Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant pr...Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant products were examined with thermtygravimetrie analysis （TGA） and high performance liquid chro- matography（HPLC）. Thermogravimetry data shows that BDP decomposes at 375℃ when 5 % weight lost. Experiments results show that catalyst is preferably AICI3 and the amount of it is preferably 1% relative to bisphenol A by mole. POCl3/bisphenol A mole ratio is preferably about 5：1 to 6：1. Experiments unclosed that a seal apparatus is very important to the properties of product.展开更多
文摘Bisphenol A bis（diphenyl phosphate） oligomer（BDP） is prepared successfully from the reactants consisting of phosphorus oxyehloride （POCl3）, bisphenol A and phenol with a Friedel-Crafts catalyst. The resultant products were examined with thermtygravimetrie analysis （TGA） and high performance liquid chro- matography（HPLC）. Thermogravimetry data shows that BDP decomposes at 375℃ when 5 % weight lost. Experiments results show that catalyst is preferably AICI3 and the amount of it is preferably 1% relative to bisphenol A by mole. POCl3/bisphenol A mole ratio is preferably about 5：1 to 6：1. Experiments unclosed that a seal apparatus is very important to the properties of product.
