral Foundation ofYanshan University(B41)theScience and Technology Foundation ofYanshan University(YDJJ0169).
文摘In order to prepare ornamental and anti-corrosive coating on aluminum alloys, preparation technology of black micro-arc ceramic coatings on Al alloys in silicate based electrolyte was studied. The influence of content of Na2WO4 and combination additive in solution on the performance of black ceramic coatings was studied; the anticorrosion performances of black ceramic coatings were evaluated through whole-immersion test and electrochemical method in 3.5% NaCl solution at different pH value; SEM and XRD were used to analyze the surface morphology and phase constitutes of the black ceramic coatings. Experimental results indicated that, without combination additives, with the increasing of Na2WO4 content in the electrolyte, ceramic coating became darker and thicker, but the color was not black; after adding combination additive, the coating turned to be black; the black ceramic coating was multi-hole form in surface. There was a small quantity of tungsten existing in the black ceramic coating beside α-Al2O3 phase and β-Al2O3 phase. And aluminum alloy with black ceramic coating exhibited excellent anti-corrosion property in acid, basic and neutral 3.5% NaCl solution.
文摘The optical properties of coatings pigmented with different black colorants were systematically investigated and their surface temperatures and cooling energy savings were estimated. The black coatings pigmented with chromite iron nickel black and manganese ferrite black spinel colorants are not cool enough to be energy efficient cool black coatings. The cool black coatings pigmented with NIR-transmitting perylene black and dioxazine purple colorants possess a green shade and a violet shade, respectively. The estimated surface temperature reduction values and annual cooling energy savings in Beijing range from 3.0°C and 1.21 kWhm-2yr-1 for the black coating pigmented with chromite iron nickel colorant to 13.8°C and 5.52 kWhm-2yr-1 for the black coating pigmented with dioxazine purple colorant, respectively.
